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Identical Particles and Second Quantization: Occupation Number Representation

Norman J. M. Horing

Published Jul 27, 2017• 0 citations
Publisher

Abstract

Abstract Focusing on systems of many identical particles, Chapter 2 introduces appropriate operators to describe their properties in terms of Schwinger’s “measurement symbols.” The latter are then factorized into “creation” and “annihilation” operators, whose fundamental properties and commutation/anticommutation relations are derived in conjunction with the Pauli exclusion principle. This leads to “second quantization” with the Hamiltonian, number, linear and angular momentum operators expressed in terms of the annihilation and creation operators, as well as the occupation number representation. Finally, the concept of coherent states, as eigenstates of the annihilation operator, having minimum uncertainty, is introduced and discussed in detail.

DOI
10.1093/oso/9780198791942.003.0002

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Abstract Focusing on systems of many identical particles, Chapter 2 introduces appropriate operators to describe their properties in terms of Schwinger’s “measurement symbols.” The latter are then factorized into “creation” and “annihilation” operators, whose fundamental properties and commutation/anticommutation relations are derived in conjunction with the Pauli exclusion principle. This leads to “second quantization” with the Hamiltonian, number, linear and angular momentum operators expressed in terms of the annihilation and creation operators, as well as the occupation number representation. Finally, the concept of coherent states, as eigenstates of the annihilation operator, having minimum uncertainty, is introduced and discussed in detail.
In this chapter we describe a technique to deal with identical particles that is called second quantization . Despite being a technique, second quantization helps a lot in understanding physics. One can learn and endlessly repeat newspaper-style statements particles are fields , fields are particles without grasping their meaning. Second quantization brings these concepts to an operational level. Since the procedure of second quantization is slightly different for fermions and bosons, we have to treat the two cases separately. We start with considering a system of identical bosons, and introduce creation and annihilation operators (CAPs) that change the number of particles in a given many-particle state, thereby connecting different states in Fock space. We show how to express occupation numbers in terms of CAPs, and then get to the heart of the second quantization: the commutation relations for the bosonic CAPs. As a next step, we construct field operators out of the CAPs and spend quite some time (and energy) presenting the physics of the particles in terms of these field operators. Only afterward, do we explain why all this activity has been called second quantization. In Section 3.4 we then present the same procedure for fermions, and we mainly focus on what is different as compared to bosons. The formalism of second quantization is summarized in Table 3.1.
Abstract Chapter 1 opens with a brief review of some basic features of quantum mechanics, including the Schrödinger equation, linear and angular momentum and the theory of the hydrogenic atom: It also includes complete orthonormal sets of eigenfunctions, the translation operator, current, spin, equation of continuity, gauge transformation, determinant & permanent multiparticle energy eigenfunctions for noninteracting particles and the Pauli exclusion principle. Attention is then focused on Dirac bra-ket notation and complete sets of commuting observables. In this connection, representations and transformation among representations are discussed in detail for the Schrödinger system state vector and the eigenstates, as well as bra-ket matrix elements of operators. Finally, Schwinger’s interpretation of ket-bra matrix operator structures (Schwinger “Measurement Symbols”) in terms of annihilation and creation of systems in eigenstates is introduced.
The properties of a quantum mechanical system composed of many identical particles are most conveniently described in terms of the second-quantized, Heisenberg representation, particle-creation, and annihilation operators. The creation operator, ψ †( r , t), when acting to the right on a state of the system, adds a particle to the state at the space-time point r , t; the annihilation operator ψ ( r , t), the adjoint of the creation operator, acting to the right, removes a particle from the state at the point r , t.
This is a self-contained and hopefully readable account on the method of creation and annihilation operators (also known as the Fock space representation or the "second quantization" formalism) for non-relativistic quantum mechanics of many particles. Assuming knowledge only on conventional quantum mechanics in the wave function formalism, we define the creation and annihilation operators, discuss their properties, and introduce corresponding representations of states and operators of many-particle systems. As the title of the note suggests, we cover most topics treated in sections 6.7 and 6.8 of Feynman's "Statistical Mechanics: A Set of Lectures". As a preliminary, we also carefully discuss the symmetry of wave functions describing indistinguishable particles. We note that all the contents of the present note are completely standard, and the definitions and the derivations presented here have been known to many. Although the style of the present note may be slightly more mathematical than standard physics literatures, we do not try to achieve full mathematical rigor.(Note to experts: In particular we here DERIVE the (anti)commutation relations of the creation and annihilation operators, rather than simply declaring them. In this sense our approach is quite close to that of Feynman's. But we here focus on the action of creation/annihilation operators on general NNN body wave functions, while Feynman makes a heavy use of Slater-determinant-type states from the beginning. We hope that our presentation provides a better perspective on the formalism.)
Abstract This chapter sets out the second-quantisation treatment for systems of identical bosons or fermions. Key features such as the symmetrisation principle and super-selection rules are presented. Orthogonality and completeness requirements for mode functions are set out, and Fock states are defined in terms of mode occupancy, leading to the definitions of mode annihilation and creation operators and the determination of their commutation (bosons) or anticommutation (fermions) rules. Important two-mode states such as binomial states and relative-phase eigenstates are considered. Field creation and annihilation operators are defined and related to multi-particle position eigenstates. The Hamiltonian is expressed in terms of both mode operators and field operators, state dynamics being treated via Liouville–von Neumann, master or Matsubara equations for the density operator. Normal ordering is introduced and applied to expressions for the vacuum state projector. Multi-particle position probabilities are considered and related to normally ordered quantum correlation functions.