The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas system model and numerically demonstrated irreversible growth of entanglement entropy caused by erasure of spread non-equilibrium state information. Here, we mathematically prove that for a typical macroscopic system in a non-equilibrium state
∣ϕ0⟩, the quantum state
∣ϕ0′⟩=O^(t)∣ϕ0⟩ will inevitably evolve toward equilibrium. Our work demonstrates that the second law of thermodynamics, and consequently the ergodic hypothesis in statistical physics, can be understood and proven from a quantum information perspective. From this perspective, the second law can be stated as: In typical macroscopic physical systems, the spreading and erasure of non-equilibrium information is inevitable.
The role of quantum entanglement in thermodynamical systems remains elusive. Does entanglement result in thermodynamic advantages or does it impose fundamental limitations? Here, we unambiguously quantify the amount of heat and work in a quantum system that is due to the presence of entanglement. This is achieved by constraining the system's non-equilibrium dynamics to separable states, thereby isolating the impact entanglement has on thermodynamic effects. Unlike thermodynamic entanglement measures, which signify a loose connection between entanglement and thermodynamic properties, imposing a constraint constitutes an active intervention into a system -- answering how much of a system's thermodynamics is caused by (not correlated with) its quantumness. We benchmark our theory by applying the constrained dynamics to several multipartite systems, including quantum batteries and quantum refrigerators.
These are lecture notes for a short course given at the Les Houches Summer School on ``Integrability in Atomic and Condensed Matter Physics'', in summer 2018. Here, I pedagogically discuss recent advances in the study of the entanglement spreading during the non-equilibrium dynamics of isolated integrable quantum systems. I first introduce the idea that the stationary thermodynamic entropy is the entanglement accumulated during the non-equilibrium dynamics and then join such an idea with the quasiparticle picture for the entanglement spreading to provide quantitive predictions for the time evolution of the entanglement entropy in arbitrary integrable models, regardless of the interaction strength.