We present a complete protocol for cavity-free quantum networking based on collective enhancement in Rydberg atom ensembles. The scheme combines Rydberg blockade, collectively enhanced light--matter coupling, and phase-matched directional emission to remove the need for optical cavities while retaining efficiencies comparable to cavity-assisted interfaces. The protocol proceeds in three steps: (i)~local control--ensemble entanglement generated by Rydberg blockade with gate fidelity
Fgate≈99.93%; (ii)~atom--photon conversion through Raman emission from an oblate spheroidal ensemble, yielding directional emission efficiency
ηdir≈73% and single-node efficiency
ηnode≈40%; and (iii)~remote atom--atom entanglement via Hong--Ou--Mandel interference, producing Bell states with fidelity
F>97.5%. Incorporating quantum memories allows up to
M≈100 retry attempts within a coherence time
T2>100μs, enabling entanglement generation rates of approximately
4kHz over a 20~km separation. Collectively enhanced Rydberg ensembles thus provide a practical, cavity-free interface for scalable distributed quantum computing and secure quantum communication.
In this Letter we report an experiment that verifies an atomic-ensemble quantum memory via a measurement-device-independent scheme. A single photon generated via Rydberg blockade in one atomic ensemble is stored in another atomic ensemble via electromagnetically induced transparency. After storage for a long duration, this photon is retrieved and interfered with a second photon to perform a joint Bell-state measurement (BSM). The quantum state for each photon is chosen based on a quantum random number generator, respectively, in each run. By evaluating correlations between the random states and BSM results, we certify that our memory is genuinely entanglement preserving.