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Applied Mathematics

Canonical Transformations, Quantization, Mutually Unbiased and Other Complete Bases

Donald Jack Kouri, Cameron L. Williams, Nikhil Pandya

Published Jan 1, 2017• 1 citation
Publisher

Abstract

Using ideas based on supersymmetric quantum mechanics, we design canonical transformations of the usual position and momentum to create generalized “Cartesian-like” positions, W, and momenta, Pw , with unit Poisson brackets. These are quantized by the usual replacement of the classical , x Px by quantum operators, leading to an infinite family of potential “operator observables”. However, all but one of the resulting operators are not Hermitian (formally self-adjoint) in the original position representation. Using either the chain rule or Dirac quantization, we show that the resulting operators are “quasi-Hermitian” relative to the x-representation and that all are Hermitian in the W-representation. Depending on how one treats the Jacobian of the canonical transformation in the expression for the classical momentum, Pw , quantization yields a) continuous mutually unbiased bases (MUB), b) orthogonal bases (with Dirac delta normalization), c) biorthogonal bases (with Dirac delta normalization), d) new W-harmonic oscillators yielding standard orthonormal bases (as functions of W) and associated coherent states and Wigner distributions. The MUB lead to W-generalized Fourier transform kernels whose eigenvectors are the W-harmonic oscillator eigenstates, with the spectrum (±1,±i) , as well as “W-linear chirps”. As expected, W, Pw satisfy the uncertainty product relation: ΔWΔPw ≥1/2 , h=1.

DOI
10.4236/am.2017.87071

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Using ideas based on supersymmetric quantum mechanics, we design canonical transformations of the usual position and momentum to create generalized “Cartesian-like” positions, W, and momenta, Pw , with unit Poisson brackets. These are quantized by the usual replacement of the classical , x Px by quantum operators, leading to an infinite family of potential “operator observables”. However, all but one of the resulting operators are not Hermitian (formally self-adjoint) in the original position representation. Using either the chain rule or Dirac quantization, we show that the resulting operators are “quasi-Hermitian” relative to the x-representation and that all are Hermitian in the W-representation. Depending on how one treats the Jacobian of the canonical transformation in the expression for the classical momentum, Pw , quantization yields a) continuous mutually unbiased bases (MUB), b) orthogonal bases (with Dirac delta normalization), c) biorthogonal bases (with Dirac delta normalization), d) new W-harmonic oscillators yielding standard orthonormal bases (as functions of W) and associated coherent states and Wigner distributions. The MUB lead to W-generalized Fourier transform kernels whose eigenvectors are the W-harmonic oscillator eigenstates, with the spectrum (±1,±i) , as well as “W-linear chirps”. As expected, W, Pw satisfy the uncertainty product relation: ΔWΔPw ≥1/2 , h=1.
We consider the problem of designing a variety of "system guided" basis sets for quantum mechanical anharmonic oscillators. Using ideas based on supersymmetric quantum mechanics, we design canonical transformations of the usual position and momentum to generate generalized "Cartesian-like positions, W and momenta, p_W" with unit Poisson brackets. These are quantized following Dirac, leading to an infinite family of potential "operator observables". The fundamental issue is that all but one of the operators are not Hermitian (formally self-adjoint) in the original position representation. We show that the resulting operators are "quasi-Hermitian" relative to the x-representation and that all are Hermitian in the W-representation. Depending on how one treats the Jacobian of the canonical transformation in the expression for the classical momentum, p_W, quantization yields a) continuous mutually unbiased bases (MUB) b) orthogonal bases (with Dirac delta normalization) c) biorthogonal bases (with Dirac delta normalization) d) new W-harmonic oscillators yielding standard orthonormal bases (as functions of W) and associated coherent states. The MUB include W-generalized Fourier transform kernels whose eigenvectors are the W-harmonic oscillator eigenstates, with the spectrum (p/m i, p/m i). The W, p_W satisfy the uncertainty product relation: Delta-W * Delta-p_W gte 1/2.
The commutator of position and momentum operators is first considered in the coordinate and momentum representations, and then in an abstract Hilbert space. The reader is then introduced to canonical operators with the associated canonical quantization of commutation rules, which consists of maps defined on a symplectic space and taking values in the set of unitary operators on a Hilbert space. If the symplectic space is finite-dimensional, all of its irreducible representations are unitarily equivalent. The Weyl exponentiated form of the commutation relations is described and investigated. One then arrives at the definition of Weyl systems, and it is shown how to recover from them the formulation in terms of self-adjoint operators which satisfy a generalized form of commutation relations. Further topics are the Heisenberg representation for temporal evolution and the generalized uncertainty relations. Unitary operators associated with symplectic linear transformations are then considered, and, within this framework, translations, rotations and the harmonic oscillator are considered. The Weyl programme is then reassessed. Lastly, the basic postulates of modern quantum theory are eventually studied: the probabilistic nature of the predictions of results of measurements; the correspondence between observables and self-adjoint operators on Hilbert spaces; the expected result of measuring an observable quantity; and the evolution of the state vector in systems which are not affected by any external influence. The chapter ends with an outline of rigged Hilbert space formalism and its applications. The commutator in wave mechanics In the first part of this book we studied wave mechanics within the framework of the Schrödinger equation.
The usual form P0 for the quantum-mechanical operator P conjugate to a generalized coordinate q1 is, in atomic units, P0=−ig−12 ∂/∂q1(g12),where g is the Jacobian of the transformation from Cartesian coordinates to the generalized coordinates. However, in some cases, this plusible form for P is not Hermitian with respect to physically acceptable bound-state wavefunctions, as it must be if it is to represent a real observable quantity. In this paper, the general form P=−i(A·grad+12 div A)is justified. Here A = h1q̂1, where h1 is the metric scale factor corresponding to q1, and q̂1 is the unit vector in the direction of increasing q1. This general form reduces to P0 if the usual formula for the divergence is applied. In the cases where P0 is not Hermitian, it transpires that q̂1 is ill-defined at one or both of the end points α and β of the range of q1, and the divergence formula is thus invalid at such points. It is shown that, in order to obtain a Hermitian form for P, certain terms involving delta functions similar to Dirac's must be added to the usual formula for div A. These terms can be regarded as implicit in div A. If q̂1 is ill-defined at the lower limit q1 = α, then the resulting new Hermitian form for P, which we propose as the correct one, is P=−i[g−12 ∂/∂q1(g12)+12 δ+(q1−α)]. If q̂1 is, in addition, ill-defined at the upper limit q1 = β, then the extra term +½i δ_(β − q1) must be added. Corresponding new forms are obtained for the Laplacian operator. In addition, the new formulas for P are applied to hypervirial relations. In the Appendix, Charles Goebel obtains a similar expression for the momentum operators by replacing the metric scale function by θg where θ is a step function, unity inside and zero outside the range of definition of the generalized coordinates. The differentiation of θ then produces the delta functions.
A previously developed novel theory for the formal canonical quantization of classically dissipating systems will be the starting point for a detailed discussion of the quantum statistical aspects of the simple linearly damped harmonic oscillator. The formalism essentially involves complex classical canonical coordinates and momenta, and thus quite naturally leads to the possibility of creation and annihilation operators. Furthermore, the occurrence of quantal noise operators appears to be of principal importance for the conservation of the fundamental commutator in the course of time, as will be expressed in a simple fluctuation-dissipation relation. Making a canonical transformation back to the real, Cartesian Hermitian position and momentum an "effective" Hermitian Hamiltonian will be derived, with which a transformation is made from the Heisenberg frame to the Schr\"odinger frame where the density operator equation will be computed. This will make it obvious that no proper Schr\"odinger equation exists for the dissipative subsystem on its own, thus reflecting an incomplete knowledge. The master equation will then be translated into its Wigner representation. The intimate connection between the diffusion coefficients in the resulting Fokker-Planck equation and the uncertainty relation will be demonstrated in a clear fashion.
The development of supersymmetric (SUSY) quantum mechanics has shown that some of the insights based on the algebraic properties of ladder operators related to the quantum mechanical harmonic oscillator (QMHO) carry over to the study of more general systems. At this level of generality, pairs of eigenfunctions of so-called partner Hamiltonians are transformed into each other, but the entire spectrum of any one of them cannot be deduced from this intertwining relationship in general – except in special cases. In this paper, we present a more general structure that provides all eigenvalues for a class of Hamiltonians that do not factor into a pair of operators satisfying canonical commutation relations. Instead of a pair of partner Hamiltonians, we consider two pairs that differ by an overall shift in their spectrum. This is called coupled supersymmetry. In that case, we also develop coherent states and present some uncertainty principles which generalise the Heisenberg uncertainty principle. Coupled SUSY is explicitly realised by an infinite family of differential operators which admit orthonormal bases of eigenfunctions of generalised harmonic oscillators.
In this work we take a closer look at the algebraic-operator correspondence between the momentum space and the position space which defines the form of the canonical momentum operator in position space in Quantum Mechanics (QM). Starting from the Fourier transform (FT) relationship, we present a Hermitian generalization of the canonical momentum operator in position space. The action of the generalized operator is found to generate a local flow accompanied by position-dependent rescaling, rather than a global translation. Explicit eigenfunctions are obtained for representative cases and are shown to possess a well-defined limit to the plane-wave solution in QM. As an illustration, the infinite square well problem is solved using the generalized operator, yielding a deformed spectrum that has a smooth limit to the standard QM result.