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Anomalous Statistics of Bose-Einstein Condensate in an Interacting Gas: An Effect of the Trap’s Form and Boundary Conditions in the Thermodynamic Limit

Sergey V. Tarasov, Vl. V. Kocharovsky, Vitaly V. Kocharovsky

Published Feb 27, 2018• 11 citations
Publisher

Abstract

We analytically calculate the statistics of Bose-Einstein condensate (BEC) fluctuations in an interacting gas trapped in a three-dimensional cubic or rectangular box with the Dirichlet, fused or periodic boundary conditions within the mean-field Bogoliubov and Thomas-Fermi approximations. We study a mesoscopic system of a finite number of trapped particles and its thermodynamic limit. We find that the BEC fluctuations, first, are anomalously large and non-Gaussian and, second, depend on the trap's form and boundary conditions. Remarkably, these effects persist with increasing interparticle interaction and even in the thermodynamic limit-only the mean BEC occupation, not BEC fluctuations, becomes independent on the trap's form and boundary conditions.

DOI
10.3390/e20030153

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We analytically calculate the statistics of Bose-Einstein condensate (BEC) fluctuations in an interacting gas trapped in a three-dimensional cubic or rectangular box with the Dirichlet, fused or periodic boundary conditions within the mean-field Bogoliubov and Thomas-Fermi approximations. We study a mesoscopic system of a finite number of trapped particles and its thermodynamic limit. We find that the BEC fluctuations, first, are anomalously large and non-Gaussian and, second, depend on the trap's form and boundary conditions. Remarkably, these effects persist with increasing interparticle interaction and even in the thermodynamic limit-only the mean BEC occupation, not BEC fluctuations, becomes independent on the trap's form and boundary conditions.
We calculate the Bose-Einstein-condensate (BEC) occupation statistics vs the interparticle interaction in a dilute gas with a nonuniform condensate in a box trap within the Bogoliubov approach. The results are compared against the previously found BEC-occupation statistics in (i) an ideal gas and (ii) a weakly interacting gas with a uniform condensate. In particular, we reveal and explicitly describe an appearance of a nontrivial transition from the ideal gas to the Thomas-Fermi regime. The results include finding the main regimes of the BEC statistics---the anomalous non-Gaussian thermally dominated fluctuations and the Gaussian quantum-dominated fluctuations---as well as a crossover between them and their manifestations in a mesoscopic system. Remarkably, we show that the effect of the boundary conditions, imposed at the box trap, on the BEC fluctuations does not vanish in the thermodynamic limit of a macroscopic system even in the presence of the interparticle interactions. Finally, we discuss a challenging problem of an experimental verification of the theory of the BEC fluctuations addressing a much deeper level of the many-body statistical physics than usually studied quantities related to the mean condensate occupation.
The mesoscopic effects in the quantum trapped gases of the Bose atoms constitute\nthe main subject of the present thesis. These effects are the most difficult for\nthe theoretical analysis in the quantum statistical physics since they can’t be seen by\nneither a standard quantum mechanics of the simple microscopic systems of one or\nvery few atoms nor a standard statistical physics of the macroscopic systems that are\ninfinite in the bulk (thermodynamic) limit.\nMost of the experiments on the cold quantum gases performed in the last decade,\nstarting from the first demonstration of BEC in 1995, involve the mesoscopic systems\nof a finite number of atoms. The mesoscopic effects should manifest themselves most\nclearly and easily near a critical temperature of BEC; however, they could be observed\nalso above and below the critical temperature.\nHere I study the quantum and thermal fluctuations of the Bose-Einstein condensate\n(BEC) in a box with the periodic boundary conditions under a particle-number\nconstraint. The above constraint is the only reason for the BEC and is crucial for the\nmesoscopic effects in the BEC fluctuations, especially in the vicinity of the critical\ntemperature in the Bose gas.\nI employ the particle-number conserving operator formalism of Girardeau and\nArnowitt introduced in 1959 to analyze the canonical ensemble fluctuations. I present\nanalytical formulas and numerical calculations for the central moments of the ground\nstate occupation fluctuations in an ideal Bose gas in a box with a mesoscopic number of particles.\nI present the analysis of the BEC statistics both on a temperature at a fixed\nnumber of particles and on a number of particles at a fixed temperature. Both analyses\nare valid for the purpose of understanding the important mesoscopic effects near the\ncritical temperature. I emphasize the non-Gaussian nature of the fluctuations.\nThe presented formalism can be generalized to the case of a weakly interacting\nBose gas in a box in the framework of the Bogoliubov approximation. The work in\nthis direction is in progress but is not included in the present thesis.
Abstract For a gas of trapped interacting atoms forming a Bose condensate, we demonstrate a possibility of a significant influence of the boundary conditions on the statistics of the number of particles in the fundamental mode of the system. The analysis is carried out in the Bogoliubov – Popov low-temperature approximation for model homogeneous cubic traps with periodic or combined periodic and zero boundary conditions. It is shown that the effect of the boundary conditions does not weaken even in the region of parameters corresponding to the relatively strong interaction in the Thomas – Fermi asymptotic case, and does not disappear when proceeding to the thermodynamic limit.
We consider equilibrium canonical-ensemble fluctuations of the Bose-Einstein condensate (BEC) in a trap using the particle-number conserving operator formalism of Girardeau and Arnowitt [Phys. Rev. 113, 755 (1959)] and the concept of the canonical-ensemble quasiparticles. We find explicit expressions for the characteristic function and all cumulants of the ground-state occupation statistics both for the dilute weakly interacting and ideal Bose gases. We present analytical formulas for the moments of the ground-state occupation fluctuations in the weakly interacting and ideal Bose gases in a box (``homogeneous gas'') as well as in the ideal Bose gas in an arbitrary power-law trap, in particular, in an arbitrary harmonic trap. We calculate the effect of Bogoliubov coupling between quasiparticles on suppression of the ground-state occupation fluctuations at moderate temperatures and their enhancement at very low temperatures. We clarify a crossover between ideal-gas and weakly interacting gas statistics, which is governed by a pair-correlation, squeezing mechanism. The important conclusion is that in most cases the ground-state occupation fluctuations are anomalously large and are not Gaussian even in the thermodynamic limit.
We find the universal structure and scaling of the Bose-Einstein condensation (BEC) statistics and thermodynamics (Gibbs free energy, average energy, heat capacity) for a mesoscopic canonical-ensemble ideal gas in a trap with an arbitrary number of atoms, any volume, and any temperature, including the whole critical region. We identify a universal constraint-cutoff mechanism that makes BEC fluctuations strongly non-Gaussian and is responsible for all unusual critical phenomena of the BEC phase transition in the ideal gas. The main result is an analytical solution to the problem of critical phenomena. It is derived by, first, calculating analytically the universal probability distribution of the noncondensate occupation, or a Landau function, and then using it for the analytical calculation of the universal functions for the particular physical quantities via the exact formulas which express the constraint-cutoff mechanism. We find asymptotics of that analytical solution as well as its simple analytical approximations which describe the universal structure of the critical region in terms of the parabolic cylinder or confluent hypergeometric functions. The obtained results for the order parameter, all higher-order moments of BEC fluctuations, and thermodynamic quantities perfectly match the known asymptotics outside the critical region for both low and high temperature limits. We suggest two- and three-level trap models of BEC and find their exact solutions in terms of the cutoff negative binomial distribution (which tends to the cutoff gamma distribution in the continuous limit) and the confluent hypergeometric distribution, respectively. Also, we present an exactly solvable cutoff Gaussian model of BEC in a degenerate interacting gas. All these exact solutions confirm the universality and constraint-cutoff origin of the strongly non-Gaussian BEC statistics. We introduce a regular refinement scheme for the condensate statistics approximations on the basis of the infrared universality of higher-order cumulants and the method of superposition and show how to model BEC statistics in the actual traps. In particular, we find that the three-level trap model with matching the first four or five cumulants is enough to yield remarkably accurate results for all interesting quantities in the whole critical region. We derive an exact multinomial expansion for the noncondensate occupation probability distribution and find its high-temperature asymptotics (Poisson distribution) and corrections to it. Finally, we demonstrate that the critical exponents and a few known terms of the Taylor expansion of the universal functions, which were calculated previously from fitting the finite-size simulations within the phenomenological renormalization-group theory, can be easily obtained from the presented full analytical solutions for the mesoscopic BEC as certain approximations in the close vicinity of the critical point.
Bose-Einstein condensation (BEC) of a noninteracting Bose gas of N particles in a two-dimensional box with Dirichlet boundary conditions is studied. Confirming previous work, we find that BEC occurs at finite N at low temperatures T without the occurrence of a phase transition. The conventionally-defined transition temperature T(E) for an infinite three-dimensional (3D) system is shown to correspond in a 2D system with finite N to a crossover temperature between a slow and rapid increase in the fractional boson occupation N(0)/N of the ground state with decreasing T. We further show that T(E)∼1/logN at fixed area per boson, so in the thermodynamic limit there is no significant BEC in 2D at finite T. Thus, paradoxically, BEC only occurs in 2D at finite N with no phase transition associated with it. Calculations of thermodynamic properties versus T and area A are presented, including Helmholtz free energy, entropy S, pressure p, ratio of p to the energy density U/A, heat capacity at constant volume (area) C(V) and at constant pressure C(p), isothermal compressibility κ(T) and thermal expansion coefficient α(p), obtained using both the grand-canonical ensemble (GCE) and canonical ensemble (CE) formalisms. The GCE formalism gives acceptable predictions for S, p, p/(U/A), κ(T) and α(p) at large N, T and A but fails for smaller values of these three parameters for which BEC becomes significant, whereas the CE formalism gives accurate results for all thermodynamic properties of finite systems even at low T and/or A where BEC occurs.