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Physical Review B

Chirality and spin transformation of triplet Cooper pairs upon interaction with singlet condensate

Andreas Moor, Anatoly Fjodorovich Volkov, K. B. Efetov

Published Dec 15, 2015• 19 citations
Publisher

Abstract

We show that the fully polarized triplet $s$-wave component is characterized not only by the spin direction, but also by chirality. Interaction of a polarized triplet component and a singlet one results in creation of triplet Cooper pairs with opposite spin direction or of different chiralities. Such spin transformation leads to interesting phenomena in multiterminal magnetic Josephson junctions. We calculate the dc Josephson current ${I}_{\text{J}}$ in a multiterminal Josephson contact of the ${S}_{\text{m}}/n/{S}_{\text{m}}^{\ensuremath{'}}$ type with ``magnetic'' superconductors ${S}_{\text{m}}$ that generate fully polarized triplet components. The superconductors ${S}_{\text{m}}$ are attached to magnetic insulators (filters) which let pass electrons with a fixed spin direction only. The filter axes are assumed to be oriented antiparallel to each other. The Josephson current is zero in two-terminal Josephson junction, i.e., in $S/n/{S}_{\text{m}}$ or in ${S}_{\text{m}}/n/{S}_{\text{m}}^{\ensuremath{'}}$ contact. But in the three-terminal Josephson junction, with another $S$ superconductor attached to the normal wire, the finite current ${I}_{\text{J}}$ appears flowing from the $S$ superconductor to ${S}_{\text{m}}$ superconductors. The currents through the right (left) superconductors ${S}_{\text{m}}$ are opposite in sign, ${I}_{\text{R}}\ensuremath{\equiv}{I}_{\text{J}}={I}_{\text{c}}sin({\ensuremath{\chi}}_{\text{R}}+{\ensuremath{\chi}}_{\text{L}}\ensuremath{-}2\ensuremath{\chi})=\ensuremath{-}{I}_{\text{L}}$, where ${\ensuremath{\chi}}_{\text{L/R}}$ and $\ensuremath{\chi}$ are the phases of superconductors ${S}_{\text{m}},{S}_{\text{m}}^{\ensuremath{'}}$, and $S$, respectively. We discuss possibilities of experimental observation of the effect.

DOI
10.1103/physrevb.92.214510

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Abstract We propose the Josephson junctions linked by a normal metal between a d + id superconductor and another d + id superconductor, a d-wave superconductor, or a s-wave superconductor for identifying the chiral d + id superconductivity. The time-reversal breaking in the chiral d-wave superconducting state is shown to result in a Josephson φ0-junction state where the current-phase relation is shifted by a phase φ0 from the sinusoidal relation, other than 0 and π. The ground-state phase difference φ0 and the critical current can be used to definitely confirm and read the information about the d + id superconductivity. A smooth evolution from conventional 0-π transitions to tunable φ0-states can be observed by changing the relative magnitude of two types of d-wave components in the d + id pairing. On the other hand, the Josephson junction involving the d + id superconductor is also the simplest model to realize a φ0- junction, which is useful in superconducting electronics and superconducting quantum computation.
The influence of chiral molecular potentials on phase-coherent transport in superconducting Josephson junctions is investigated. Within a Bogoliubov--de Gennes tight-binding framework, a superconducting--normal--superconducting (SNS) junction functionalized by adsorbed chiral molecules is modeled, where electrostatic gradients generated by the molecules induce spin--orbit coupling in the normal region. The equilibrium charge current--phase relation is found to remain largely insensitive to molecular chirality in symmetric, zero-field configurations. In contrast, the spin-polarized equilibrium current exhibits a pronounced chirality-dependent response, with opposite enantiomers producing distinct and anisotropic spin-polarized Josephson currents. The resulting handedness contrast can be enhanced through control parameters such as molecular orientation and the strength of the induced spin--orbit coupling. The temperature dependence of these currents further shows that the chirality-dependent signatures persist across a range of temperatures well below the superconducting critical temperature. These results identify Josephson interferometry as a phase-sensitive setting for probing chirality-dependent spin structure and highlight spin-polarized superconducting transport as a controlled route toward integrating chiral molecular functionality into superconducting spintronic devices.
Entanglement is a valuable resource for quantum computing and information technologies. A promising way to obtain spin-entangled electrons is the splitting of Cooper pairs residing in superconductors. This is realized by a nanodevice called Cooper pair splitter. A Cooper pair splitter is realized by tunnel-coupling a superconductor to two quantum dots, which are each further tunnelcoupled to separate terminal leads. This setup enables the extraction and splitting of Cooper pairs from the superconductor into the terminals via the quantum dots. The quantum dots are commonly fabricated from semiconducting materials like InAs and InSb, that can manifest spin-orbit interaction. This thesis studies the effect of spin-orbit interaction on the spin state of the electron pair in the Cooper pair splitter. Activating the spin-orbit effects in a Cooper pair splitter requires a static magnetic field to be applied to the quantum dots. Together with the gate electrodes controlling the electrostatic energy of the quantum dots, the external magnetic field provides a handle for addressing different two-particle spin states. The spin-orbit interaction can be activated by various combinations of the gate voltage and Zeeman magnetic field, that create resonances between different states of the system. The most interesting coherent evolution, that can be invoked in this way, involves the simultaneous activation of the two spin-polarized triplet states. This gives a rise to an entangled Bell state, (|↑↑>+|↓↓>) / √2, that moreover exhibits spin blockade and thus stabilizes entanglement in the Cooper pair splitter. Secondly, the spin-orbit interaction can be used to bypass suppressed Cooper pair tunneling at a high superconductor-quantum dots detuning. Introducing a large Zeeman magnetic field allows Cooper pairs to tunnel in to the dots given that their spin state flips to the triplet |↓↓>. Although this regime lacks spin-entanglement, it is of interest for creating triplet Cooper pairs and spin-polarized superconducting currents.
It was theoretically proposed that a forward-biased $p\ensuremath{-}n$ junction with a superconducting layer (P-N-S) would produce pure, polarization-entangled photons due to inherent spin-singlet pairing of electrons. However, any heterostructure interface generically induces Rashba spin-orbit coupling, which in turn generates a mixed singlet-triplet superconducting order parameter. Here we study the effect of triplet pairing on the purity of photons produced through Cooper pair recombination. A unique directional dependence of the state purity is found for a triplet superconductor with fixed $\mathbit{d}$: pure, entangled photons are produced when the photon polarization axis is parallel to $\mathbit{d}$. Induced triplet pairing in a singlet superconductor is shown to degrade the state purity, while induced singlet pairing in a triplet superconductor is shown to enhance the production of entangled pairs. These considerations may aid the design of functional devices to produce entangled photons.
We discuss possibilities of utilizing superconductors with Cooper condensates in triplet pairing states (where the spin of condensate pairs is S=1) for practical realization of quantum computers. Superconductors with triplet pairing condensates have features that are unique and cannot be found in the usual (singlet pairing, S=0) superconductors. The symmetry of the order parameter in some triplet superconductors (e.g., ruthenates) corresponds to doubly-degenerate chiral states. These states can serve as qubit base states for quantum computing.
Abstract Correlations are fundamental in describing many body systems - not only in natural sciences. However, in experiments, correlations are notoriously difficult to assess on the microscopic scale, especially for electron spins. Here, we demonstrate a direct measurement of the spin cross-correlations between the currents of a Cooper pair splitter, an electronic device that emits electrons originating from Cooper pairs in a superconductor. While it is firmly established theoretically that these electron pairs form maximally spin-entangled singlet states with opposite spin projections, no spin correlation experiments have been demonstrated so far. We use ferromagnetic sidegates, compatible with superconducting electronic structures, to individually spin polarize the transmissions of two quantum dots fabricated in the two electronic paths, which act as tunable spin filters. The signals are detected in standard transport and in highly sensitive transconductance experiments. We find that the spin-cross correlation is negative, compatible with spin singlet emission, and deviates from the ideal value mostly due to a finite overlap of the Zeeman split quantum dot states. Our results demonstrate a new route to perform spin auto- and cross correlation experiments in nanometer scaled electronic devices, especially suitable for those relying on magnetic field sensitive superconducting elements, like unconventional, triplet or topologically non-trivial superconductors, or to perform Bell tests with massive particles, like electrons.