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Chemical Physics

A theoretical study on laser cooling of silicon monofluoride

Wensha Xia, Mingkai Fu, Haitao Ma, Wensheng Bian

Published Jan 19, 2017• 11 citations
Publisher
DOI
10.1016/j.chemphys.2017.01.007

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We report an experimental investigation on the Doppler-free saturated absorption spectroscopy of buffer-gas-cooled Barium monofluoride (BaF) molecules in a 4 K cryogenic cell. The obtained spectra with a resolution of 19 MHz, much smaller than previously observed in absorption spectroscopy, clearly resolve the hyperfine transitions. Moreover, we use these high-resolution spectra to fit the hyperfine splittings of excited A ( v = 0) state and find the hyperfine splitting of the laser-cooling-relevant A 2 Π 1/2 ( v = 0, J = 1/2,+) state is about 18 MHz, much higher than the previous theoretically predicted value. This provides important missing information for laser cooling of BaF molecules.
We theoretically investigate the laser cooling of fermionic barium monofluoride (137BaF) molecules, which are promising candidates for precision studies of weak parity violation and nuclear anapole moments. This molecular species features two nuclear spins, resulting in a hyperfine structure that is considerably more complicated than the one found in the usual laser-cooled diatomics. We use optical Bloch equations and rate equations to show that optical cycling, sub-Doppler cooling and bichromatic forces can all be realized under realistically achievable experimental conditions.