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Physical Review A

Quantum master equation with dissipators regularized by thermal fluctuations

Arnab Chakrabarti, Rangeet Bhattacharyya

Published Jun 18, 2018• 15 citations
Publisher

Abstract

We report an alternate formulation of the quantum master equation (QME) to describe the dynamics of a quantum system weakly coupled to a heat bath, in the presence of weak external driving. A key feature of this approach is the introduction of an explicit Hamiltonian to model the thermal fluctuations in the heat bath. We show that the resulting time coarse-grained dynamical equation for the quantum system has dissipators with a natural regulator, which emerges from an ensemble average over the fluctuations. Importantly, such regularized dissipators arise from the second-order contributions of both the external drive as well as the system-environment coupling. We show that the second-order drive terms, regularized to time-scales set by the fluctuations, result in dynamic drive-induced frequency shifts as well as drive-dependent relaxation phenomena. Considering the specific case of an ensemble of two-level systems, subjected to a linearly polarized external drive, we derive the modified Bloch Equations with such drive-dependent shift and damping terms. The resulting drive-induced frequency shifts converge to the known forms of dynamic frequency shifts, such as the Bloch-Siegert shift or the dynamic Stark shift, in appropriate limits. The Kramers-Kronig pairs of these frequency shifts - manifest as drive-dependent damping terms in the modified Bloch Equations and help explain the Redfield limit of free-induction-decay (FID) rates as well as the non-Bloch decay of Rabi oscillations in isotropic medium. Our method predicts correct orders of magnitudes of non-Bloch decay rates in isotropic medium as well as their observed temperature dependence. The QME reported here, correctly describes all known aspects of the driven-dissipative dynamics up to second-order of an open quantum system with appropriate thermal signatures and as such is expected to provide deeper insights into the study of quantum information processing on real systems.

DOI
10.1103/physreva.97.063837

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We report an alternate formulation of the quantum master equation (QME) to describe the dynamics of a quantum system weakly coupled to a heat bath, in the presence of weak external driving. A key feature of this approach is the introduction of an explicit Hamiltonian to model the thermal fluctuations in the heat bath. We show that the resulting time coarse-grained dynamical equation for the quantum system has dissipators with a natural regulator, which emerges from an ensemble average over the fluctuations. Importantly, such regularized dissipators arise from the second-order contributions of both the external drive as well as the system-environment coupling. We show that the second-order drive terms, regularized to time-scales set by the fluctuations, result in dynamic drive-induced frequency shifts as well as drive-dependent relaxation phenomena. Considering the specific case of an ensemble of two-level systems, subjected to a linearly polarized external drive, we derive the modified Bloch Equations with such drive-dependent shift and damping terms. The resulting drive-induced frequency shifts converge to the known forms of dynamic frequency shifts, such as the Bloch-Siegert shift or the dynamic Stark shift, in appropriate limits. The Kramers-Kronig pairs of these frequency shifts - manifest as drive-dependent damping terms in the modified Bloch Equations and help explain the Redfield limit of free-induction-decay (FID) rates as well as the non-Bloch decay of Rabi oscillations in isotropic medium. Our method predicts correct orders of magnitudes of non-Bloch decay rates in isotropic medium as well as their observed temperature dependence. The QME reported here, correctly describes all known aspects of the driven-dissipative dynamics up to second-order of an open quantum system with appropriate thermal signatures and as such is expected to provide deeper insights into the study of quantum information processing on real systems.
Drive-induced shifts, such as ac Stark shift and Bloch-Siegert shift, are routinely used in various spectroscopies. These shifts are experimentally known to show dispersive Lorentzian behavior as a function of its characteristic frequencies in optical pumping experiments. However, the drive-induced Stark shifts, as calculated using Floquet or dressed atom approaches, do not show the above nonlinear behavior. To address this, we theoretically investigated the drive-induced shifts using a previously reported fluctuation-regulated quantum master equation [A. Chakrabarti and R. Bhattacharyya, Phys. Rev. A 97, 063837 (2018)]. The shifts are obtained as closed-form expressions over the entire detuning range of the drive. The predicted shifts match satisfactorily with the known experimental data of the light shifts. We show that the calculated shifts are a Kramers-Kronig pair of the drive-induced dissipation in conformity with experimental findings. Moreover, we show that at low temperatures, i.e., for less thermal fluctuations, our results asymptotically match with the known theoretical form of the shifts. In the high-temperature regime, we predict that the shifts decrease in magnitude and are inversely proportional to the square of the temperature.
We construct a quantum Markovian master equation for a driven system coupled to a thermal bath. The derivation utilizes an explicit solution of the propagator of the driven system. This enables the validity of the master equation to be extended beyond the adiabatic limit. The nonadiabatic master equation (NAME) is derived employing the weak system-bath coupling limit. The NAME is valid when a separation of timescales exists between the bath dynamics and the external driving. In contrast to the adiabatic master equation, the NAME leads to coupled equations of motion for the population and coherence. We employ the NAME to solve the example of an open driven time-dependent harmonic oscillator. For the harmonic oscillator the NAME predicts the emergence of coherence associated with the dissipation term. As a result of the nonadiabatic driving the thermalization rate is suppressed. The solution is compared with both numerical calculations and the adiabatic master equation.
We present a non-equilibrium quantum master equation for a driven open quantum system in the presence of a continuously applied electromagnetic field. Starting from a driven Caldeira-Leggett (CL) model in which the external electromagnetic field couples simultaneously to the subsystem and reservoir degrees of freedom, the canonical fluctuation-dissipation theorem (FDT) relations that encode the coefficients of the master equation can no longer be expected to hold. The bath statistics acquire an explicit dependence on the two-time autocorrelation function of the applied field, leading to drive-biased noise correlations and the potential for non-Markovian dynamics. By eliminating the reservoir degrees of freedom at the operator level, we obtain a modified Hu-Paz-Zhang (HPZ) master equation, in which the diffusion coefficients and coherent forces inherit an explicit memory dependence on the external field. We demonstrate that the physically observable resonant frequency remains encoded in the homogeneous Green's function of the Generalized Langevin equation (GLE), while the drive-induced corrections manifest exclusively through modified diffusion and drift terms, should the drive be treated classically. The resultant field-modified HPZ master provides a unified microscopic framework for understanding field-biased open quantum systems with direct pertinence to a wide variety of experiments in quantum optics and microscopic quantum circuits.
Abstract Optical Bloch equations (OBE) describe the coherent exchange of energy between a quantum bit (qubit) and a quasi-resonant driving field in the presence of a thermal bath. Despite it being an ubiquitous process in quantum technologies, a sound thermodynamic analysis is still missing. We hereby provide such an analysis, by deriving the relevant framework from first principles. We start from a complete microscopic description of the qubit-bath system where definitions of heat, work and entropy production are unambiguous. We trace out the bath and coarse-grain the resulting expressions in time, using a methodology similar to the derivation of the dynamical master equation, to derive closed expressions for the first and second law in terms of system properties. Long coarse graining times yield the Floquet Master equation and its already known thermodynamic description. Short coarse-graining times yield instead the OBE and a novel thermodynamic framework which explicitly depends on quantum coherences in the qubit’s energy basis which produce quantum signatures in the heat and entropy production flows. This allows us to characterize a genuinely quantum non-equilibrium situation, where the coherences created by the driving field are continuously erased by the bath. Our findings can be readily extended to larger open quantum systems. They carry the seeds for future thermodynamic analyses of quantum gates and the design of quantum engines in the strong coherent driving regime.
Driven-dissipative qubit-resonator dynamics, which are the basis of most dispersive superconducting qubit measurement schemes, are often modeled with Lindblad master equations built from subsystem local jump operators, even when the qubit and resonator are appreciably hybridized. In this work we revisit this setting using a microscopic Bloch-Redfield approach, where dissipation is constructed in the eigenbasis of the coupled qubit-resonator Hamiltonian with a complete, frequency dependent, open system description of the transmission line environment. Here, we show that the Lindblad and Bloch-Redfield decay rates can be quantitatively different in the absence of driving, while in the driven case we demonstrate that the time-independent Redfield dissipator and its time-dependent generalization can show qualitatively different behaviors as a function of driving strength. Finally, we investigate the effects of driving in structured spectral densities, recovering the suppression of measurement-induced relaxation in the presence of a so called Purcell filter.
A qubit--harmonic-oscillator open system coupled to thermal baths was considered and the master equation describing the evolution of the open system was deduced when the qubit transition frequency is $\ensuremath{\lesssim}0.1$ the oscillator frequency. The master equation is valid in all the qubit-oscillator state space and holds for all values of the qubit-oscillator coupling including the ultrastrong and deep strong coupling regimes. It only requires an oscillator frequency much larger than the relaxation rates. The qubit-oscillator coupling can enhance or decrease both the relaxation rates and the frequency shifts induced by the thermal baths. It was found that weak, sinusoidal qubit driving forces the qubit-oscillator open system to behave like a driven qubit whose evolution is governed by equations similar to those of the Bloch vector in the optical Bloch equations and whose transition frequency decreases with increasing qubit-oscillator coupling strength. Finally, it was shown how one can reach the adiabatic regime by using sinusoidal qubit driving with large driving frequency and the concepts of $\ensuremath{\pi}$ and $\ensuremath{\pi}/2$ pulses were generalized to manipulate transitions between dressed states.