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The Japan Society of Applied Physics

Diamond films growth for single photon emitter formation

Tokuyuki Teraji

Published Feb 6, 2014• 0 citations
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physica status solidi (a)•Sep 20, 2026•0 citations
AlN is a promising material for integrated quantum photonics due to its broad transparency window, its compatibility with CMOS technology, and the possibility to host localized light emitters acting as single photon sources. However, little is understood yet about the microscopic nature and formation mechanisms of these light emitters. In this contribution, we demonstrate that their formation efficiency depends significantly on the growth conditions of the AlN thin film. We reveal that localized light emitters with distinct zero-phonon lines in the 600--800~nm range can be efficiently formed in epitaxial AlN thin films grown under N-rich conditions by exposing the AlN to a post-growth treatment consisting in a proton irradiation followed by an annealing process. In contrast, the density of light emitters formed in AlN grown under Al-rich conditions remains low, even after the thin films have been exposed to the post-growth treatment. These results open a pathway toward a better understanding of the microscopic nature of these light emission centers, as well as their engineered integration as quantum light sources in AlN-based optomechanical platforms.
A method for obtaining luminescent diamond nanoparticles doped with germanium from nanocrystalline diamond (NCD) films grown by microwave plasma‐assisted chemical vapor deposition (MPCVD) is presented. Thermal etching in the presence of an alkali metal nitrate enables the selective disruption of intercrystallite boundaries, resulting in the formation of individual particles without mechanical grinding. Structural and morphological characterization by scanning and transmission electron microscopy, atomic force microscopy, Raman spectroscopy, and dynamic light scattering reveals the formation of particles with characteristic sizes down to ~100 nm, along with a minor fraction of larger microcrystals. The particles retain the crystalline quality of the parent film and exhibit photoluminescence associated with Ge‐V and Si‐V centers. Second‐order correlation measurements reveal single‐photon emission from a minority of Ge‐V‐related diffraction‐limited spots, demonstrating the presence of isolated optically active Ge‐V emitters in the nanoparticle sample. The proposed approach provides a scalable route for producing luminescent diamond nanoparticles for photonic and quantum applications.