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Quantum coherent dynamics in molecular magnetic rings

A. Honecker, Florian Meier, Daniel Loss, Bruce Normand

Published Sep 11, 2001• 1 citation
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Progress of Theoretical Physics Supplement•Jan 1, 2002•3 citations
he multiqubit entangled states are coherently controlled in the quantum spin systems composed of N+1N+1N+1 interacting antiferromagnetic molecular rings. The tunable intermolecular couplings arise from the local exchange interactions between electron spins of NNN circumjacent magnets and those of one central molecular ring. The quantum dynamics of such system is analytically deduced by the effective spin hamiltonian with anisotropic Heisenberg couplings. It is found that entangled WWW states can be generated with a high precision under the circumstance of quantum fluctuations. The multiqubit entangled state is also transferred from some molecular rings to others by the selection of intermolecular couplings.
We investigate the relaxation effects on the quantum dynamics in a two-state molecular system interacting with a single-mode strongly amplitude-squeezed coherent field using the second-order Monte Carlo wave-function method. The molecular population inversion (collapse-revival behavior of Rabi oscillations) is known to show the echoes after each revival, which are referred to as ringing revivals, in the case of strongly squeezed coherent fields with oscillatory photon-number distributions due to the phase-space interference effect. Two types of relaxation effects, i.e., cavity relaxation (the dissipation of an internal single mode to outer mode) and molecular coherent (phase) relaxation caused by nuclear vibrations on ringing revivals are investigated from the viewpoint of the quantum-phase dynamics using the quasiprobability (QQQ function) distribution of a single-mode field and the off-diagonal molecular density matrix $\ensuremath{\mid}{\ensuremath{\rho}}_{\mathrm{elec}\phantom{\rule{0.3em}{0ex}}1,2}(t)\ensuremath{\mid}$. It turns out that the molecular phase relaxation attenuates both the entire revival-collapse behavior and the increase in $\ensuremath{\mid}{\ensuremath{\rho}}_{\mathrm{elec}\phantom{\rule{0.3em}{0ex}}1,2}(t)\ensuremath{\mid}$ during the quiescent region, whereas a very slight cavity relaxation particularly suppresses the echoes in ringing revivals more significantly than the first revival but hardly changes a primary variation in envelope of $\ensuremath{\mid}{\ensuremath{\rho}}_{\mathrm{elec}\phantom{\rule{0.3em}{0ex}}1,2}(t)\ensuremath{\mid}$ in the nonrelaxation case.