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Mathematics and Mechanics of Complex Systems

Quantum mechanics: some basic techniques for some basic models, II: The techniques

V. Grecchi

Published Dec 31, 2016• 0 citations
Publisher

Abstract

This paper is a continuation of the previous one: "Quantum mechanics: some basic techniques for some basic models, I: The models".The main subject is the perturbation theory in quantum mechanics giving diverging perturbation series for the energy levels of the oscillators.Thus, a short historical introduction on the methods of the sum of diverging power series is given.

DOI
10.2140/memocs.2016.4.353

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This paper is a continuation of the previous one: "Quantum mechanics: some basic techniques for some basic models, I: The models".The main subject is the perturbation theory in quantum mechanics giving diverging perturbation series for the energy levels of the oscillators.Thus, a short historical introduction on the methods of the sum of diverging power series is given.
We give a brief and basic introduction to perturbation theory. The main idea is to attempt to consider the situation of interest as a small perturbation of a simpler situation (which can be understood completely), and in particular to consider a system with a weak interaction as a perturbation of a non-interacting system. We develop the interaction picture, which allows approximating the time-evolution of an interacting system by the partial sums of the Dyson series, a fundamental tool for the sequel. We illustrate these ideas on a rudimentary model of the interaction of electrons and “photons”.
The subject of perturbation theory in non-relativistic quantum mechanics is introduced. First, perturbation theory for stationary states in the absence of degeneracy is studied. The case of nearby levels, perturbations of a one-dimensional harmonic oscillator, the occurrence of degeneracy, Stark and Zeeman effects are then described in detail. After a brief outline of the variational method, the Dyson series for time-dependent perturbation theory is derived, with application to harmonic perturbations. The Fermi golden rule is also presented. The chapter ends with an assessment of four branches of the subject: regular perturbation theory, asymptotic perturbation theory, and summability methods, spectral concentration and singular perturbations. Approximate methods for stationary states It is frequently the case, in physical problems, that the full Hamiltonian operator H consists of an operator H 0 whose eigenvalues and eigenfunctions are known exactly, and a second term V resulting from a variety of sources (e.g. the interaction with an electric field, or a magnetic field, or the relativistic corrections to the kinetic energy, or the effects of spin). The problems and aims of perturbation theory for stationary states can be therefore summarized as follows. (i) Once the domain of (essential) self-adjointness of the ‘unperturbed’ Hamiltonian H 0 is determined, find on which domain the ‘sum’ H = H 0 + V represents an (essentially) self-adjoint operator (the reader should remember from appendix 4. A that in general, once some operators A and B are given, the intersection of their domains, on which their sum is defined, might be the empty set). […]
Modern computers have made possible the evaluation of higher order terms of perturbation series. Apart from the empirical work involving numerical calculations, much formal mathematical work has been done on the convergence properties of perturbation series and of Pade approximants which represent them. Some of the modern work in perturbation theory is reviewed in the context of traditional results from the theory of real and complex variables. The two major versions of time-independent perturbation theory, the Rayleigh-Schrodinger (RS) and Brillouin-Wigner (BW) theories, are compared and contrasted, and the alternative techniques for evaluating the terms in the energy series are discussed. The sum-over-states method, the differential equation method and the variational principle method are treated, with emphasis on their inter-relations.
The detailed transition from classical mechanics to quantum mechanics, particularly in regard to the question of quantum corrections to the semiclassical quantization, can be completely understood for the x4{x}^{4}x4 perturbed harmonic oscillator. This is a consequence of five facts: (i) The quantum perturbation series for the energy can be solved order by order in closed form. (ii) The quantum series rearranges directly into the classical canonical perturbation series plus quantum corrections proportional to successively higher powers of ${\ensuremath{\Elzxh}}^{2}$. (iii) The classical series and the subseries for the quantum corrections converge (subseries by subseries) to the terms of the Jeffreys-Wentzel-Kramers-Brillouin (JWKB) expansion for the energy (to all orders of \ensuremath{\Elzxh}). (iv) The (all-order) JWKB expansion, conversely, yields the quantum perturbation series and consequently uniquely determines the exact eigenvalue. (v) The ratio of the quantum energy to the classical energy at action (n+1/2)\ensuremath{\Elzxh} differs from 1 asymptotically by 1/[9\ensuremath{\pi}(n+1/2)2{+1/2)}^{2}+1/2)2], independent of both \ensuremath{\Elzxh} and the perturbation coupling constant, as the harmonic-oscillator quantum number n approaches \ensuremath{\infty}. An interesting additional feature is the mechanism by which the convergence of the classical perturbation series and of the series for the quantum corrections gets turned into the divergence of the quantum perturbation series.
The starting point in a quantum mechanical problem is the construction of a Schrödinger equation. We try to solve it exactly to obtain wave function. A Schrödinger equation is exactly solvable only for a certain number of simple potentials. In most of the cases the Schrödinger equation cannot be solved exactly. The solution of the Schrödinger equation for the real systems is usually complicated and often exact solutions are very difficult to find or solutions not exist. Examples include as anharmonic oscillator, hydrogen atom in an electric field, a plane rotator in the presence of an applied electric field and so on. Therefore, we need to rely on approximation methods. The simple and most interesting and powerful approximate method is the perturbation theory developed by Schrödinger in 1926 [1]. Earlier Lord Rayleigh [2] analysed harmonic vibrations of a string perturbed by small inhomogeneities. The work of Rayleigh was pointed out by Schrödinger. Consequently, the method is also called Rayleigh-Schrödinger perturbation theory. This method is powerful for determining the changes in the discrete energy values and the associated eigenfunctions of a system due to a weak perturbation, provided the eigenpairs of the undisturbed system are available. The approximations obtained from the perturbation theory are used to calculate energy level diagrams and to understand the splitting and assignments of atomic and molecular spectra [35]. The perturbation theory has been proven to be useful in several fields of theoretical physics and also in chemistry. It provides considerable insight into various phenomena. The main disadvantage of this method is that in certain problems the perturbation series converges slowly or diverges.