Abstract The geometry of quantum states provides a unifying framework for estimation processes based on quantum probes, and it establishes the ultimate bounds of the achievable precision. We show a relation between the statistical distance between infinitesimally close quantum states and the second order variation of the coherence of the optimal measurement basis with respect to the state of the probe. In quantum phase estimation protocols, this leads to propose coherence as the relevant resource that one has to engineer and control to optimize the estimation precision. Furthermore, the main object of the theory i.e. the symmetric logarithmic derivative, in many cases allows one to identify a proper factorization of the whole Hilbert space in two subsystems. The factorization allows one to discuss the role of coherence versus correlations in estimation protocols; to show how certain estimation processes can be completely or effectively described within a single-qubit subsystem; and to derive lower bounds for the scaling of the estimation precision with the number of probes used. We illustrate how the framework works for both noiseless and noisy estimation procedures, in particular those based on multi-qubit GHZ-states. Finally we succinctly analyze estimation protocols based on zero-temperature critical behavior. We identify the coherence that is at the heart of their efficiency, and we show how it exhibits the non-analyticities and scaling behavior proper of a large class of quantum phase transitions.
Abstract The geometry of quantum states provides a unifying framework for estimation processes based on quantum probes, and it establishes the ultimate bounds of the achievable precision. We show a relation between the statistical distance between infinitesimally close quantum states and the second order variation of the coherence of the optimal measurement basis with respect to the state of the probe. In quantum phase estimation protocols, this leads to propose coherence as the relevant resource that one has to engineer and control to optimize the estimation precision. Furthermore, the main object of the theory i.e. the symmetric logarithmic derivative, in many cases allows one to identify a proper factorization of the whole Hilbert space in two subsystems. The factorization allows one to discuss the role of coherence versus correlations in estimation protocols; to show how certain estimation processes can be completely or effectively described within a single-qubit subsystem; and to derive lower bounds for the scaling of the estimation precision with the number of probes used. We illustrate how the framework works for both noiseless and noisy estimation procedures, in particular those based on multi-qubit GHZ-states. Finally we succinctly analyze estimation protocols based on zero-temperature critical behavior. We identify the coherence that is at the heart of their efficiency, and we show how it exhibits the non-analyticities and scaling behavior proper of a large class of quantum phase transitions.
The geometry of quantum states provides a unifying framework for estimation processes based on quantum probes, and it allows to derive the ultimate bounds of the achievable precision. We show a relation between the statistical distance between infinitesimally close quantum states and the second order variation of the coherence of the optimal measurement basis with respect to the state of the probe. In Quantum Phase Estimation protocols, this leads to identify coherence as the relevant resource that one has to engineer and control to optimize the estimation precision. Furthermore, the main object of the theory i.e., the Symmetric Logarithmic Derivative, in many cases allows to identify a proper factorization of the whole Hilbert space in two subsystems. The factorization allows: to discuss the role of coherence vs correlations in estimation protocols; to show how certain estimation processes can be completely or effectively described within a single-qubit subsystem; and to derive lower bounds for the scaling of the estimation precision with the number of probes used. We illustrate how the framework works for both noiseless and noisy estimation procedures, in particular those based on multi-qubit GHZ-states. Finally we succinctly analyze estimation protocols based on zero-temperature critical behaviour. We identify the coherence that is at the heart of their efficiency, and we show how it exhibits the non-analyticities and scaling behaviour proper of a large class of quantum phase transitions.
In an idealistic setting, quantum metrology protocols allow to sense physical parameters with mean squared error that scales as 1/N2 with the number of particles involved---substantially surpassing the 1/N-scaling characteristic to classical statistics. A natural question arises, whether such an impressive enhancement persists when one takes into account the decoherence effects that are unavoidable in any real-life implementation. In this thesis, we resolve a major part of this issue by describing general techniques that allow to quantify the attainable precision in metrological schemes in the presence of uncorrelated noise. We show that the abstract geometrical structure of a quantum channel describing the noisy evolution of a single particle dictates then critical bounds on the ultimate quantum enhancement. Our results prove that an infinitesimal amount of noise is enough to restrict the precision to scale classically in the asymptotic N limit, and thus constrain the maximal improvement to a constant factor. Although for low numbers of particles the decoherence may be ignored, for large N the presence of noise heavily alters the form of both optimal states and measurements attaining the ultimate resolution. However, the established bounds are then typically achievable with use of techniques natural to current experiments. In this work, we thoroughly introduce the necessary concepts and mathematical tools lying behind metrological tasks, including both frequentist and Bayesian estimation theory frameworks. We provide examples of applications of the methods presented to typical qubit noise models, yet we also discuss in detail the phase estimation tasks in Mach-Zehnder interferometry both in the classical and quantum setting---with particular emphasis given to photonic losses while analysing the impact of decoherence.
Abstract Quantum multiparameter estimation involves estimating multiple parameters simultaneously and can be more precise than estimating them individually. Our interest here is to determine fundamental quantum limits to the achievable multiparameter estimation precision in the presence of noise. We first present a lower bound to the estimation error covariance for a noisy initial probe state evolving through a noiseless quantum channel. We then present a lower bound to the estimation error covariance in the most general form for a noisy initial probe state evolving through a noisy quantum channel. We show conditions and accordingly measurements to attain these estimation precision limits for noisy systems. We see that the Heisenberg precision scaling of 1/N can be achieved with a probe comprising N particles even in the presence of noise. In fact, some noise in the initial probe state or the quantum channel can serve as a feature rather than a bug, since the estimation precision scaling achievable in the presence of noise in the initial state or the channel in some situations is impossible in the absence of noise in the initial state or the channel. However, a lot of noise harms the quantum advantage achievable with N parallel resources, and allows for a best precision scaling of 1/N 1 / N . Moreover, the Heisenberg precision limit can be beaten with noise in the channel, and we present a super-Heisenberg precision limit with scaling of 1/N2 for optimal amount of noise in the channel, characterized by one-particle evolution operators. Furthermore, using γ-particle evolution operators for the noisy channel, where γ > 1, the best precision scaling attainable is 1/N2γ, which is otherwise known to be only possible using 2γ-particle evolution operators for a noiseless channel.
In this thesis we explore aspects of dynamics of open quantum systems related to coherence and quantum correlations - necessary resources for enhanced quantum metrology and quantum computation. We first discuss limits to the precision of parameter estimation when using a quantum system in the presence of noise. To this end we introduce a variational principle for the quantum Fisher information (QFI) bounding the estimation errors of any measurement, which motivates an efficient iterative algorithm for finding optimal system preparations for noisy estimation experiments. Furthermore, we investigate influence of noise correlations on the precision in phase and frequency estimation, by delivering bounds for both spatially and temporarily correlated (non-Markovian) dephasing noise. This allows us to prove the Zeno limit in frequency estimation, conjectured in Phys. Rev. A 84, 012103 (2011) and Phys. Rev. Lett. 109, 233601 (2012). The enhanced estimation precision in quantum metrology can be, however, achieved only using highly entangled states. We propose a scheme of generating such highly correlated states as outputs of Markovian open quantum systems near first-order dynamical phase transitions. We show that the quadratic scaling of the QFI with time is present for experiments within the correlation time of the dynamics and describe a theoretical scheme for quantum enhanced estimation of an optical phase-shift using the photons being emitted from an intermittent quantum system. Finally, we establish the basis for a theory of metastability in Markovian open quantum systems, by extending methods from classical stochastic dynamics. We argue that the partial relaxation into long-lived metastable states - distinct from the asymptotic stationary state - may preserve initial coherences within decoherence-free subspaces or noiseless subsystems, thus allowing for quantum computation during the metastable regime.
We discuss the application of techniques of quantum estimation theory and quantum metrology to thermometry. The ultimate limit to the precision at which the temperature of a system at thermal equilibrium can be determined is related to the heat capacity when global measurements are performed on the system. We prove that if technical or practical limitations restrict our capabilities to local probing, the highest achievable accuracy to temperature estimation reduces to a sort of mesoscopic version of the heat capacity. Adopting a more practical perspective, we also discuss the relevance of qubit systems as optimal quantum thermometers, in order to retrieve the temperature, or to discriminate between two temperatures, characterizing a thermal reservoir. We show that quantum coherence and entanglement in a probe system can facilitate faster, or more accurate measurements of temperature. While not surprising given this has been demonstrated in phase estimation, temperature is not a conventional quantum observable, therefore these results extend the theory of parameter estimation to measurement of non-Hamiltonian quantities. Finally we point out the advantages brought by a less standard estimation technique based on sequential measurements, when applied to quantum thermometry.
The quantum Fisher information matrix (QFIM) is central to multiparameter quantum metrology, dictating the attainable sensitivity via the quantum Cramér-Rao bound. In this work, we investigate the ultimate precision limits for relativistic quantum thermometry in a bipartite system of uniformly accelerated Unruh-DeWitt detectors. Utilizing the symmetric logarithmic derivative (SLD) formalism within the QFIM framework, we analyze the individual and simultaneous estimation of the Unruh temperature T and the initial-state parameter Δ0. In the noiseless case, we demonstrate that these two parameters are quantum compatible, allowing the multiparameter quantum Cramér-Rao bound to be saturated without a loss of precision. We then examine the impact of environmental effects by comparing Markovian and non-Markovian dynamics. In the Markovian regime, dissipation leads to a monotonic degradation of estimation precision; conversely, non-Markovian memory effects induce temporal oscillations and transient precision enhancements due to information backflow. The robustness of the estimation protocols is further analyzed under correlated noisy channels, including amplitude damping, phase flip, and phase damping. We show that dissipative noise results in more significant precision loss than purely dephasing mechanisms, whereas classical correlations in the noise mitigate this degradation. Finally, we discuss the estimation of the detector energy-level spacing ω as a natural extension, highlighting its sensitivity to the environmental structure. Our results provide a unified framework for relativistic multiparameter quantum metrology within the context of open quantum systems.