Quantum mechanics is one of the crowning achievements of human thought. There is no theory that is more successful in predicting phenomena over such a wide range of situations—and with such accuracy—than quantum mechanics. From the basic principles of chemistry to the working of the semiconductors in your mobile phone, and from the Big Bang to atomic clocks, quantum mechanics comes up with the goods. At the same time, we still have trouble pinpointing exactly what the theory tells us about nature. Quantum mechanics is hard, but perhaps not as hard as you think.
Quantum mechanics is one of the crowning achievements of human thought. There is no theory that is more successful in predicting phenomena over such a wide range of situations—and with such accuracy—than quantum mechanics. From the basic principles of chemistry to the working of the semiconductors in your mobile phone, and from the Big Bang to atomic clocks, quantum mechanics comes up with the goods. At the same time, we still have trouble pinpointing exactly what the theory tells us about nature. Quantum mechanics is hard, but perhaps not as hard as you think.
Quantum mechanics is the fundamental theory of nature at small scales and low energies of atoms and subatomic particles. Quantum mechanics is inescapable. Nearly all fields of modern physics, from elementary particles to the big bang, from semiconductors to solar energy cells, are related to quantum physics. Particles have characteristic trait of both particles and waves. The Schrodinger equation is the basic equation of quantum mechanics. The Schrodinger equation was established based on the quantization of energy conservation using quantum operators and the de Broglie relation. Wave function plays an important role in quantum mechanics. The probability interpretation assumes that the norm of the wave function measures the probability of the system in a particular coordinate or representation, in which the total probability is normalized.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
Quantum mechanics occupies a unique position in the history of science. It has survived all experimental tests to date, culminating with the most precise comparison of any measurement to any theory – a 1987 measurement of the electron's magnetic moment, or gyromagnetic ratio g e = 2.002 319 304 39 (Van Dyck et al. 1987), agreeing with QED theory to 12 digits. Despite this and other dramatic successes of quantum mechanics, its foundations are often questioned, owing to the glaring difficulties in reconciling quantum physics with the classical laws of physics that govern macroscopic bodies. If quantum mechanics is indeed a complete theory of nature, why does it not apply to everyday life? Even Richard Feynman (1982), a fierce defender of quantum mechanics, memorably stated that: We have always had a great deal of difficulty in understanding the world view that quantum mechanics represents … Okay, I still get nervous with it … It has not yet become obvious to me that there is no real problem. I cannot define the real problem, therefore I suspect there's no real problem, but I'm not sure there's no real problem. In the dawn of the twenty-first century, John A. Wheeler's big question “Why the quantum?” has returned to the forefront of physics with full steam. Advances in experimental physics are beginning to realize the same thought-experiments that proved helpful to Einstein, Bohr, Heisenberg, Schrödinger, and the other founders of quantum mechanics.
The textbook covers the background theory of various effects discussed from first principles, as clearly as possible, to introduce students to the main ideas of quantum physics and to teach the basic mathematical methods and techniques used in the fields of advanced quantum physics, atomic physics, laser physics, nanotechnology, quantum chemistry, and theoretical mathematics. Many of the predictions of quantum physics appear to be contrary to our intuitive perceptions, and the student will learn how it comes about that microscopic objects (particles) behave in unusual ways that are called quantum effects, what we mean by quantum, and where this idea came from. The textbook is supplemented with Problems and Solutions in Quantum Physics, which contains a wide range of tutorial problems from simple confidence builders to fairly challenging problems that provide adequate understanding of the basic concepts of quantum physics.
Why yet another book on quantum mechanics? Quantum mechanics was born in the first quarter of the twentieth century and has received an enormous number of theoretical and experimental confirmations over the years. It is considered to be the fundamental physical paradigm, and has a wide range of applications, from cosmology to chemistry, and from biology to information sciences. It is one of the greatest intellectual achievements of the past century. As an effect of its invention, the very concept of physical reality was changed, and “observation,” “measurement,” “prediction,” and “state of the system” acquired a new and deeper meaning. Probability was not unknown in physics: it was introduced by Boltzmann in order to control the behavior of a system with a very large number of particles. It was the missing concept in order to understand the thermodynamics of macroscopic bodies, but the structure of the physical laws remained still deterministic. The introduction of probability was needed as a consequence of our lack of knowledge of the initial conditions of the system and of our inability to solve an enormous number of coupled non-linear differential equations. In quantum mechanics, the tune is different: if we have 10 6 radioactive atoms no intrinsic unknown variables decide which of them will decay first. What we observe experimentally seems to be an irreducible random process. The original explanation of this phenomenon in quantum mechanics was rather unexpected.
Quantum mechanics deals with the behaviour of matter and light on the atomic and subatomic scale. It attempts to describe and account for the properties of molecules and atoms and their constituents--electrons, protons, neutrons, and other more esoteric particles such as quarks and gluons. Its concepts frequently conflict with common-sense notions derived from observations of the everyday world. Quantum mechanics has attracted some of the ablest scientists of the 20th century, and they have erected what is perhaps the finest intellectual edifice of the period. Quantum mechanics is concerned with phenomena that are so small-scale that they cannot be described in classical terms. The history of quantum mechanics may be divided into three main periods. The first began with Planck's theory of black-body radiation in 1900; it may be described as the period in which the validity of Planck's constant was demonstrated but its real meaning was not fully understood. The second period began with the quantum theory of atomic structure and spectra proposed by Niels Bohr in 1913. True quantum mechanics appeared in 1926, reaching fruition nearly simultaneously in a variety of forms--namely, the matrix theory of Max Born and Werner Heisenberg, the wave mechanics of Louis V. de Broglie and Erwin Schrodinger, and the transformation theory of P.A.M. Dirac and Pascual Jordan.