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Springer eBooks

Spherically Symmetric Potentials Hydrogen Atom Problem, Rotation Vibration Spectra, Three-Dimensional Oscillator

Ajoy Kumar Ghatak, S. Lokanathan

Published Jan 1, 2004• 0 citations
Publisher
DOI
10.1007/978-1-4020-2130-5_10

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Three-Dimensional Problem: Spherically Symmetric Potential and Orbital Angular Momentum

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The Solvable and the Symmetric: A Narrative Review of Exactly Solvable Quantum Systems, from the Oscillator to Supersymmetric Factorization

Zen Revista, 10 PHYSICS

The exactly solvable systems---the harmonic oscillator, the hydrogen atom, and the angular momentum algebra---are quantum mechanics' solved ground: the spectra computed in closed form that calibrated the theory, taught its methods, and revealed the symmetries that make solvability itself a theorem. This article presents a narrative review of the primary literature of that ground, from de Broglie's 1924 thesis---the wave hypothesis the solvable problems confirmed---through Heisenberg's 1925 umdeutung, Schrödinger's 1926 eigenvalue problem, whose oscillator and rotator opened the solvable list, Dirac's 1926 theory of quantum mechanics and Pauli's 1926 hydrogen solution by the new algebra, Darwin's 1927 vector waves, Dirac's 1928 electron---the relativistic hydrogen's fine structure---Wigner's 1931 group theory and its application to the atomic spectra, Condon and Shortley's 1935 atomic spectra canon, Fock's 1935 hydrogen symmetry---the O(4) hidden behind the spectrum---to the factorization method's systematization in Infeld and Hull's 1951 review and its supersymmetric completion in Cooper, Khare, and Sukhatme's 1995 physics reports. The synthesis is organized around three themes: the solved spectra, in which the oscillator's and hydrogen's levels fixed the new mechanics' validity; the hidden symmetries, in which Runge-Lenz and spherical symmetry explained the solvabilities; and the factorization program, in which the ladder operators' algebra became a method---the exactly solvable potentials classified. It is concluded that the solvable systems are quantum mechanics' load-bearing examples---and that their symmetries remain the theory's deepest explanation of why some problems close.

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Introductory Quantum Mechanics

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Part 1: the need for the quantum mechanics quantization of radiation the special theory of relativity wave-particle duality the nature of matter waves the uncertainty principle the Bohr atom. Part 2 Schrodinger's equation: the postulates of quantum mechanics the wave equation the wave equation in three dimensions the time-independent Schrodinger equation stationary states normalisation probability flux physical constraints on the wave-function wave packets Gaussian wave-packets and the uncertainty principle. Part 3 One-dimensional potential wells: potential wells the one-dimensional infinite square well discussion of infinite square-well results eigenvalue equations the finite square well finite square well eigenfunctions the control of the wave-function by the wave equation numerical integration of Schrodinger's equation continuum solutions of the square-well potential interpretation of unbound-particle wave functions the double potential well the quantum bouncer electric fields and the tilted well the harmonic oscillator - introduction the quantum oscillator discussion of harmonic oscillator eigenvalues and eigenfunctions the classical probability density more potential wells. Part 4 Schrodinger's equation in three dimensions: particle in a three dimensional box degeneracy Schrodingers equation in spherical polar coordinates - the hydrogen atom normalisation. Part 5 Formal development of quantum mechanics: eigenvalues equations, operators and measurements the momentum operator, eigenvalues and eigenfunctions the position operator and its eigenfunctions Hermitian operators orthogonality of eigenfunctions the expansion postulate example - the b-decay of tritium expectation values compatibility of observables - commutators non-commuting operators time-dependence of expectation values - Ehrenfest's theorem abstract operators - the parity operator, matrix mechanics. Part 6 Angular momentum: angular momentum operators angular momentum commutators angular momentum eigenvalues and eigenfunctions interpretation of angular momentum eigenvalues interpretation of angular momentum eigenfunctions the Stern-Gerlach apparatus and electron spin spin operators - the Pauli Spin matrices the Zeeman effect measurements in quantum mechanics. Part 7 Spherically symmetric potential wells: the rigid rotator the radial equation the hydrogen atom and hydrogen like ions the isotropic harmonic oscillator molecular vibrations - the Morse potential the spherical square well general properties of spherically symmetric potential wells. (Part contents)

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Applications of the Formalism-II

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In this chapter, the authors solve the Schrodinger equation for a harmonic oscillator using two methods, analytical method and algebraic method. They discuss the quantum properties of the harmonic oscillator. A harmonic oscillator is a system that exhibits simple harmonic motion or periodic motion, a motion that repeats itself after equal intervals of time. Many systems such as spring, simple pendulum, vibrating string and molecular vibration can be approximated as simple harmonic oscillators. The authors consider a simple harmonic oscillator, a spring whose spring constant is "k" attached to a mass "m" as a simple harmonic oscillator. They describe the Schrodinger equation in spherical coordinates. The authors also solve the three-dimensional Schrodinger equation for the hydrogen atom. For the hydrogen atom, the potential energy function is dependent only on radial distance and is independent of angular variables. The hydrogen atom consists of a positively charged proton surrounded by an electron that orbits around it.

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Spherical Symmetrical Potentials: Generalities

WORLD SCIENTIFIC eBooks•Mar 1, 2023•0 citations
The exactly solvable systems---the harmonic oscillator, the hydrogen atom, and the angular momentum algebra---are quantum mechanics' solved ground: the spectra computed in closed form that calibrated the theory, taught its methods, and revealed the symmetries that make solvability itself a theorem. This article presents a narrative review of the primary literature of that ground, from de Broglie's 1924 thesis---the wave hypothesis the solvable problems confirmed---through Heisenberg's 1925 umdeutung, Schrödinger's 1926 eigenvalue problem, whose oscillator and rotator opened the solvable list, Dirac's 1926 theory of quantum mechanics and Pauli's 1926 hydrogen solution by the new algebra, Darwin's 1927 vector waves, Dirac's 1928 electron---the relativistic hydrogen's fine structure---Wigner's 1931 group theory and its application to the atomic spectra, Condon and Shortley's 1935 atomic spectra canon, Fock's 1935 hydrogen symmetry---the O(4) hidden behind the spectrum---to the factorization method's systematization in Infeld and Hull's 1951 review and its supersymmetric completion in Cooper, Khare, and Sukhatme's 1995 physics reports. The synthesis is organized around three themes: the solved spectra, in which the oscillator's and hydrogen's levels fixed the new mechanics' validity; the hidden symmetries, in which Runge-Lenz and spherical symmetry explained the solvabilities; and the factorization program, in which the ladder operators' algebra became a method---the exactly solvable potentials classified. It is concluded that the solvable systems are quantum mechanics' load-bearing examples---and that their symmetries remain the theory's deepest explanation of why some problems close.
Part 1: the need for the quantum mechanics quantization of radiation the special theory of relativity wave-particle duality the nature of matter waves the uncertainty principle the Bohr atom. Part 2 Schrodinger's equation: the postulates of quantum mechanics the wave equation the wave equation in three dimensions the time-independent Schrodinger equation stationary states normalisation probability flux physical constraints on the wave-function wave packets Gaussian wave-packets and the uncertainty principle. Part 3 One-dimensional potential wells: potential wells the one-dimensional infinite square well discussion of infinite square-well results eigenvalue equations the finite square well finite square well eigenfunctions the control of the wave-function by the wave equation numerical integration of Schrodinger's equation continuum solutions of the square-well potential interpretation of unbound-particle wave functions the double potential well the quantum bouncer electric fields and the tilted well the harmonic oscillator - introduction the quantum oscillator discussion of harmonic oscillator eigenvalues and eigenfunctions the classical probability density more potential wells. Part 4 Schrodinger's equation in three dimensions: particle in a three dimensional box degeneracy Schrodingers equation in spherical polar coordinates - the hydrogen atom normalisation. Part 5 Formal development of quantum mechanics: eigenvalues equations, operators and measurements the momentum operator, eigenvalues and eigenfunctions the position operator and its eigenfunctions Hermitian operators orthogonality of eigenfunctions the expansion postulate example - the b-decay of tritium expectation values compatibility of observables - commutators non-commuting operators time-dependence of expectation values - Ehrenfest's theorem abstract operators - the parity operator, matrix mechanics. Part 6 Angular momentum: angular momentum operators angular momentum commutators angular momentum eigenvalues and eigenfunctions interpretation of angular momentum eigenvalues interpretation of angular momentum eigenfunctions the Stern-Gerlach apparatus and electron spin spin operators - the Pauli Spin matrices the Zeeman effect measurements in quantum mechanics. Part 7 Spherically symmetric potential wells: the rigid rotator the radial equation the hydrogen atom and hydrogen like ions the isotropic harmonic oscillator molecular vibrations - the Morse potential the spherical square well general properties of spherically symmetric potential wells. (Part contents)
In this chapter, the authors solve the Schrodinger equation for a harmonic oscillator using two methods, analytical method and algebraic method. They discuss the quantum properties of the harmonic oscillator. A harmonic oscillator is a system that exhibits simple harmonic motion or periodic motion, a motion that repeats itself after equal intervals of time. Many systems such as spring, simple pendulum, vibrating string and molecular vibration can be approximated as simple harmonic oscillators. The authors consider a simple harmonic oscillator, a spring whose spring constant is "k" attached to a mass "m" as a simple harmonic oscillator. They describe the Schrodinger equation in spherical coordinates. The authors also solve the three-dimensional Schrodinger equation for the hydrogen atom. For the hydrogen atom, the potential energy function is dependent only on radial distance and is independent of angular variables. The hydrogen atom consists of a positively charged proton surrounded by an electron that orbits around it.