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Journal of Experimental and Theoretical Physics

On the Energy of a “Two-Dimensional” Two-Electron Atom

В. В. Скобелев

Published Dec 1, 2017• 9 citations
Publisher

Abstract

With the use of the known solution of the Schrödinger equation for an electron in the nucleus field in the polar coordinates, the energy of a “two-dimensional” two-electron atom in the ground state, as well as its single ionization energy, has been calculated both in perturbation theory and with an almost century-old method of variation of the parameter Z in a trial wavefunction of the ground state. Since such two-dimensional atoms, e.g., helium atoms, can in principle be implemented in experiments by “freezing” of one degree of freedom in the phase of Bose–Einstein condensate, the conclusions made in this work can be tested. Fundamental features of the calculation of the energy of “one-dimensional” two-electron atoms and the formation of their Bose–Einstein condensate have also been discussed. The results obtained in this work coincide in a number of particular cases with the results obtained in a previous work, where some results were absent.

DOI
10.1134/s1063776117120081

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With the use of the known solution of the Schrödinger equation for an electron in the nucleus field in the polar coordinates, the energy of a “two-dimensional” two-electron atom in the ground state, as well as its single ionization energy, has been calculated both in perturbation theory and with an almost century-old method of variation of the parameter Z in a trial wavefunction of the ground state. Since such two-dimensional atoms, e.g., helium atoms, can in principle be implemented in experiments by “freezing” of one degree of freedom in the phase of Bose–Einstein condensate, the conclusions made in this work can be tested. Fundamental features of the calculation of the energy of “one-dimensional” two-electron atoms and the formation of their Bose–Einstein condensate have also been discussed. The results obtained in this work coincide in a number of particular cases with the results obtained in a previous work, where some results were absent.
The theory of Bose-Einstein condensation in a two-dimensional(2D) harmonic trap is developed from 2D Gross-Pitaevskii equation. The 2D interaction strength is obtained from a 2D collision theory. We show the realization of 2D condensation of trapped Bose atoms directly by obtaining the stable solutions for the condensate wave function from the 2D Gross-Pitaevskii equation. We calculate the ground-state energy of the 2D system, and also the wave function of the 2D vortex state. In particular, the 2D energy state becomes less stable than the 3D case with the number of trapped atoms. The results of the 2D Bose condensation are also compared with those of the well-known 3D case.
We present a two-dimensional analysis of the two-electron problem which comes from the classical conservation theorems and from which we obtain a version of the Dirac equation for the helium atom. Approximate solutions for this equation are discussed in two different methods, although in principle it can be solved analytically. One method is variational, of the Hylleraas type, the execution of which is left for a later communication. In contrast, the other method will have a more complete treatment, in which the set of equations will be separated into its angular and radial components. Furthermore, an exact solution for the angular component will be displayed as well as an approximate solution for the radial component, valid only for the fundamental state of the atom.
Abstract This chapter reiterates the quantum numbers for atomic orbitals, known from general chemistry, and places them into the context developed so far. It is sketched how the Schrodinger equation (SE) for the hydrogen atom hydrogen-like systems (one electron plus a nucleus of charge Z) is set up. When the nucleus is treated as a fixed point charge, the SE is only for the electron. The solutions of the SE can be obtained by switching to spherical polar coordinates, such that the variables are separable in terms of the electron distance from the nucleus, r, and two angles. The kinetic energy of the electron then has a radial component, and an angular component. The latter is associated with the angular momentum quantum number, which is codified by the letters s, p, d, f, and so forth. A step by step solution of the SE is provided later, in chapter 19.
An important technique for teaching introductory wave mechanics is provided by the numerical calculation of stationary state solutions of the Schrödinger equation. Realistic problems in wave mechanics that do not require sophisticated computer techniques are very valuable for the instruction of undergraduates. In the central-field model for atoms, the calculation of electron states reduces to the solution of a one-dimensional differential equation whose numerical solutions are no more difficult to obtain than those for a finite square well. A method used by our students is discussed in this paper for the calculation of the electron wavefunctions in a central-field potential. By working this problem, students obtain meaningful results that give them insight into the theory of atomic structure. Results of their experience are included, and possibilities of extending this example are discussed.
A simple, "exactly solvable" atomic model will be presented that helps to discuss some of the interesting features of multiphoton ionization of atoms. The electromagnetic field is treated non-perturbatively, it can be strong. The atomic electrons are assumed to be non-interacting (Hartree model). They are bound in a harmonic oscillator potential (one- or three-dimensional). At the ionization energy, the potential is cut off and the free electron has no Coulomb attraction. The Schrodinger equation has exact analytic solutions valid in the inner or outer regions. If the field is turned on adiabatically, the exact solution can be found by matching these solutions at the boundary; both of their value and the normal derivative at all times. Thus the machine calculation reduces to repeated application of fast Fourier transforms and to the solution of linear equations (unfortunately a lot of them).
Abstract:   The well-known variation method of calculating the total energy of a two-electron atom is generalized to the case of any set of quantum numbers of electrons in spaces of three or fewer dimensions, yielding the corresponding expressions for energy and screening constant. From these results, the particular cases of the basic and the lowest excited states follow, as earlier considered by us and other authors. We clarify the correct use of these results. Moreover, we generalize the standard relations connecting the average values of kinetic and potential energy with the total energy of an electron in a nucleus field in three dimension for any quantum state and extend it to subspaces of one and  two dimensions in a three-dimensional space. The results of this work could be a useful addition to a university course on quantum mechanics.