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Bulletin of the American Physical Society

Bose-Einstein condensation of a non-ideal Bose gas of atoms with large spin

Andrei I. Pavlov, V. S. Babichenko, Ilya Polishchuk

Published Mar 6, 2018• 0 citations
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We rigorously revisit a textbook model used to figure out the Bose-Einstein condensation (BEC) phenomenon created by dilute cold alkali atoms gases in a magnetic-optical trap. It consists of a d-dimensional (d=1,2,3) ideal non-relativistic spin-0 Bose gas confined in a box and trapped in an isotropic harmonic potential. Throughout we review and clarify a series of methods involved in the derivation of the thermodynamics in the grand-canonical situation. To make the derivation consistent with the usual rules of the statistical mechanics, we assign through our open-trap limit approach the role of canonical parameter to a rescaled number of particles (instead of an effective density involving the pulsation of the trap). Within this approach, we formulate an Einstein-like and Penrose-Onsager-like criterion of BEC and show their equivalence. Afterwards, we focus on the spatial localization of the condensate/thermal gas. When dealing with the reduced density matrix, our method is similar to the loop path approach.
We observe multistep condensation of sodium atoms with spin F=1, where the different Zeeman components m_{F}=0,±1 condense sequentially as the temperature decreases. The precise sequence changes drastically depending on the magnetization m_{z} and on the quadratic Zeeman energy q (QZE) in an applied magnetic field. For large QZE, the overall structure of the phase diagram is the same as for an ideal spin-1 gas, although the precise locations of the phase boundaries are significantly shifted by interactions. For small QZE, antiferromagnetic interactions qualitatively change the phase diagram with respect to the ideal case, leading, for instance, to condensation in m_{F}=±1, a phenomenon that cannot occur for an ideal gas with q>0.