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Nova acta Leopoldina

Structure, entropy and quantum theory

Ilya Prigogine

Published Jan 1, 1972• 2 citations
OpenAlex

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Remarks on the entropy in quantum macrophysics

K. Urbanik

Colloquium Mathematicum•Jan 1, 1964•0 citations
This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized Probabilistic Theories". For these theories, a thought experiment by von Neumann is adapted to obtain a natural thermodynamic entropy definition, following a proposal by J. Barrett. Mathematical properties of this entropy are compared to physical consequences of the thought experiment. The validity of the second law of thermodynamics is investigated. In that context, observables and projective measurements are generalized to prove an entropy increase for projective measurements of ensembles. Information-theoretically motivated definitions of the entropy are compared to the entropy from the thermodynamic thought experiment. The conditions for the thermodynamic entropy to be well-defined are considered in greater detail. Several further properties of the theories under consideration (e.g. whether there is higher order interference, Pfister's state discrimination principle) and their relation to entropy are investigated.
Causal structures give us a way to understand the origin of observed correlations. These were developed for classical scenarios, but quantum mechanical experiments necessitate their generalisation. Here we study causal structures in a broad range of theories, which include both quantum and classical theory as special cases. We propose a method for analysing differences between such theories based on the so-called measurement entropy. We apply this method to several causal structures, deriving new relations that separate classical, quantum and more general theories within these causal structures. The constraints we derive for the most general theories are in a sense minimal requirements of any causal explanation in these scenarios. In addition, we make several technical contributions that give insight for the entropic analysis of quantum causal structures. In particular, we prove that for any causal structure and for any generalised probabilistic theory, the set of achievable entropy vectors form a convex cone.
Causal structures give us a way to understand the origin of observed correlations. These were developed for classical scenarios, but quantum mechanical experiments necessitate their generalisation. Here we study causal structures in a broad range of theories, which include both quantum and classical theory as special cases. We propose a method for analysing differences between such theories based on the so-called measurement entropy. We apply this method to several causal structures, deriving new relations that separate classical, quantum and more general theories within these causal structures. The constraints we derive for the most general theories are in a sense minimal requirements of any causal explanation in these scenarios. In addition, we make several technical contributions that give insight for the entropic analysis of quantum causal structures. In particular, we prove that for any causal structure and for any generalised probabilistic theory, the set of achievable entropy vectors form a convex cone.