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Mathematical Notes

Statistical Transition of Bose Gas to Fermi Gas

Виктор Павлович Маслов

Published May 1, 2018• 6 citations
Publisher

Abstract

It is well known that the formula for the Fermi distribution is obtained from the formula for the Bose distribution if the argument of the polylogarithm, the activity a, the energy, and the number of particles change sign. The paper deals with the behavior of the Bose–Einstein distribution as a → 0; in particular, the neighborhood of the point a = 0 is studied in great detail, and the expansion of both the Bose distribution and the Fermi distribution in powers of the parameter a is used. During the transition from the Bose distribution to the Fermi distribution, the principal term of the distribution for the specific energy undergoes a jump as a → 0. In this paper,we find the value of the parameter a, close to zero, but not equal to zero, for which the Bose distribution (in the statistical sense) becomes zero. This allows us to find the point a , distinct from zero, at which a jump of the specific energy occurs. Using the value of the number of particles on the caustic, we can obtain the jump of the total energy of the Bose system to the Fermi system. Near the value a = 0, the author uses Gentile statistics, whichmakes it possible to study the transition fromthe Bose statistics to the the Fermi statistics in great detail. Here an important role is played by the self-consistent equation obtained by the author earlier.

DOI
10.1134/s0001434618050292

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It is well known that the formula for the Fermi distribution is obtained from the formula for the Bose distribution if the argument of the polylogarithm, the activity a, the energy, and the number of particles change sign. The paper deals with the behavior of the Bose–Einstein distribution as a → 0; in particular, the neighborhood of the point a = 0 is studied in great detail, and the expansion of both the Bose distribution and the Fermi distribution in powers of the parameter a is used. During the transition from the Bose distribution to the Fermi distribution, the principal term of the distribution for the specific energy undergoes a jump as a → 0. In this paper,we find the value of the parameter a, close to zero, but not equal to zero, for which the Bose distribution (in the statistical sense) becomes zero. This allows us to find the point a , distinct from zero, at which a jump of the specific energy occurs. Using the value of the number of particles on the caustic, we can obtain the jump of the total energy of the Bose system to the Fermi system. Near the value a = 0, the author uses Gentile statistics, whichmakes it possible to study the transition fromthe Bose statistics to the the Fermi statistics in great detail. Here an important role is played by the self-consistent equation obtained by the author earlier.
The properties of the ideal Bose gas are calculated from the integral equations for the energy and the number of particles as a function of the temperature and chemical potential. It is shown that the integral equations break down below the Einstein temperature that corresponds to the transition to the low-temperature state. The lowest single-particle energy level must be treated explicitly to get the proper equations. With the inclusion of the lowest single-particle energy level, the low-temperature behavior is calculated. The occupation of the lowest level becomes comparable to the total number of particles in the system below the Einstein temperature, and equal to the total number of particles at zero temperature. A numerical solution to the properties of the Bose gas is discussed, and the detailed calculations are assigned to the problems at the end of the chapter.
Abstract The Bose-Einstein condensation of a gas is investigated. Starting from the well-known formulae for Bose statistics, the problem has been generalized to include a variety of potential fields in which the particles of the gas move, and the number w of dimensions has not been restricted to three. The energy levels are taken to be εi≡εs1,....,s10=constanth2ms1α−1a12+...+swαaw2(1≤α≤2) the quantum numbers being s1 ,w= 1, 2, ..., and a1, ..., aw being certain characteristic lengths. (For α = 2, the potential field is that of the w-dimensional rectangular box; for α = 1, we obtain the w-dimensional harmonic oscillator field.) A direct rigorous method is used similar to that proposed by Fowler & Jones (1938). It is shown that the number q = w/α determines the appearance of an Einstein transition temperature T0·For q≤ 1 there is no such point, while for q > 1 a transition point exists. For 1 < q≤ 2, the mean energy ϵ- per particle and the specific heat dϵ-/dT are continuous at T = T0· For q > 2, the specific heat is discontinuous at T = T0, giving rise to a A λ-point. A well-defined transition point only appears for a very large (theoretically infinite) number N of particles. T0 is finite only if the quantity v = N/(a1 .... aw)2/ α¯is finite. For a rectangular box, v is equal to the mean density of the gas. If v tends to zero or infinity as N→ ∞, then T0 likewise tends to zero or infinity. In the case q > 1, and at temperatures T < T 0' there is a finite fraction N0 /N of the particles, given by N 0/N = 1-(T/T0)q, in the lowest state. London’s formula (1938 b) for the three-dimensional box is an example of this equation. Some further results are also compared with those given by London’s continuous spectrum approximation.
The number-theoretical problem of partition of an integer corresponds to D=2D=2D=2. This problem obeys the Bose--Eeinstein statistics, where repeated terms are admissible in the partition, and to the Fermi--Dirac statistics, where they are inadmissible. The Hougen--Watson P,Z-diagram shows that this problem splits into two cases: the positive pressure domain corresponds to the Fermi system, and the negative, to the Bose system. This analogy can be applied to the van der Waals thermodynamics. The thermodynamic approach is related to four potentials corresponding to the energy, free energy, thermodynamic Gibbs potential, enthalpy. The important notion of de Broglie's wavelength permits passing from particle to wave packet, in particular, to Bose and Fermi distributions. Particles of ideal Bose and Fermi gases and the decay of a boson consisting of two fermions into separate fermions are studied. The case of finitely many particles NNN of the order of 10210^2102 is considered by heuristic considerations like those Fock used to derive the Hartree--Fock equation. The case of N≪1N\ll1N≪1 is studied by Gentile statistics, tropical geometry and nonstandard analysis (Leibnitz differential or monad). A relation for the energy of neutron separation from the atomic nucleus is obtained when the atomic nucleus volume and de Broglie's wavelength are known. The Appendix is author's paper written in 1995.
Bose gases and Fermi gases represent two fundamental particle systems in statistical mechanics, governed by Bose-Einstein and Fermi-Dirac distributions, respectively. This paper provides a comprehensive analysis of the thermodynamic quantities, phase transitions, chemical potentials, and energy level relationships of these gases. The study utilizes Laurent series expansions and group theory analysis to explore the statistical properties and behavior of Bose and Fermi gases under various conditions. Additionally, the paper derives a new energy-mass equation based on metric and curvature RRR.
By expanding the grand partition function, we obtain the expression for partition function of two dimensional free particles which is seen to be of the same form as that of one dimensional harmonic oscillators. For such systems it is shown that the difference in statistics does not appear in thermal behavior. When the energy levels of the particles are modified as ε n 1 , n 2 = Δ + b ( n 1 2 + n 2 2 ), Δ >0, the Bose condensation occurs and, if we set Δ =2 b , the condensation temperature qualitatively agrees with that of Osborne. The speciffic heat of free Bosons in a narrow box is calculated as the function of temperature, its width d being taken 7.1 Å and 14.2 Å. The results show that the maximum of the specific heat occurs at higher temperatures than that of the case d =∞, and its height becomes lower. The weak excitation of a Fermi system can be treated as excitons which obey Bose statistics. And we can show, by the method analogous to that of Ward and Wilks and Dingle, that the sound wave in a Fermi gas should be considered as the second sound, or the propagation of fluctuation in exciton distribution. Its propagation velocity is shown to become p0/3mp_{0}/\sqrt{3}mp0​/3​m, where p 0 is the momentum at the Fermi surface.
The topic of Bose–Einstein condensation in a uniform, non-interacting gas of bosons is treated in most textbooks on statistical mechanics. In the present chapter we discuss the properties of a non-interacting Bose gas in a trap. We shall calculate equilibrium properties of systems in a semi-classical approximation, in which the energy spectrum is treated as a continuum. For this approach to be valid the temperature must be large compared with Δ∊/ k , where Δ∊ denotes the separation between neighbouring energy levels. As is well known, at temperatures below the Bose–Einstein condensation temperature, the lowest-energy state is not properly accounted for if one simply replaces sums by integrals, and it must be included explicitly. The statistical distribution function is discussed in Sec. 2.1, as is the single-particle density of states, which is a key ingredient in the calculations of thermodynamic properties. Calculations of the transition temperature and the fraction of particles in the condensate are described in Sec. 2.2. In Sec. 2.3 the semi-classical distribution function is introduced. From this we obtain the density profile and the velocity distribution of particles, and use these to determine the shape of an anisotropic cloud after free expansion. Thermodynamic properties of Bose gases are calculated as functions of the temperature in Sec. 2.4. Finally, Sec. 2.5 treats corrections to the transition temperature due to a finite particle number.