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分子科学討論会講演プログラム&要旨(Web)

水素分子の光解離によるH(2p)原子対のエンタングルメント発生とその反応による変化

田邊健彦, 丈 小田切, 中野元善, 熊谷嘉晃, 鈴木功, 河内宣之

Published Jan 1, 2009• 0 citations
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量子もつれ H(2p)原子対の特異な崩壊過程

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In this paper, as a continuation of our recent article demonstrating that the 2p atom pair is entangled in the H2 photodissociation [Phys. Rev. A 111, 023116 (2025)], we have discovered the origins of the entanglement for the 2p atom-pair state and obtained the entanglement entropies by origins. The same investigation has been carried out for the precursor molecular state of the 2p atom pair. The reason for the increase of the entanglement entropy during the dissociation from the precursor molecule into the H(2p) + H(2p) atom pair has been made clear.
We have measured the coincidence time spectra of two Lyman-α photons emitted by a pair of H(2p) atoms in the photodissociation of H 2 at the incident photon energy of 33.66 eV and at the hydrogen gas pressures of 0.40 Pa and 0.02 Pa, from which the angular distributions of two Lyman-α photons have been obtained. The experimental angular distributions indicate the generation of the entangled pair of H(2p) atoms as predicted by the theory of our group (Miyagi et al 2007 J. Phys. B 40 617) and the role of a new kind of reaction, i.e. the reaction of the entangled pair of H(2p) atoms with an H 2 molecule that efficiently changes the entanglement. It has turned out that more entangled pairs of H(2p) atoms survive at 0.02 Pa than at 0.40 Pa. The decay time constant in the coincidence time spectrum at 0.02 Pa is approximately half the lifetime of a single H(2p) atom, 1.60 ns, while the decay time constant at 0.40 Pa is in agreement with the lifetime of a single H(2p) atom. It follows that the decay faster than the lifetime of a single H(2p) atom originates from the entanglement in the pair of H(2p) atoms.