Irreversible process of a weakly coupled one-dimensional quantum perfect Lorentz gas is studied on the basis of the fundamental laws of physics in terms of the complex spectral analysis associated with the resonance state of the Liouvillian. Without any phenomenological operations, such as a coarse-graining of space-time or a truncation of the higher order correlation, we obtained irreversible processes on a purely dynamical basis in all space and time scale including the microscopic atomic interaction range that is much smaller than the mean-free-length. The list of development of the complex spectral analysis of the Hamiltonian (instead of the Liouvillian) in quantum optical systems and in quantum nano-devices is also presented.
Irreversible process of a weakly coupled one-dimensional quantum perfect Lorentz gas is studied on the basis of the fundamental laws of physics in terms of the complex spectral analysis associated with the resonance state of the Liouvillian. Without any phenomenological operations, such as a coarse-graining of space-time or a truncation of the higher order correlation, we obtained irreversible processes on a purely dynamical basis in all space and time scale including the microscopic atomic interaction range that is much smaller than the mean-free-length. The list of development of the complex spectral analysis of the Hamiltonian (instead of the Liouvillian) in quantum optical systems and in quantum nano-devices is also presented.
Kinetic theory in nonequilibrium statistical physics is discussed in terms of the complex spectral representation of the Liouvillian for quantum systems. We show that the collision operator appearing in the kinetic equation is the “self-energy part” of the Liouvillian. Solving the dispersion equation associated to the “self-energy part”, one can construct the resonance states of the Liouvillian which have complex eigenvalues. The imaginary part of the eigenvalue gives a decay rate in irreversible process in nonequilibrium statistical physics. As illustrations of the resonance states of the Liouvillian we consider two examples; one is a one-dimensional system in which a polaron is weakly interacting with a thermal reservoir consisting of an acoustic phonon field, and the other is a molecular chain that is described by the Davydov Hamiltonian, which has been introduced as a simple model that describes a protein chain. We show that the imaginary part of the spectrum of the Liouvillian in these systems has rich structures showing band structure, an accumulation point, and a fractal structure reminiscent of Hofstadter's butterfly.
Recent developments on the complex spectral representation of the evolution operators have shown that irreversibility is a rigorous dynamical process that takes place outside the Hilbert space for non‐integrable systems, both classical and quantum. Irreversibility is a direct consequence of microscopic dynamical processes associated with resonance singularities, rather than our incomplete knowledge. We discuss the excitation process of a quantum unstable particle by scattering of a wave packet. Using complex eigenstates of the Hamiltonian one may construct a microscopic dynamical entropy (or H function) without any approximation. In order to have scattering, one has to target the wave packet to the particle. This introduces a nonlocal pre‐collisional correlation giving a low dynamical entropy. During the moment the excited particle is created, there appears an entropy flow from the field to the particle. This lowers the particle component of the entropy, even though the total entropy production is always positive. This implies that the excitation of the particle may be considered as the construction of a non‐equilibrium structure due to entropy flow.
Open quantum system, coupled with an external bath is a key research field of quantum physics. Steady state is the state in which any initial state converges after a long time and is usually of the most interest. However, relatively speaking, the nonequilibrium dynamical processes of quantum many-body systems have been rarely studied. This is mainly due to the fact that quantum many-body systems generally have interactions, and the Hilbert space required for a complete description of their dynamical processes will grow exponentially with the number of particles increasing, and the computational difficulty will increase dramatically as well. Hence, it is a difficult problem to completely describe their dynamical processes completely. With the development of quantum technologies, the interest in the nonequilibrium dynamics of open quantum many-body systems is aroused. A common phenomenon is the metastable state, where the system initially relaxes into a long-lived state and then converges to the final stationary state for a longer time. In this paper, we establish a low-dimensional approximation to describe the metastability dynamics in Markovian open quantum system, based on the spectra of the Liouvillian super-operator. The separation of time scales implies a splitting in the spectrum, and this spectral division allows us to eliminate the fast decay modes by using the perturbation method, and then we establish the effective description in the low-lying eigenmodes subspace. Furthermore, we study the dynamics process of the Rydberg atomic system under electromagnetically induced transparency (EIT) conditions and find that the system can handle metastable dynamics if the atomic interactions are considered. We compare the effective dynamics in the subspace with the actual dynamics in the full space, and the results show that the effective dynamics works well on condition that the perturbation approximation holds. Our work provides a feasible idea and method for establishing an effective and simplified description of the dynamical process of open quantum many-body systems.
We address the longstanding challenge in quantum many-body theory of reconciling unitary dynamics with irreversible relaxation. In classical chaos, the unitary evolution operator develops Ruelle-Pollicott (RP) resonances inside the unit circle in the continuum limit, leading to mixing. In the semiclassical limit, chaotic single-particle quantum systems relax with the same RP resonances. In contrast, the theory of quantum many-body RP resonances and their link to irreversibility remain underdeveloped. Here, we relate the spectral form factor to the sum of autocorrelation functions and, in generic many-body lattice systems without conservation laws, we argue that all quantum many-body RP resonances converge inside the unit disk, highlighting the role of nonunitary and the thermodynamic limit. While we conjecture this picture to be general, we analytically prove the emergence of irreversibility in the random phase model (RPM), a paradigmatic Floquet quantum circuit model, in the limit of large local Hilbert space dimension. To this end, we couple it to local environments and compute the exact time evolution of autocorrelation functions, the dissipative form factor, and out-of-time-order correlation functions (OTOCs). Although valid for any dissipation strength, we then focus on weak dissipation to clarify the origin of irreversibility in unitary systems. When the dissipationless limit is taken after the thermodynamic limit, the unitary quantum map develops an infinite tower of decaying RP resonances-chaotic systems display so-called anomalous relaxation. We identify the exact RP resonances in the RPM and prove that the same RP resonances are obtained from operator truncation. We also show that the OTOC in the RPM can undergo a two-stage relaxation, and that during the second stage, the approach to the stationary value is again controlled by the leading RP resonance. Finally, we demonstrate how conservation laws, many-body localization, and nonlocal interactions merge the leading RP resonance into the unit circle, thereby suppressing anomalous relaxation. Our findings clarify the microscopic origin of macroscopic relaxation in quantum systems and emphasize the role of RP resonances as a largely unexplored signature of many-body quantum chaos.
We point out that the quantum dynamical map of an open quantum system can be generated by an effective Liouville operator. The effective Liouville shows the dynamical breaking of time reversibility. This breaking of reversibility is expressed by the effective Liouville's discrete spectrum having negative imaginary parts. This generated dynamics of open quantum systems is capable of memory effects described by a frequency dependence of the spectrum. When memory effects can be neglected or smoothed out, the effective Liouville generates the well known semi-group dynamics of open systems in the Markov approximation. The spectral analysis of the effective Liouville -with or without memory- allows to represent the quantum dynamical map and expectation values of physical quantities by metric expressions using complex eigenvalues and bi-orthonormal eigenmodes. The long time dynamics is dominated by the zero-mode, which forms the stationary state of the open system. The relaxation time scale τ is set by the inverse of the smallest negative imaginary part of the non-vanishing effective eigenvalues of the effective Liouville. In generic cases of system-environment-coupling this time scale τ is the relevant scale for both, the relaxation of diagonal elements (populations) and the decay of off-diagonal elements (coherences) of an initial density matrix in the stationary state's diagonal representation. It also sets the time scale after which the entropy tends to its stationary value. The effective Liouville and its spectral content thus give a framework to study the dynamic breaking of time reversibility, memory effects, decoherence, relaxation to a stationary state and the role of entropy in open quantum systems.
Starting from the quantum statistical master equation derived in [1] we show how the connection to the semi-classical Boltzmann equation (SCBE) can be established and how irreversibility is related to the problem of separability of quantum mechanics. Our principle goal is to find a sound theoretical basis for the description of the evolution of an electron gas in the intermediate regime between pure classical behavior and pure quantum behavior. We investigate the evolution of one-particle properties in a weakly interacting N-electron system confined to a finite spatial region in a near-equilibrium situation that is weakly coupled to a statistical environment. The equations for the reduced n-particle density matrices, with n < N are hierarchically coupled through two-particle interactions. In order to elucidate the role of this type of coupling and of the inter-particle correlations generated by the interaction, we examine first the particular situation where energy transfer between the N-electron system and the statistical environment is negligible, but where the system has a finite memory. We then formulate the general master equation that describes the evolution of the coarse grained one-particle density matrix of an interacting confined electron gas including energy transfer with one or more bath subsystems, which is called the quantum Boltzmann equation (QBE). The connection with phase space is established by expressing the one-particle states in terms of the overcomplete basis of coherent states, which are localized in phase space. In this way we obtain the QBE in phase space. After performing an additional coarse-graining procedure in phase space, and assuming that the interaction of the electron gas and the bath subsystems is local in real space, we obtain the semi-classical Boltzmann equation. The validity range of the classical description, which introduces local dynamics in phase space is discussed.