Cambridge University Press eBooks

Introduction to the Principles of Quantum Mechanics

Gabriel Laufer

Published Jul 13, 1996• 0 citations

Abstract

Ever splitting the light! How often do they strive to divide that which, despite everything, would always remain single and whole. Goethe (quoted in Zajonc 1993) Introduction The use of electromagnetic wave theory and geometrical optics to describe propagation of light is satisfactory when there is no exchange of energy between radiation and matter. All observable characteristics – direction of propagation, polarization, diffraction, interference, the energy of radiation, and so forth – are accurately described by one of these so-called classical theories. However, with the exception of absorption by lossy media (eqn. 4.36) or the effects of dispersion (eqn. 4.22), classical theories fail to give reasons for many phenomena that have practical consequences in modern technology and that involve interaction between radiation and matter. Even the partially successful descriptions of dispersion or loss cannot explain the existence of the multitude of spectrally distinct absorption lines; cannot predict the wavelengths for absorption or the wavelengths for anomalous dispersion; cannot account for all the absorbed energy; and, most importantly, cannot predict or describe the effect of optical gain, which is closely related to absorption. Thus, the principles of operation of many important devices of modern optics such as lasers, photodiodes, electronic cameras, and television screens cannot be explained by classical theories. Even the emission by the sun or an incandescent lamp are beyond the scope of these theories. It is evident therefore that a new, modern theory is necessary – one that is either more complete than, or simply complements, the classical theories.

DOI: 10.1017/cbo9781139174190.010

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