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Journal of Modern Physics

Quantum Effect on Elementary Process of Diffusion and Collective Motion of Brown Particles

Takahisa Okino

Published Jan 1, 2018• 5 citations
Publisher

Abstract

The correlation between the Schrödinger equation and the diffusion equation revealed that the relation of material wave is not a hypothesis but an actual one valid in a material regardless of the photon energy. Using the relations of material wave and uncertain principle, the quantum effect on elementary process of diffusion is discussed. As a result, the diffusivity is obtained as a universal expression applicable to any problem of diffusion phenomena. The Gauss theorem in theory and the Kirkendall effect in experimentation reveal the necessity of the coordinate transformation for a diffusion equation. The mathematical method for solving an interdiffusion problem of many elements system is established. The phase shift of the obtained analytical solution indicates the correlation between the solutions of each diffusion equation expressed by a fixed coordinate system and by a moving coordinate system. Based on the coordinate transformation theory, some unsolved problems of diffusion theory are reasonably solved and also some new important findings are discussed in relation to matters in the existing diffusion theory.

DOI
10.4236/jmp.2018.95063

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The correlation between the Schrödinger equation and the diffusion equation revealed that the relation of material wave is not a hypothesis but an actual one valid in a material regardless of the photon energy. Using the relations of material wave and uncertain principle, the quantum effect on elementary process of diffusion is discussed. As a result, the diffusivity is obtained as a universal expression applicable to any problem of diffusion phenomena. The Gauss theorem in theory and the Kirkendall effect in experimentation reveal the necessity of the coordinate transformation for a diffusion equation. The mathematical method for solving an interdiffusion problem of many elements system is established. The phase shift of the obtained analytical solution indicates the correlation between the solutions of each diffusion equation expressed by a fixed coordinate system and by a moving coordinate system. Based on the coordinate transformation theory, some unsolved problems of diffusion theory are reasonably solved and also some new important findings are discussed in relation to matters in the existing diffusion theory.
Since a material is composed of micro particles, investigating behavior of those particles is essentially dominant for materials science. The diffusivity of diffusion equation is relevant to not only a collective motion of micro particles but also a motion of single particle. An elementary process of diffusion was thus theoretically investigated in a local space and time. As a result, the investigation concluded that the wave nature of micro particle results from denying the mathematical density theorem of a real time in the Newton mechanics. In other words, the basic theory of quantum mechanics is established in accordance with the cause-and-effect relationship in the Newton mechanics, for the first time, regardless of the de Broglie hypothesis. In relation to the collective motion of micro particles, the new diffusion theory was also reasonably established using the universal expression of diffusivity obtained here. In the present paper, the new findings indispensable for the fundamental knowledge in physics are thus systematically discussed in accordance with the theoretical frame in physics.
Investigating the elementary process of diffusion revealed that the De Broglie hypothesis is really valid in a material and further that the Schrödinger equation is reasonably derived from the diffusion equation. The diffusion equation is thus one of the fundamental equations in physics. The problem between a moving coordinate system and a fixed coordinate system for the diffusion equation had never been discussed until recently in the history of diffusion theory. In that situation, it is revealed that investigating the problem between those coordinate systems is indispensable for understanding the diffusion phenomena. The new findings obtained here, which are revolutionary in the existing diffusion theory, will be not only dominant but also indispensable for further advance in the diffusion study.
Investigating the elementary process of diffusion yielded the universal expression of diffusivity relevant to the angular momentum of each microparticle in a material. Using the diffusivity obtained then for the diffusion equation, the wave equation of Schrödinger was theoretically derived from the physical concept in Newton mechanics. The derivation itself reveals that any moving microparticle has the wave image as an intrinsic nature. It was theoretically revealed that the relation having been accepted as a hypothesis proposed by De Broglie is valid for any moving microparticle and that another relation of matter-wave is possible. The new diffusion theory based on the matter-wave will be useful for further development of the nanotechnology in materials science.
The theory of non-dissipative diffusion is constructed on an example of diffusion of a light particle in a dilute medium of heavy particles and it is shown that in low dissipative systems there are specific effects of non-dissipativity similar to quantum effects.In a non-dissipativity region mean energy of the light particle is conserved and processes are described by two non-linear diffusion equations with forward and backward time derivatives.Then these two diffusion equations are linearized and give one linear Schrödinger equation for complex amplitudes of probability.As a result, in the non-dissipative classical diffusion should be added probability amplitudes and there holds the superposition principle for these amplitudes.A mean square length of free passage and a mean square momentum define an elementary phase volume and a diffusion constant and they obey the uncertainty relations.It is shown that the formalism of quantum mechanics describes the classical non-dissipative diffusion with a homogeneous diffusion constant and that quantum mechanics is only a particular case when the elementary phase volume of free passage is universal and equal to the Planck constant.
The relation of matter wave, which is well-known as a hypothesis proposed by de Broglie in 1923, gave basis for establishing the quantum mechanics. After that, experimental results revealed that a micro particle has a wave nature. However, the theoretical validity of the relation itself has never been revealed since his proposal. Theoretical basis that a micro particle has a wave nature has been thus disregarded in the unsolved state. The diffusion equation having been accepted as Fick’s second law was derived from the theory of Markov process in mathematics. It was then revealed that the diffusivity D depends on an angular momentum of a micro particle in a local space. The fact being unable to discriminate between micro particles in a local space resulted in having to accept the existence of minimum time t0 (>0) in the quantum mechanics. Based on t0 and D obtained here, the theoretical validity of relation of matter wave was confirmed. Denying the density theorem in mathematics for time in physics indicates that the probabilistic interpretation is essentially indispensable for understanding the quantum mechanics. The logical necessity of quantum theory itself is thus understandable through introducing t0 into the Newton mechanics. It is remarkable that the value of t0 between 1.14×10-17 s ≤ t0 ≤1.76×10-14 s obtained here is extremely larger than that of the well-known Planck time tp=5.396×10-44 s.