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Applied Physics Research

Previously Unknown Physical Formulas which Hold in a Hydrogen Atom and are Derived without Using Quantum Mechanics

Koshun Suto

Published Jul 19, 2017• 2 citations
Publisher

Abstract

It is thought that quantum mechanics is the physical science describing the behavior of the electron in the micro world, e.g., inside a hydrogen atom. However, the author has previously derived the energy-momentum relationship which holds inside a hydrogen atom. This paper uses that relationship to investigate the relationships between physical quantities which hold in a hydrogen atom. In this paper, formulas are derived which hold in the micro world and make more accurate predictions than the classical quantum theory. This paper concludes that quantum mechanics is not the only theory enabling investigation of the micro world.

DOI
10.5539/apr.v9n4p7

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It is thought that quantum mechanics is the physical science describing the behavior of the electron in the micro world, e.g., inside a hydrogen atom. However, the author has previously derived the energy-momentum relationship which holds inside a hydrogen atom. This paper uses that relationship to investigate the relationships between physical quantities which hold in a hydrogen atom. In this paper, formulas are derived which hold in the micro world and make more accurate predictions than the classical quantum theory. This paper concludes that quantum mechanics is not the only theory enabling investigation of the micro world.
Despite its successes, quantum mechanics (QM) has remained mysterious to all who have encountered it. Starting with Bohr and progressing into the present, the departure from intuitive, physical reality has widened. The connection between QM and reality is more than just a “philosophical” issue. It reveals that QM is not a correct or complete theory of the physical world and that inescapable internal inconsistencies and incongruities arise when attempts are made to treat it as physical as opposed to a purely mathematical “tool.” Some of these issues are discussed in a review by F. Laloe [Am. J. Phys. 69, 655 (2001)]. In an attempt to provide some physical insight into atomic problems and starting with the same essential physics as Bohr of e moving in the Coulombic field of the proton and the wave equation as modified by Schrodinger, a classical approach is explored that yields a remarkably accurate model and provides insight into physics on the atomic level. The proverbial view, deeply seated in the wave-particle duality notion, that there is no large-scale physical counterpart to the nature of the electron may not be correct. Physical laws and intuition may be restored when dealing with the wave equation and quantummechanical problems. Specifically, a theory of classical quantum mechanics (CQM) is derived from first principles that successfully applies physical laws on all scales. Rather than using the postulated Schrodinger boundary condition “Ψ → 0 as r → ∞,” which leads to a purely mathematical model of the electron, the constraint is based on experimental observation. Using Maxwell’s equations, the classical wave equation is solved with the constraint that the bound (n = 1)state electron cannot radiate energy. By further application of Maxwell’s equations to electromagnetic and gravitational fields at particle production, the Schwarzschild metric is derived from the classical wave equation, which modifies general relativity to include conservation of spacetime in addition to momentum and matter/energy. The result gives a natural relationship among Maxwell’s equations, special relativity, and general relativity. CQM holds over a scale of spacetime of 85 orders of magnitude — it correctly predicts the nature of the universe from the scale of the quarks to that of the cosmos. A review is given by G. Landvogt [Internat. J. Hydrogen Energy 28, 1155 (2003)].
In the scientific community dominates the conviction that the hydrogen atom is the simplest, and existing theories based on equations of Schrodinger and Dirac fully describe all the subtleties of behavior of an electron in a hydrogen atom. In this paper and in the following articles will be shown that in addition to the known state-based solutions of the Schrodinger and Dirac equations, there are states which were not studied and they were not known, or often simply were discarded with the phrase have no physical meaning. Further it will be shown that the existing equations of quantum mechanics, namely the Dirac equation, Klein-Gordon equation and especially the Schrodinger equation, can not accurately describe all the subtleties of behavior of an electron in a hydrogen atom. As a result there will be given a reasonable basis for the feasibility of an experimental search or targeted synthesis of new unknown states of the hydrogen atom.
Quantum Mechanics and its Interpretations Peter E. Hodgson (bio) Quantum Mechanics is an elegant and indeed beautiful formalism, and enables the results of many physical measurements to be calculated with great accuracy. But from the earliest days there has been intense debate about the interpretation of quantum mechanics, and it shows no signs of being settled; if anything, it is becoming more intense over the years. It should therefore be evident that the most that can be done here is to try to show where the real difficul-ties lie, and how the failure to recognize that quantum mechanics is an essentially statistical theory has led to a series of confusing quantum paradoxes. It is just these paradoxes that have often been used to support theological speculations. The Discovery of the Quantum The quantum nature of the physical world was discovered by Max Planck in the early years of the twentieth century. He was studying thermodynamics and his attention was drawn to the frequency distribution of black-body radiation. This radiation is emitted from a small hole in a heated enclosure with rough walls, which ensures [End Page 62] that the radiation reaches statistical equilibrium before emission. The frequency distribution is found to be independent of the material lining the walls of the oven, so Planck realized that it must be a fundamental characteristic of all matter. This frequency distribution had been measured by several experimentalists, and Planck resolved to try to see how it can be derived theoretically. Already Rayleigh and Jeans had used classical radiation theory to derive an expression that fitted the data well at low frequencies but tended to infinity at high energies, which was of course unacceptable. The physicist Wien had derived a formula that fitted the data at high frequencies but failed at low frequencies. Planck used an ingenious argument based on entropy to interpolate between these two formulae and obtained a formula, now known as the Planck distribution, that fitted the data perfectly. His next task was to understand the physics behind his formula. He used the familiar technique of assuming that the energy is emitted in small finite amounts, and then let their size tend to zero, so as to represent a continuous distribution. To his great surprise, the intermediate formula with discrete amounts of energy, called quanta, gave the Planck distribution, but the final result, with infinitely small quanta, did not. All his instincts as a physicist rebelled against this conclusion. Surely energy must be emitted continuously. He tried hard to find a way to avoid this unwelcome conclusion, but without success. He had to admit that it is a feature of the world. Soon it was confirmed by Einstein’s interpretation of the photoelectric effect. This story shows clearly that physicists do not impose their ideas on the world, but recognize and accept what they find, whether or not it agrees with their original ideas. The world is made by God in ways that often we cannot imagine. [End Page 63] The Old Quantum Theory A few years later Rutherford discovered that the atom has a small central nucleus containing most of its mass surrounded by a number of electrons. Bohr used the idea of the quantum to build his model of the atom. He assumed that the electrons go around the nucleus in discrete orbits, and that radiation is emitted when an electron falls from one orbit to a lower one. With this model, he was able to calculate to high accuracy the frequencies of the radiation emitted from an excited hydrogen atom. This was a great achievement, but to get his result he had to assume that the electrons stayed in their orbits, whereas classical theory predicted that they would continuously lose energy and rapidly spiral into the nucleus. Quantum Mechanics and its Interpretations These problems were solved by the development of quantum mechanics in the 1920s by Heisenberg, Schrodinger, Dirac, and others. This enabled what is called the wave function to be calculated for any physical system, and from the wave function the probabilities of occurrence of measurable quantities can be found. It is a beautiful theory, and is the indispensable means of calculation for atomic, nuclear...
The hydrogen atom is the Rosetta stone of the early twentieth century atomic physics. The attempt to decipher its structure and properties led to the development of quantum mechanics and the unraveling of many of the mysteries of atomic, molecular, and solid state physics, and a good deal of chemistry and modern biology. Unlike the various one-dimensional model problems that we have been studying in the previous chapters, the hydrogen atom is a real physical system in three dimensions. It consists of an electron moving in a spherically symmetric potential well due to the Coulomb attraction of the positively charged nucleus. In three dimensions, the electron is not constrained to move linearly. It can execute orbital motions and, thus, has angular momentum. Not only is the total energy of the electron in the atom quantized, its angular momentum also has interesting and unexpected quantized properties that cannot possibly be understood on the basis of classical mechanics and electrodynamics. They are, however, the natural and necessary consequences of the basic postulates of quantum mechanics, as will be shown in this chapter. According to classical mechanics and electrodynamics, it is not possible to have a stable structure consisting of a small positively charged nucleus at the center of an electrically neutral atom with an electron sitting in its vicinity. For the electron not to be attracted into the positive charge, it must be orbiting around the nucleus so that the centrifugal force will counter the Coulomb attraction of the nucleus and maintain a constant electron orbit.
Bohr’s quantum condition is an indispensable assumption for classical quantum theory. However, strictly speaking, Bohr's quantum condition does not hold when deriving the energy of an electron forming a hydrogen atom from the perspective of the theory of relativity. In this paper, it is thought that the relationship enfolded in Bohr's quantum condition, i.e., is suitable as a new quantum condition to replace Bohr’s quantum condition. Also, in quantum mechanics, the energy of an electron is derived based on the theory of relativity, as exemplified in the theory of Sommerfeld. However, this paper points out that the previous energy formula based on the theory of relativity is mistaken. It also proposes a previously unknown formula for the kinetic energy of an electron.
Over the course of the past century, quantum mechanics has become extremely successful in describing the atoms and elementary particles that make up the world that we know.Strange enough, the current model of quantum mechanics doesn't allow things that are real, to be described in terms of things that are real.A theory that describes things as they really are is more likely to be true and successful.Therefore, while it is hard to say that quantum mechanics is wrong, our interpretation of it is rather unsatisfactory.The present paper proposes an interpretation of quantum mechanics whereby the matter wave and its eigenstates are formed through an underlying, bifurcative self-interaction of the quantum field.Subsequently it will be shown that based on the latter the proton-to-electron mass ratio can accurately be calculated.