Experiments involving so-called elastic collisions between an atom and a cavity should allow the non-destructive detection of very small numbers of photons and the direct measurement of cavity field quantum jumps.An atom and a small cavity with highly reflecting walls can couple and correlate strongly to each other, resulting in pheno mena which may lead to the development of new kinds of field sensors to detect photons without destroying them; the same pheno mena also illustrate basic concepts of quan tum mechanics.The study of these effects, at first theoretical and now entering an acti ve experimental phase, forms a part of cav ity quantum electrodynamics [1], a growing field spanning atomic physics and quantum optics with many potential applications. The Atom-Cavity "Molecule"Consider an atom in a cavity whose size matches exactly the wavelength of a photon the atom can emit in a transition between two of its energy levels.If the atom Is initially excited and the resonator empty, a photon will be radiated within a short period of time in the cavity.Since this photon is trapped in the atom's vicinity by the reflecting cavity walls, it will be absorbed at a later time, the atom jumping back to the upper level, com mencing an ideally endless cycle of photon emission and absorption processes.Re markably, the exchanged photon also me diates a small force between the atom and the cavity walls [2], in the same way as charged particles exert a force on each other by exchanging a photon, or atoms attract each other in a molecule by trading electrons.The molecule analogy can help us under stand some basic features of the atom-cavi ty system.Two atoms with chemical affinity exchange an electron at a rate which de pends on their distance apart.As a result, they experience a force, which either ties them together in a molecular bound state, or repels them from each other in an "antibind ing" state.The same physics goes on in the atom-cavity system, albeit at a quite diffe rent energy scale.This system has two energy eigenstates, namely a binding one in which the excitation is shared symmetrically between the atom and the cavity (sum of the excited atom with no photon and the deexcited atom with one photon), and an anti-
Experiments involving so-called elastic collisions between an atom and a cavity should allow the non-destructive detection of very small numbers of photons and the direct measurement of cavity field quantum jumps.An atom and a small cavity with highly reflecting walls can couple and correlate strongly to each other, resulting in pheno mena which may lead to the development of new kinds of field sensors to detect photons without destroying them; the same pheno mena also illustrate basic concepts of quan tum mechanics.The study of these effects, at first theoretical and now entering an acti ve experimental phase, forms a part of cav ity quantum electrodynamics [1], a growing field spanning atomic physics and quantum optics with many potential applications. The Atom-Cavity "Molecule"Consider an atom in a cavity whose size matches exactly the wavelength of a photon the atom can emit in a transition between two of its energy levels.If the atom Is initially excited and the resonator empty, a photon will be radiated within a short period of time in the cavity.Since this photon is trapped in the atom's vicinity by the reflecting cavity walls, it will be absorbed at a later time, the atom jumping back to the upper level, com mencing an ideally endless cycle of photon emission and absorption processes.Re markably, the exchanged photon also me diates a small force between the atom and the cavity walls [2], in the same way as charged particles exert a force on each other by exchanging a photon, or atoms attract each other in a molecule by trading electrons.The molecule analogy can help us under stand some basic features of the atom-cavi ty system.Two atoms with chemical affinity exchange an electron at a rate which de pends on their distance apart.As a result, they experience a force, which either ties them together in a molecular bound state, or repels them from each other in an "antibind ing" state.The same physics goes on in the atom-cavity system, albeit at a quite diffe rent energy scale.This system has two energy eigenstates, namely a binding one in which the excitation is shared symmetrically between the atom and the cavity (sum of the excited atom with no photon and the deexcited atom with one photon), and an anti-
A single two-level emitter coupled to a single mode of an electromagnetic resonator constitutes the most fundamental instance of light--matter interaction. Realizations of this type of system are investigated in the field of cavity quantum electrodynamics (cavity QED). Particularly important are schemes in which the coupling is strong enough to exceed the spontaneous emission rate as well as cavity damping. In this case, the coherent exchange of excitation between source and photon is the dominating process, providing the unique possibility to deterministically control the quantum evolution of the system. Great progress has recently been accomplished, technologically as well as conceptually, and the focus section in this issue of Journal of Optics B: Quantum and Semiclassical Optics features five articles highlighting important recent developments in the field. Strong coupling between single atoms and the electromagnetic cavity field have been achieved in two distinct regimes, the optical and the microwave region. The latter is represented by the micromaser, a high-Q microwave cavity pumped by a beam of highly excited Rydberg atoms. It has proved to be an almost ideal system for the generation of non-classical field states. A constraint in these experiments is the fact that the field inside the cavity can only be examined indirectly, by analysing the occupation of atoms leaving the cavity. While only two atomic states were previously identified for this purpose, V A Reshetov shows in his article (pages 119--126) that more information on the field may be extracted by taking advantage of the Zeeman substructure of the atomic levels. In the optical domain of cavity QED, by contrast, the state of the resonator field may be probed directly by measuring the light leaking from the cavity using photodetectors. In order to minimize damping, high-quality cavities must be employed. In most optical experiments these are Fabry--Perot resonators with ultra-high reflectivity mirrors, with losses as low as a few parts per million being state of the art. At the same time, the coupling of atoms and photons is enhanced by reducing the length of the cavity, so that strong coupling conditions are reached. A very attractive application of this type of cavity QED setup is the possibility of exerting control over the quantum dynamics of the system. An impressive example is the implementation of quantum feedback, reported in the paper by W P Smith and L A Orozco (pages 127--134). Using information gained from detecting a single photon escaping from the cavity, active feedback is applied to halt the dynamical evolution of the system. This is the first time active feedback has been used to modify the quantum evolution of a system at the single-photon level. The authors discuss how detunings between the subsystems affect the quantum feedback, an issue particularly relevant for ensembles of atoms with a spread in detuning. Perfect quantum feedback in this case requires the use of additional parameters to control the system. The majority of optical cavity QED experiments performed so far have used as a medium atoms traversing the cavity on random trajectories, such as, for example, thermal atomic beams. In this case, the observation of quantum effects is degraded in two ways. The Doppler effect and the finite transit time lead to line broadening, while the spatial structure of the cavity mode results in atoms in different locations experiencing different coupling with the photonic field. J E Reiner et al (pages 135--142) investigate the impact of these effects on quantum fluctuations in their cavity QED system. In order to overcome line broadening, they have developed a continuous cold atomic beam, extracted from a magneto-optical trap. An even better control of broadening effects and fluctuating coupling strength is provided by trapping the atoms inside the cavity and cooling them to temperatures at which their position spread is smaller than the optical wavelength. Much recent activity has been devoted to developing such an ultimate cavity QED system. A Vukics et al (pages 143--153) present a theoretical proposal for dynamically trapping and cooling atoms inside a cavity. By driving the atoms with a standing wave injected from the side of the cavity and by weakly exciting the cavity field itself, they predict three-dimensional trapping of the atom for periods around 1 second, an extremely long time on the typical scale of cavity QED dynamics. The essential component of their scheme is the interference between the two driving fields, determining the temperature of the particle and the stable trapping positions. In the quest for better confinement of radiation, lately, an appealing alternative to the Fabry--Perot cavity has been investigated -- the optical microsphere resonator. A sphere with a diameter of a few tens of microns, it supports so-called whispering gallery modes near its circumference, for which quality factors up to 10 10 have been measured. In order to exploit the correspondingly low field damping rates for cavity QED, a method must be found to couple atomic or solid state emitters to these modes. S Göotzinger et al (pages 154--158) report the coupling of single nanocrystals on the surface of a microsphere through the evanescent field of the mode. Selective excitation of a single nano-emitter was accomplished with a scanning confocal microscope. The system is a promising candidate for cavity QED with single-quantum emitters. The ability to fully control the quantum dynamics of atoms and light is beginning to spawn early applications. The most notable example is quantum information processing. This requires the coherent manipulation of single-quantum systems, which is ideally provided by cavity QED interaction in the strong-coupling limit. The development of practical devices will be among the principal future tasks for research in the field. This will include physical systems, which have not been covered in this issue, such as semiconductors, quantum dots as emitters, or photonic crystals as resonator structures. Cavity QED is therefore guaranteed to remain a vigorous field in the years to come.
A microscopic system under continuous observation exhibits at random times sudden jumps between its states. The detection of this essential quantum feature requires a quantum non-demolition (QND) measurement1, 2, 3 repeated many times during the system evolution. Quantum jumps of trapped massive particles (electrons, ions or molecules4,5,6,7,8) have been observed, which is not the case of the jumps of light quanta. Usual photodetectors absorb light and are thus unable to detect the same photon twice. They must be replaced by a transparent counter 'seeing' photons without destroying them3. Moreover, the light has to be stored over a duration much longer than the QND detection time. We have fulfilled these challenging conditions and observed photon number quantum jumps. Microwave photons are stored in a superconducting cavity for times in the second range. They are repeatedly probed by a stream of non-absorbing atoms. An atom interferometer measures the atomic dipole phase shift induced by the non-resonant cavity field, so that the final atom state reveals directly the presence of a single photon in the cavity. Sequences of hundreds of atoms highly correlated in the same state, are interrupted by sudden state-switchings. These telegraphic signals record, for the first time, the birth, life and death of individual photons. Applying a similar QND procedure to mesoscopic fields with tens of photons opens new perspectives for the exploration of the quantum to classical boundary9, 10.
Up to now in this work we have not been concerned with the environment in which an atom and the radiation field interact. We have implicitly assumed that the radiation propagates in free space and that there are no boundaries to reflect radiation emitted by the atom. We shall show in this complement that when such boundaries do exist and are sufficiently reflecting, or more especially when the atom is enclosed in a resonant cavity, its radiative properties, such as its absorption spectrum and the rate of spontaneous emission, are drastically altered. This can be the case even if the cavity boundaries themselves are very far from the atom, on the atomic scale of distances. The conditions under which these cavity quantum electrodynamic effects can be observed are actually quite difficult to reach and this is why, usually, it is possible to assume that the radiative properties of a system are independent of the enclosure surrounding it. Nevertheless, thanks to some outstanding technical achievements, these effects can be observed in remarkable experiments. Atoms coupled to cavities then appear as a promising system in quantum information either for quantum processing or for single photon sources (see Complement 5E). Presentation of the problem Consider the system sketched in Figure 6B.1, in which an atom at rest at the origin of coordinates is enclosed in a cavity of volume V , with perfectly reflecting walls.
It was first realized by Purcell (1) that the spontaneous emission rate of a quantum system can be enhanced or suppressed by placing it in a resonant radiofrequency cavity. Spontaneous emission as it was first theoretically described by Einstein (2) is not a pure property of matter. It is described by matter coupled to quantized radiation field modes, which can be manipulated in an artificial structure such as a cavity. Cavity quantum electrodynamics (QED) is used to describe such effects that intimately depend on the fact that light is made of photons. Cavity QED has been extensively studied in atoms and the experimental proof was awarded with the Nobel Prize in 2012 (3). It has been applied to cooling of single atoms and for the detection of single atoms and creating and studying states with few photons and few atoms (4). In more recent developments these ideas have been extended to manipulate electronic states (5) and vibrations in molecules (6, 7). In PNAS, Flick et al. (8) introduce recent theoretical developments for the application of cavity QED to molecules and suggest possible novel applications to photochemistry. These include nonadiabatic dynamics of molecules in cavities, the modification of molecular properties, and the integration of QED with density functional theory.
A quantized electromagnetic field mode can be described as a harmonic oscillator whose coordinate is the electric field displacement (Fig. 1 A ). The zero point energy translates into a nonvanishing field intensity ⟨ e 2 ⟩ in the ground state | 0 ⟩ (vacuum fluctuations). The electric vacuum field increases for a small cavity volume e c = ℏ ω c V ϵ 0 , [1]
Fig. 1.
( A ) Illustration of the standing wave cavity mode and the resulting field quantization (Fock states). ( B ) Combined matter-field states (dressed states, | ± , n ⟩ …
[↵][1]1To whom correspondence should be addressed. Email: smukamel{at}uci.edu.
[1]: #xref-corresp-1-1
During these three years we focused on several topics in quantum otpics and quantum electrodynamics. A central theme in our investigations is that of the photon wave function. Can quantum optics and quantum electrodynamics experiments be described simply, in position space, with the help of a wave function describing the photon(s) featured in the experiment ? The answer to that question is not quite obvious: the usual description of photons takes place in the reciprocal space of wave vectors. But these experiments call for a wave mechanical description in the position representation, as is done in quantum mechanics textbooks in situations featuring massive particles. Moreover, in a recent experiment [1], single photon trajectories through a Young two-slit setup have been observed. In order to try and describe these trajectories formally, it is natural to build a wave mechanical formalism for photons. We therefore studied in detail the formal construction of the photon wave function, an object which was little studied until the 1990s. We also studied the properties of the photon wave function in the presence of sources.To do that, we considered several open (interacting) quantum systems. We saw that there exists in principle an infinite number of possibilities when defining the photon wave function. We emphasised several criteria on the basis of which it appears that only three choices for the wave function are interesting. One of them coincides with an object introduced and used by Glauber [2] to study light detection andthe correlations of the electromagnetic field in the quantum regime. We also saw that, in the absence of sources, the propagation equation for a single photon is formally equivalent to Maxwell’s equations. At low photon numbers, the wave function formalism can be very useful. We adapted it to interacting systems,first, to cavity quantum electrodynamics (QED) [3], in particular to the experiments carried out by Serge Haroche’s group [4]. We proposed a simple model to describe photons in QED cavities. With this model, and with the helpof the photon wave function, we studied the propagation of photons escaping a cavity. We also constructed the Lindblad master equation without introducing nonunitary quantum jumps (also see [5]). We finally investigated the spacetime evolution of a photon which is emitted during the decay of an atomic electron. After having carefully studied the dynamics of the electronic decay, especially at very short times [6, 7], we set out to describe the emitted electromagnetic field as rigorously as possible. This emitted field, surprisingly, does not evolve causally. Though this is not entirely unexpected in view of Hegerfeldt’s theorem, which states [8] that causality is impossible for quantum systems which are described by a Hamiltonian with a spectrum which is bounded by below, we identified [9] two other sources of non causality. One of them was predicted qualitatively by Shirokov [10], while the other one, which is completely new as far as we can tell, is still to be better understood
Cavity quantum electrodynamics (QED), the system of a single atom interacting with a single mode of a high finesse optical resonator, has tremendous potential for use in quantum logic, quantum information processing, and in enabling observation of quantum mechanical effects in the laboratory. The work of this thesis demonstrates a number of steps toward realizing these goals, by employing an experimental system with the strongest atom-field coupling achieved to date in optical cavity QED. The effects of strong coupling in cavity QED are studied for single cold atoms measured one at a time, in real time. The passage of single atoms through the cavity is employed to map out the frequency response of the system, and to demonstrate that quantum rather than semiclassical theory provides the correct theoretical model. The mechanical effects of strong coupling on single atoms are explored, these experiments demonstrating the first trapping of single atoms with single photons. Additionally, strong coupling enables high signal-to-noise ratio for monitoring atomic position at single photon field strengths; this capability is employed to investigate the motion of atoms trapped within the cavity. The transmitted cavity field is used to reconstruct the trajectories of single atoms, thereby realizing a new form of microscopy - the Atom-Cavity Microscope. Technical developments necessary to create the cavities used in this experiment are detailed. Ideas for future extensions to the experiment are proposed; a zero light-shift dipole force trap, and measurement of photon statistics of a single strongly coupled atom (which realizes a photon blockade device) are discussed.