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Elsevier eBooks

Radial wave functions for hydrogen atom

Norman Henry March

Published Jan 1, 1975• 0 citations
Publisher
DOI
10.1016/b978-0-08-017819-6.50015-0

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The function of the radial wave of a hydrogen atom in the principal quantum numbers (n) 4 and 5

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The simplest atom consisting of a proton and an electron is a hydrogen atom. The energy level and the probability of finding an electron in a hydrogen atom can be determined based on the function of radial wave. The function of radial wave of a hydrogen atom is influenced by the principal quantum number ( n ) and the orbital quantum number ( l ). Completion of the function of radial wave of a hydrogen atom in the principal quantum numbers( n ) 4 and 5 uses the time-independent Schrodinger equation approach in spherical coordinates, variable separation method and uses the associated Laguerre function. The normalized of the function of radial wave of a hydrogen atom R nl ( r ) at n = 4 produces four wave functions:R 40 ( r ); R 41 ( r ); R 42 ( r ); R 43 ( r ), whereas at n = 5 produces five wave functions:R 50 ( r ); R 51 ( r ); R 52 ( r ); R 53 ( r ); R 54 ( r ). The results of this research in the form of the functions of radial wave of hydrogen atom can be used to determine the behavior of electron in a hydrogen atom.

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With an aim at the abstract conception of wave functions for hydrogen atom in quantum mechanics,this paper suggests the radial distribution,angular distribution and spatial distribution function of hydrogen atom electronic cloud,and also,Matlab software is used to plot their corresponding distribution charts.The analytical results indicate that the distribution patterns of hydrogen atom electronic clouds are co-determined by the radial and angular probability distribution,and that the electronic cloud distribution density is so uneven that the orbit trace can be observed.Accordingly,this method can reveal the radial,angular and spatial probability distribution laws of hydrogen atom electronic clouds intuitionally,whereby a new thinking way for analyzing the abstract wave function visualization in quantum mechanics is provided in this paper.

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Wave Functions for the Hydrogen-like Atom

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The simplest atom consisting of a proton and an electron is a hydrogen atom. The energy level and the probability of finding an electron in a hydrogen atom can be determined based on the function of radial wave. The function of radial wave of a hydrogen atom is influenced by the principal quantum number ( n ) and the orbital quantum number ( l ). Completion of the function of radial wave of a hydrogen atom in the principal quantum numbers( n ) 4 and 5 uses the time-independent Schrodinger equation approach in spherical coordinates, variable separation method and uses the associated Laguerre function. The normalized of the function of radial wave of a hydrogen atom R nl ( r ) at n = 4 produces four wave functions:R 40 ( r ); R 41 ( r ); R 42 ( r ); R 43 ( r ), whereas at n = 5 produces five wave functions:R 50 ( r ); R 51 ( r ); R 52 ( r ); R 53 ( r ); R 54 ( r ). The results of this research in the form of the functions of radial wave of hydrogen atom can be used to determine the behavior of electron in a hydrogen atom.
With an aim at the abstract conception of wave functions for hydrogen atom in quantum mechanics,this paper suggests the radial distribution,angular distribution and spatial distribution function of hydrogen atom electronic cloud,and also,Matlab software is used to plot their corresponding distribution charts.The analytical results indicate that the distribution patterns of hydrogen atom electronic clouds are co-determined by the radial and angular probability distribution,and that the electronic cloud distribution density is so uneven that the orbit trace can be observed.Accordingly,this method can reveal the radial,angular and spatial probability distribution laws of hydrogen atom electronic clouds intuitionally,whereby a new thinking way for analyzing the abstract wave function visualization in quantum mechanics is provided in this paper.