Weak measurement is a potentially powerful tool for studying post-selected quantum systems. The original approach to weak measurement requires a different von Neumann interaction between the quantum system and measurement pointer for weak values of every different observable. When studying weak values of properties of more than one particle, which is necessary for studying entanglement, these interactions can range from difficult to impossible to implement experimentally. For example, the measurement of properties on a pair of optical photons requires a strong Kerr-like nonlinearity at the two-photon level. In a recent work, we described a new method for extracting weak values of operators that can be expressed as products of two local, single-particle operators by studying the correlations in experimentally feasible local, single-particle measurements. In the present work, that theoretical approach is generalized so that weak values of products of N local, single-particle operators can be extracted from the correlations in N single-particle measurements.
Programmable arrays of alkaline-earth atoms have emerged as a versatile experimental platform for quantum science. Together with Rydberg interactions, control at the single-particle level makes such atom arrays ideal systems for studying how quantum entanglement can be harnessed to improve the performance of optical atomic clocks. In this talk, I will discuss recent work from JILA, where we have achieved this goal by engineering Rydberg interactions to prepare entangled states with metrological gain.
In this paper, we propose a generic and systematic approach for study of the electronic structure for atoms or molecules. In particular, we address the issue of single particle states, or orbitals, which should be one of the most important aspects of a quantum many-body theory. We argue that the single-particle
Green function provides a most general scheme for generating these single particle states or orbitals. We call them the
correlated atomic or molecular orbitals to make a distinction from those determined from
Hartree−Fock equation. We present the calculation of the single particle properties (i.e., the electron affinities
(EA′s) and ionization potentials
(IP′s)) for the
H2O molecule using the correlated molecular orbitals in the context of quantum chemistry with a second-order self energy. We also calculate the total ground state energy with a single
Slater wavefunction determined only from the hole states. Comparisons are made with available experimental data as well as with those from the
Hartree−Fock or density functional theory
(DFT) calculations. We conclude that the correlated atomic or molecular orbital approach provides a strictest and most powerful method for studying the single-particle properties of atoms or molecules. It also gives a better total energy than do the
Hartree−Fock and
DFT even at the single
Slater determinant level. It promises that a correlation theory based on the correlated atomic or molecular orbitals will become an approach which possesses the advantages and also overcomes their shortcomings of current quantum chemistry methods based on either the conventional quantum many-body theory or the
DFT.