We study the Majorana surface states of higher-spin topological superconductors (TSCs) that could be realized in ultracold atomic systems or doped semimetals with spin-orbit coupling. As a paradigmatic example, we consider a model with
p-wave pairing of spin-3/2 fermions that generalizes $^{3}\mathrm{He}\ensuremath{-}B$. This model has coexisting linear and cubic dispersing Majorana surface bands. We show that these are unstable to interactions, which can generate a spontaneous surface thermal quantum Hall effect (TQHE). By contrast, nonmagnetic quenched disorder induces a surface conformal field theory (CFT) that is stable against weak interactions: topological protection is enhanced by disorder. Gapless surface states of higher-spin TSCs could therefore be robustly realized in solid-state systems, where disorder is inevitable. The surface CFT is characterized by universal signatures that depend only on the bulk topological winding number, and they include power-law scaling of the density of states, a universal multifractal spectrum of local density of states fluctuations, and a quantized ratio of the longitudinal thermal conductivity ${\ensuremath{\kappa}}_{xx}$ divided by temperature
T. By contrast, ${\ensuremath{\kappa}}_{xx}/T$ for the clean surface without TQHE order would diverge as $T\ensuremath{\rightarrow}0$. Since disorder stabilizes the conducting Majorana surface fluid and quantizes thermal transport, our results suggest a close analogy between bulk TSCs and the integer quantum Hall effect.
Superfluids and superconductors can be either fully gapped or gapless with nodal structures in momentum space. Both the gapped and nodal phases can be topologically protected and possess nontrivial topological invariants. Topological quantum phase transitions exist at zero temperature between different gapped phases or between gapped and nodal phases. These phase transitions can be driven by chemical potential and/or spin exchange fields. The two phases separated by the phase transition can have the same local order but differ in global topology. Thus, these topological quantum phase transitions cannot be described by the Landau paradigm of symmetry breaking. Although some aspects of these transitions, such as the change of topological invariants and gapless boundary states, have been discussed before, a complete theory of these transitions has yet to be developed. In this dissertation, we construct effective field theories to study the universality and thermodynamic signatures of these transitions. We find four different universality classes in superfluids and superconductors. Certain thermodynamic quantities, such as compressibility or spin susceptibility, change non-analytically across the transitions. For certain time-reversal symmetry breaking fields that lead to bulk phase transitions, there also exist topological phase transitions on the surface. All the topological phase transitions studied in this dissertation only exist at zero temperature. At finite temperature, different states are connected by smooth crossovers. There exists a quantum critical region at finite temperature near the quantum critical point (QCP). In this quantum critical region, thermodynamic quantities have universal scaling dependence on temperature dictated by the universality class of the QCP. We argue that these scaling properties can be used to probe and differentiate these QCPs. These bulk and surface topological quantum phase transitions are discussed in various concrete models, such as chiral and time-reversal invariant p-wave superfluids, topological superconductors of emergent Dirac fermions, and topological superconducting model of CuₓBi₂Se₃.