铕原子4f 7 6p 3/2 n d自电离态的光谱

沈 礼 薛智丽, 沈礼, 戴长建

徐捷, 李颖峰

Vadim A. Alekseev, Peter J. M. van der Burgt, Donald W. Setser

Stimulated emission (SE) induced by pulsed two-photon excitation of the 6p′[1/2]0, 6p′[3/2]2, 7p[1/2]0, 7p[3/2]2, and 7p[5/2]2 states of the Xe atom has been studied. Spectra of SE were recorded in the 800–3500 nm region, which covers the 6p′, 7p → 7s (2500–3500 nm), 6p′, 7p → 5d (1000–2000 nm), 7s → 6p (1200–1900 nm) transitions, as well as the near-IR 6p → 6s (800–1000 nm) transitions. It is shown that excitation of the 7p states results in radiative cascade via the 7s states, 7p → 7s → 6p, although at least one case of cascading via the 5d states is also observed. Spectra of SE induced by excitation of the 6p′ states are dominated by the 6p′ → 6s′ transitions in the near IR and the 6p′ → 5d[1/2]1 → 6p[1/2]1 → 6s[3/2]1 cascade; the 6p′ → 7s → 6p cascade is also observed, although the secondary 7s → 6p emission is rather weak in comparison with excitation of the 7p states.

Shan He, Junzhi Chu, Dong Liu +9 more

The kinetic processes of Xe (6p[1/2]0, 6p[3/2]2, and 6p[5/2]2) atoms under the focused condition were investigated. The atomic density of the laser prepared state significantly increases. Therefore, the probability of the energy-pooling between two high-lying atoms increases. There are three major types of the energy-pooling collisions. The first type is the energy-pooling ionization. Once the excitation laser is focused, the obvious ionization can be observed from the side window whenever the laser prepared state is 6p[1/2]0, 6p[3/2]2, or 6p[5/2]2 state. Ionization of Xe is attributed to the energy-pooling ionization or a Xe* atom reabsorbing another excitation photon. The second type is energy-pooling with big energy difference. When the 6p[1/2]0 state is the laser prepared state, the energy-pooling collision between two 6p[1/2]0 atoms can produce one 5d[3/2]1 atom and one 6s′[1/2]0 atom. The third type is energy-pooling with small energy difference. The intensities of fluorescence lines are much stronger that five secondary 6p states act as the upper states, and the rising edges of these fluorescence lines are much steeper. The primary mechanism of generating the secondary 6p atoms is energy-pooling collision instead of collision relaxation. Based on the collision probability, the rate of energy-pooling between two 6p[1/2]0 atoms is deduced (6.39 × 108 s−1). In addition, the 6s atoms also increase under the focused condition. Therefore, all the fluorescence lines are serious trailing by radiation trapping.

白光, 晴天

清 内川, 日佐雄 大澤, 菅隆之 +1 more