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Russian Physics Journal

Relativistic Corrections to the Energy of the Electron in a Hydrogenlike Atom

В. В. Скобелев

Published Nov 1, 2017• 2 citations
Publisher
DOI
10.1007/s11182-017-1189-1

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In the relativistic description of atomic systems in external fields, the total momentum and the external electric field couple to the angular momentum of the individual particles. Therefore, the motional state of an ion in a particle trap influences measurements of internal observables such as energy levels or the ggg factor. We calculate the resulting relativistic shift of the Larmor frequency and the corresponding ggg-factor correction for a bound electron in a hydrogenlike ion in the 1S1 S1S state due to the ion moving in a Penning trap and show that it is negligible at the current precision of measurements. We also show that the analogous energy shift for measurements with an ion in the ground state of a Paul trap vanishes in leading order.
Two-photon decay of hydrogenlike ions is studied within the framework of second-order perturbation theory, based on the relativistic Dirac's equation. Special attention is paid to the effects arising from the summation over the negative-energy (intermediate virtual) states that occur in such a framework. In order to investigate the role of these states, detailed calculations have been carried out for the $2{s}_{1/2}\ensuremath{\rightarrow}1{s}_{1/2}$ and $2{p}_{1/2}\ensuremath{\rightarrow}1{s}_{1/2}$ transitions in neutral hydrogen H as well as for hydrogenlike xenon Xe53+{\text{Xe}}^{53+}Xe53+ and uranium U91+{\text{U}}^{91+}U91+ ions. We found that for a correct evaluation of the total and energy-differential decay rates, summation over the negative-energy part of Dirac's spectrum should be properly taken into account both for high-ZZZ and low-ZZZ atomic systems.