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Physical Review A

Thermal quantum transition-path-time distributions, time averages, and quantum tunneling times

Eli Pollak

Published Apr 10, 2017• 7 citations
Publisher

Abstract

The transition-path-time distribution is formalized for quantum systems and applied to a number of examples. Using a symmetrized thermal density, transition times are studied for the free particle, a $\ensuremath{\delta}$-function potential, a square-barrier potential, and symmetric-double-well dynamics at very low temperature. These studies exemplify extreme nonlocality for motion in $\ensuremath{\delta}$-function potentials, vanishing tunneling times for the square-barrier potential, and varying transit times in the symmetric-double-well potential. In all cases, there are regions where the longer the distance traversed, the shorter the mean transit time is. For the thermal density correlation functions studied here, the Hartman effect exemplifies itself through the independence of the transit time on the barrier height. However, due to the thermal distribution, the transit time does depend on the barrier width, initially decreasing with increasing width but then increasing again.

DOI
10.1103/physreva.95.042108

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The transition-path-time distribution is formalized for quantum systems and applied to a number of examples. Using a symmetrized thermal density, transition times are studied for the free particle, a \ensuremathδ\ensuremath{\delta}\ensuremathδ-function potential, a square-barrier potential, and symmetric-double-well dynamics at very low temperature. These studies exemplify extreme nonlocality for motion in \ensuremathδ\ensuremath{\delta}\ensuremathδ-function potentials, vanishing tunneling times for the square-barrier potential, and varying transit times in the symmetric-double-well potential. In all cases, there are regions where the longer the distance traversed, the shorter the mean transit time is. For the thermal density correlation functions studied here, the Hartman effect exemplifies itself through the independence of the transit time on the barrier height. However, due to the thermal distribution, the transit time does depend on the barrier width, initially decreasing with increasing width but then increasing again.
The standard approaches to tunneling times are replaced by considering time correlation functions. A class of correlation functions that is always positive is identified and used to define quantum mechanical transition time probability distributions. The formalism is used to study the quantum dynamics of a thermal position correlation function of a parabolic barrier Hamiltonian. The transition time probability distribution between two points distributed symmetrically about the barrier top shifts to shorter times as the temperature is reduced and tunneling is increased. A study of the mean transition time as a function of the distance between the center of the initial and final densities shows that when the temperature is sufficiently low and tunneling dominates the dynamics, increasing the length of the path traversed decreases the mean transition time. The introduction of friction to the dynamics does not "destroy" this phenomenon, except when the friction coefficient is very large.
We define, using a path-integral method, an amplitude distribution for the traversal time of a particle tunneling through a barrier. We calculate this without approximation for the case of a square barrier potential. The form of the integrated distribution is shown to be determined by the uncertainty principle: if the particle is known to spend a time \ensuremath{\le}\ensuremath{\tau} inside the barrier, then an effective uncertainty \ensuremath{\Delta}V is introduced in the barrier height, such that \ensuremath{\Delta}V\ensuremath{\tau}\ensuremath{\approxeq}\ensuremath{\Elzxh}. The distribution has a number of interesting properties: it is noisy at very short times, oscillates periodically at intermediate times, and saturates to a constant at long times. The first two properties arise as a result of resonances in the transmission amplitude, which play an important role in the distribution. The characteristic (median) time scale for the distribution is shown to be ${\mathrm{\ensuremath{\tau}}}_{\mathit{Q}}$=2md2{\mathit{md}}^{2}md2/\ensuremath{\Elzxh}. We show that this represents the average traversal time for particle energies that are close to the energy of the barrier height. For very opaque barriers, the oscillations have a very short period. We show that this can lead to anomalously short average traversal times, and resolves the outstanding problem that the average velocity of a tunneling particle may exceed the speed of light. For particles with energies above the height of the barrier (classical traversal), we find that the real part of the distribution is dominated by the classical path, and has a sharp peak around the classical traversal time. It is argued that the form of the distribution found in this work may be applied to general barrier shapes.
A quantum mechanical transition path time probability distribution is formulated and its properties are studied using a parabolic barrier potential model. The average transit time is well defined and readily calculated. It is smaller than the analogous classical mechanical average transit time, vanishing at the crossover temperature. It provides a direct route for determining tunneling times. The average time may be also used to define a coarse grained momentum of the system for the passage from one side of the barrier to the other. The product of the uncertainty in this coarse grained momentum with the uncertainty in the location of the particle is shown under certain conditions to be smaller than the ℏ/2 formal uncertainty limit. The model is generalized to include friction in the form of a bilinear interaction with a harmonic bath. Using an Ohmic friction model one finds that increasing the friction, increases the transition time. Only moderate values of the reduced friction coefficient are needed for the quantum transition time and coarse grained uncertainty to approach the classical limit which is smaller than ℏ/2 when the friction is not too small. These results show how one obtains classical dynamics from a pure quantum system without invoking any further assumptions, approximations, or postulates.
We derive the exact distribution of times spent in the classically forbidden region by a particle as it tunnels through a square barrier potential. We find that the integrated distribution has a simple interpretation. If one restricts the time spent in the barrier to be \ensuremath{\leqslant}\ensuremath{\tau}, then an effective uncertainty \ensuremath{\Delta}V is introduced in the barrier height, such that\ensuremath{\Delta}V\ensuremath{\tau}\ensuremath{\simeq}1. This uncertainty leads to unusual interference effects in the distribution. These interference effects explain why the average speed of a particle traversing a very opaque barrier may exceed the speed of light. \textcopyright{} 1990 The American Physical Society
The time dependent density matrix of a system with potential barrier is studied using path integrals. The characterization of the initial state, which is assumed to be restricted to one side of the barrier, and the time evolution of the density matrix lead to a threefold path integral which is evaluated in the semiclassical limit. The semiclassical trajectories are found to move in the complex coordinate plane and barrier penetration only arises due to fluctuations. Both the form of the semiclassical paths and the relevant fluctuations change significantly as a function of temperature. The semiclassical analysis leads to a detailed picture of barrier penetration in the real time domain and the changeover from thermal activation to quantum tunneling. Deep tunneling is associated with quasizero modes in the fluctuation spectrum about the semiclassical orbits in the long time limit. The connection between this real time description of tunneling and the standard imaginary time instanton approach is established. Specific results are given for a double well potential and an Eckart barrier.
Exact analytical solutions of the time-dependent Schrödinger equation with the initial condition of an incident cutoff wave are used to investigate the traversal time for tunneling. The probability density starts from a vanishing value along the tunneling and transmitted regions of the potential. At the barrier width it exhibits, at early times, a distribution of traversal times that typically has a peak τpτ_pτp​ and a width ΔτΔτΔτ. Numerical results for other tunneling times, as the phase-delay time, fall within ΔτΔτΔτ. The Büttiker traversal time is the closest to τpτ_pτp​. Our results resemble calculations based on Feynman paths if its noisy behaviour is ignored.