Optically addressable spins at material surfaces have represented a long-standing ambition in quantum sensing, providing atomic resolution and quantum-limited sensitivity. However, they are constrained by a finite depth at which the quantum spins can be stabilized. Here, we demonstrate a hybrid molecular-2D architecture that realizes quantum spin sensors directly on top of the surface. By anchoring spin-active molecules onto hexagonal boron nitride (hBN), we eliminate the depth of the quantum sensor while also exhibiting robust spin properties from 4~K to room temperature (RT). The Hahn-echo spin coherence time exceeds $T_2 = 3.4~\upmu\text{s}$ at 4~K, outperforming values in bulk organic crystals and overturning the prevailing expectation that spin inevitably deteriorates upon approaching the surface. By chemically tuning the molecule through deuteration, $T_2$ improves by more than 10-fold, and under dynamic decoupling, coherence is prolonged to the intrinsic lifetime limit, exceeding 300~$\upmu\text{s}$. Proximal proton spins and the magnetic response of two-dimensional magnets beneath the hBN layer have been detected at RT. These molecular spins form surface quantum sensors with long coherence, optical addressability, and interfacial versatility, enabling a scalable, adaptable architecture beyond what conventional solid-state platforms offer.Optically addressable spins at material surfaces have represented a long-standing ambition in quantum sensing, providing atomic resolution and quantum-limited sensitivity. However, they are constrained by a finite depth at which the quantum spins can be stabilized. Here, we demonstrate a hybrid molecular-2D architecture that realizes quantum spin sensors directly on top of the surface. By anchoring spin-active molecules onto hexagonal boron nitride (hBN), we eliminate the depth of the quantum sensor while also exhibiting robust spin properties from 4~K to room temperature (RT). The Hahn-echo spin coherence time exceeds $T_2 = 3.4~\upmu\text{s}$ at 4~K, outperforming values in bulk organic crystals and overturning the prevailing expectation that spin inevitably deteriorates upon approaching the surface. By chemically tuning the molecule through deuteration, $T_2$ improves by more than 10-fold, and under dynamic decoupling, coherence is prolonged to the intrinsic lifetime limit, exceeding 300~$\upmu\text{s}$. Proximal proton spins and the magnetic response of two-dimensional magnets beneath the hBN layer have been detected at RT. These molecular spins form surface quantum sensors with long coherence, optical addressability, and interfacial versatility, enabling a scalable, adaptable architecture beyond what conventional solid-state platforms offer.

quant-pharXiv:2601.19988Jan 29, 2026

Molecular interferometry experiments

Ch. J. Bordé, N. Courtier, Frédéric Du-Burck +2 more

Physics Letters AMay 1, 199493 citations

Anomalous thermal decoherence in a quantum magnet measured with neutron spin echo spectroscopy

Felix Groitl, T. Keller, Katharina Rolfs +2 more

The effect of temperature dependent asymmetric line broadening is investigated in $\mathrm{Cu}({\mathrm{NO}}_{3}{)}_{2}\ifmmode\cdot\else\textperiodcentered\fi{}2.5{\mathrm{D}}_{2}\mathrm{O}$, a model material for a one-dimensional bond alternating Heisenberg chain, using the high resolution neutron-resonance spin echo (NRSE) technique. Inelastic neutron scattering experiments on dispersive excitations including phase sensitive measurements demonstrate the potential of NRSE to resolve line shapes, which are non-Lorentzian, opening up a new and hitherto unexplored class of experiments for the NRSE method beyond standard linewidth measurements. The particular advantage of NRSE is its direct access to the correlations in the time domain without convolution with the resolution function of the background spectrometer. This application of NRSE is very promising and establishes a basis for further experiments on different systems, since the results for Cu( ${\mathrm{NO}}_{3}$ )${}_{2}\ifmmode\cdot\else\textperiodcentered\fi{}2.5{\mathrm{D}}_{2}\mathrm{O}$ are applicable to a broad range of quantum systems.The effect of temperature dependent asymmetric line broadening is investigated in $\mathrm{Cu}({\mathrm{NO}}_{3}{)}_{2}\ifmmode\cdot\else\textperiodcentered\fi{}2.5{\mathrm{D}}_{2}\mathrm{O}$, a model material for a one-dimensional bond alternating Heisenberg chain, using the high resolution neutron-resonance spin echo (NRSE) technique. Inelastic neutron scattering experiments on dispersive excitations including phase sensitive measurements demonstrate the potential of NRSE to resolve line shapes, which are non-Lorentzian, opening up a new and hitherto unexplored class of experiments for the NRSE method beyond standard linewidth measurements. The particular advantage of NRSE is its direct access to the correlations in the time domain without convolution with the resolution function of the background spectrometer. This application of NRSE is very promising and establishes a basis for further experiments on different systems, since the results for Cu(${\mathrm{NO}}_{3}$)${}_{2}\ifmmode\cdot\else\textperiodcentered\fi{}2.5{\mathrm{D}}_{2}\mathrm{O}$ are applicable to a broad range of quantum systems.

arXiv:1602.08223Physical review. B./Physical review. BApr 4, 20167 citations

In situRamsey interferometry and diffraction echo with an atomic Fermi gas

C. Marzok, Benjamin Deh, Sebastian Slama +2 more

We report on the observation of Bragg diffraction of a spin-polarized ultracold $^{6}\mathrm{Li}$ Fermi gas and demonstrate a Ramsey-type matter-wave interferometer. Suppression of $s$ -wave collisions by the Pauli principle allows for unperturbed dynamics of the atoms in the trap for longer than $2\phantom{\rule{0.3em}{0ex}}\mathrm{s}$ . Employing an echo pulse sequence, we observe coherent superpositions of momentum states which do not show any sign of decoherence during the experimentally limited observation time of $100\phantom{\rule{0.3em}{0ex}}\ensuremath{\mu}\mathrm{s}$. In contrast, significant decoherence is observed in the presence of a cold cloud of $^{87}\mathrm{Rb}$ atoms. The experiment demonstrates the feasibility of high-resolution atomic interferometry with applications for precision measurements in small volumes and near surfaces.We report on the observation of Bragg diffraction of a spin-polarized ultracold $^{6}\mathrm{Li}$ Fermi gas and demonstrate a Ramsey-type matter-wave interferometer. Suppression of $s$-wave collisions by the Pauli principle allows for unperturbed dynamics of the atoms in the trap for longer than $2\phantom{\rule{0.3em}{0ex}}\mathrm{s}$. Employing an echo pulse sequence, we observe coherent superpositions of momentum states which do not show any sign of decoherence during the experimentally limited observation time of $100\phantom{\rule{0.3em}{0ex}}\ensuremath{\mu}\mathrm{s}$. In contrast, significant decoherence is observed in the presence of a cold cloud of $^{87}\mathrm{Rb}$ atoms. The experiment demonstrates the feasibility of high-resolution atomic interferometry with applications for precision measurements in small volumes and near surfaces.

arXiv:0804.0532Physical Review AAug 12, 20085 citations

T_2

improves by more than 10-fold, and under dynamic decoupling, coherence is prolonged to the intrinsic lifetime limit, exceeding 300~$\upmu\text{s}$. Proximal proton spins and the magnetic response of two-dimensional magnets beneath the hBN layer have been detected at RT. These molecular spins form surface quantum sensors with long coherence, optical addressability, and interfacial versatility, enabling a scalable, adaptable architecture beyond what conventional solid-state platforms offer.

{\mathrm{NO}}_{3}

)${}_{2}\ifmmode\cdot\else\textperiodcentered\fi{}2.5{\mathrm{D}}_{2}\mathrm{O}$ are applicable to a broad range of quantum systems.

We report on the observation of Bragg diffraction of a spin-polarized ultracold

^{6}\mathrm{Li}

Fermi gas and demonstrate a Ramsey-type matter-wave interferometer. Suppression of

s

-wave collisions by the Pauli principle allows for unperturbed dynamics of the atoms in the trap for longer than

2\phantom{\rule{0.3em}{0ex}}\mathrm{s}

. Employing an echo pulse sequence, we observe coherent superpositions of momentum states which do not show any sign of decoherence during the experimentally limited observation time of $100\phantom{\rule{0.3em}{0ex}}\ensuremath{\mu}\mathrm{s}$. In contrast, significant decoherence is observed in the presence of a cold cloud of

^{87}\mathrm{Rb}

atoms. The experiment demonstrates the feasibility of high-resolution atomic interferometry with applications for precision measurements in small volumes and near surfaces.