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Annals of West University of Timisoara - Physics

Note On The Schrödinger Equation

C. Bizdadea, M. M. Bârcan, Iulian Negru, S. O. Saliu

Published Dec 1, 2012• 0 citations
Publisher

Abstract

Abstract A second-order formalism leading to an equation describing the same dynamics as the Schrödinger one is developed under some compatible initial conditions.
DOI
10.1515/awutp-2015-0008

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An important feature of the wave equation is that its solutions q(r, t) are uniquely specified once the initial values q(r, 0) and (del)q(r, 0)/@t are specified. As was mentioned before, if we view the wave equation as describing a continuum limit of a network of coupled oscillators, then this result is very reasonable since one must specify the initial position and velocity of an oscillator to uniquely determine its motion. It is possible to write down other “equations of motion” that exhibit wave phenomena but which only require the initial values of the dynamical variable — not its time derivative — to specify a solution. This is physically appropriate in a number of situations, the most significant of which is in quantum mechanics where the wave equation is called the Schrodinger equation. This equation describes the time development of the observable attributes of a particle via the wave function (or probability amplitude) . In quantum mechanics, the complete specification of the initial conditions of the particle’s motion is embodied in the initial value of . The price paid for this change in the allowed initial data while asking for a linear wave equation is the introduction of complex numbers into the equation for the wave. Indeed, the values taken by are complex numbers. In what follows we shall explore some of the elementary features of the wave phenomena associated with the Schrodinger equation.
The method of the effective Schrodinger equation applied to the one-dimensional problem of a moving particle in a potential box with a potential function and high-frequency time-dependent boundary conditions is investigated. The method of converting the initial equation written for a system with time-dependent boundary conditions to an equation describing a system in a constant region is briefly presented. The resulting system can be considered as a particle in a potential box, located in the field of some effective potential, different from the initial one. Next we consider a particular case of wall motion, with the subsequent construction of the effective Schrodinger equation. Rapid oscillations of the potential box as a whole (i.e., without changing its width) lead to an additional term in the effective equation proportional to the second derivative of the potential. This, in particular, can lead to the formation of potential wells at potential peaks in which bound states of a particle are possible. In the considered case, it was assumed that the oscillation amplitudes are small in comparison with the characteristic dimensions of the system.