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Charging a Quantum Many-Body Battery

Thao P. Le

Published Jan 1, 2017• 0 citations
Publisher

Abstract

The operation of conventional batteries relies primarily on electrochemical reactions and classical physics. However, an important question is whether quantum effects, such as entanglement, can lead to a significant change in the behaviour of a battery. In addition to being a fundamental problem, this is of technological interest, since there is the prospect of exploiting quantum effects to increase charging power and energy density of a battery, and to overcome the limitations of classical batteries. In this thesis, we investigate how to charge a battery composed of quantum systems and determine which quantum effects play a part in this charging. We find that certain broken symmetries in the battery model give rise to entanglement and enhance charging relative to other batteries without entanglement. We use Heisenberg XXZ spin chains as the basic model of our quantum many-body battery. The Heisenberg spin chain is a paradigmatic model of solid-state physics; simple, yet able to describe the magnetic behaviour of more complex physical systems. The models we consider either have a nearest neighbour spin-spin coupling interaction or a long range 1/r interaction. Local identical charging fields are used to deposit work in the battery. We also investigate adding noise into the charging process, and consider the performance and stability of the spin chain battery in the presence of a heat bath. We compare the different spin chains with one another, and also compare them with several different classical models, in order to determine whether or not there is a “quantum advantage”. We find that whether or not there is a quantum advantage depends on which models and what quantity we are comparing.

DOI
10.26180/4634167

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The operation of conventional batteries relies primarily on electrochemical reactions and classical physics. However, an important question is whether quantum effects, such as entanglement, can lead to a significant change in the behaviour of a battery. In addition to being a fundamental problem, this is of technological interest, since there is the prospect of exploiting quantum effects to increase charging power and energy density of a battery, and to overcome the limitations of classical batteries. In this thesis, we investigate how to charge a battery composed of quantum systems and determine which quantum effects play a part in this charging. We find that certain broken symmetries in the battery model give rise to entanglement and enhance charging relative to other batteries without entanglement. We use Heisenberg XXZ spin chains as the basic model of our quantum many-body battery. The Heisenberg spin chain is a paradigmatic model of solid-state physics; simple, yet able to describe the magnetic behaviour of more complex physical systems. The models we consider either have a nearest neighbour spin-spin coupling interaction or a long range 1/r interaction. Local identical charging fields are used to deposit work in the battery. We also investigate adding noise into the charging process, and consider the performance and stability of the spin chain battery in the presence of a heat bath. We compare the different spin chains with one another, and also compare them with several different classical models, in order to determine whether or not there is a “quantum advantage”. We find that whether or not there is a quantum advantage depends on which models and what quantity we are comparing.
Quantum thermodynamics takes over from classical thermodynamics when systems are of the scale of single particles and quantum fluctuations have a noticeable effect. An interesting topic of research of this relatively new field is the quantum battery, which in this thesis consists of an array of N identical electron spin qubits. In an article by Binder et al. [4], it is proven that in theory, an N-times decrease in charging time of the battery is achieved when global operations on qubits are permitted. This thesis investigates if a similar advantage can be achieved by using a local qubitqubit interaction operator on a one-dimensional chain of exchange-coupled electron spin qubits that are driven by microwave radiation in the presence of decoherence. This system is described by a density matrix in order to include the presence of external influences. The time-evolution of the state of the system is calculated by solving the Von-Neumann equation both analytically and numerically, which is then used to calculate the extractable work. It is shown that exchange interaction does not have a direct effect on the extractable work, since it creates entanglement between two states of the same energy level and the operator commutes with the Hamiltonian of the system. The effect of the CNOT gate on the state of the system is then investigated. While it does have an effect on the extractable work, it did not achieve a decrease in charging time. These results are only relevant for the specific system used in this thesis. For other methods and systems, exchange interaction could lead to faster charging.
Recently, it has been shown that energy can be deposited on a collection of quantum systems at a rate that scales superextensively. Some of these schemes for quantum batteries rely on the use of global many-body interactions that take the batteries through a correlated shortcut in state space. Here we extend the notion of a quantum battery from a collection of a priori isolated systems to a many-body quantum system with intrinsic interactions. Specifically, we consider a one-dimensional spin chain with physically realistic two-body interactions. We find that the spin-spin interactions can yield an advantage in charging power over the noninteracting case and we demonstrate that this advantage can grow superextensively when the interactions are long ranged. However, we show that, unlike in previous work, this advantage is a mean-field interaction effect that does not involve correlations and that relies on the interactions being intrinsic to the battery.
Quantum battery, as a novel energy storage device, offers the potential for unprecedented efficiency and performance beyond the capabilities of classical systems, with broad implications for future quantum technologies. Here, we experimentally \RefC{demonstrate quantum charging advantage (QCA)} in a scalable solid-state quantum battery. More specifically, we show how double-excitation Hamiltonians for two-level systems promote scalable QCA \RefB{with standard methods.} We effectively implement the collective evolution of quantum systems with 2 up to 12 battery cells in a superconducting quantum processor, and study the performance of quantum charging compared to its uncorrelated classical counterpart. The model considered is a linear chain of superconducting transmon qubits with only \textit{nearest-neighbor} and \textit{pairwise} interactions, which constitute the simplest model of a multi-cell quantum battery. Our results empirically realize substantial QCA without the necessity of adopting long-range and many-body interactions \RefB{ and showcase the quantum features of the QB charging processes with measurements of non-zero coherent ergotropy, incoherent ergotropy and entanglement,} revealing a promising prospect for further developments of efficient and experimentally feasible protocols for QCA.
Can collective quantum effects make a difference in a meaningful thermodynamic operation? Focusing on energy storage and batteries, we demonstrate that quantum mechanics can lead to an enhancement in the amount of work deposited per unit time, i.e., the charging power, when N batteries are charged collectively. We first derive analytic upper bounds for the collective quantum advantage in charging power for two choices of constraints on the charging Hamiltonian. We then demonstrate that even in the absence of quantum entanglement this advantage can be extensive. For our main result, we provide an upper bound to the achievable quantum advantage when the interaction order is restricted; i.e., at most k batteries are interacting. This constitutes a fundamental limit on the advantage offered by quantum technologies over their classical counterparts.
We investigate charging dynamics in many-body quantum batteries by examining the relationship between instantaneous charging power and the emergence of bipartite, tripartite, and multipartite quantum correlations across different battery--charger configurations. We find that the charging power reaches its maximum before the correlation measures peak, revealing a temporal separation between rapid energy transfer and the buildup of quantum correlations. We further study the role of interaction structure using local and many-body charging Hamiltonians for both unconstrained and constrained charging protocols, in which the total available charging resources are fixed to scale proportionally with the number of spins, thereby isolating the influence of interaction geometry and particle participation on the charging dynamics. In the unconstrained case, the enhanced charging energy observed for higher-order interactions originates primarily from the larger energy scale of the corresponding charging Hamiltonian. Under constrained conditions, however, increasing the interaction order alone provides no advantage over parallel charging when interaction and local spin-flip contributions are balanced, whereas interaction-dominated protocols significantly enhance charging performance, highlighting the importance of collective many-body dynamics. Fully collective interactions yield the largest enhancement in charging power together with stronger multipartite correlations, while partially collective interactions provide only limited improvements. Finally, extending the interaction range through next-nearest-neighbor couplings suppresses the charging power, demonstrating that, under constrained energetic resources, charging performance is governed primarily by interaction structure, particle participation, and collective many-body dynamics rather than by interaction order alone.
A quantum battery is expected to outperform its classical counterpart due to quantum effects. Usually, in a quantum battery made of N cells, quantum advantage is demonstrated through super-extensive scaling of the upper bound to the charging power with N. In this work, we show that potential quantum advantage as measured by the power bounds need not translate to tangible advantage in practice. We demonstrate this by considering an all-to-all coupled spin-chain model of a quantum battery with 2-local interactions. It exhibits super-extensive charging when analyzed using the upper bound derived from the uncertainty principle. Unlike the previously studied models, the contribution to this apparent quantum advantage is twofold—arising from both the battery and the charger. The model is also experimentally friendly, as it does not require global couplings and yet generates genuine multipartite entanglement. However, we demonstrate that the potential quantum advantage in this scenario is not tangible by employing a tighter upper bound on power. Additionally, we show that even this tighter bound can fail in a range of physical situations and indicate a quantum enhancement that is intangible in practice. Hence, we argue that actual power transferred must be evaluated along with proper characterization of the resources before claiming quantum advantage.