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Physical Review A

Atom-molecule conversion in a periodically driven spin-boson model

Sangyong Yi, Sang Wook Kim

Published Jan 19, 2016• 4 citations
Publisher

Abstract

We have investigated the dynamics of atom-molecule conversion using a periodically driven spin-boson model both quantum mechanically and semiclassically. The semiclassical dynamics is fully chaotic for small driving frequencies, so that the regular atom-molecule conversion gradually vanishes. In quantum mechanics, however, the periodic conversion takes place at small frequencies since the quantum adiabatic condition is fulfilled. Moreover, it survives for rather larger frequencies that breaks the adiabatic condition, which is understood by considering the so-called dynamical localization. It implies that the periodic atom-molecule conversion is more robust than we expect from the semiclassical approximation. We also show that for much larger frequencies delocalization takes place so that the dynamics becomes diffusive.

DOI
10.1103/physreva.93.013616

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We have investigated the dynamics of atom-molecule conversion using a periodically driven spin-boson model both quantum mechanically and semiclassically. The semiclassical dynamics is fully chaotic for small driving frequencies, so that the regular atom-molecule conversion gradually vanishes. In quantum mechanics, however, the periodic conversion takes place at small frequencies since the quantum adiabatic condition is fulfilled. Moreover, it survives for rather larger frequencies that breaks the adiabatic condition, which is understood by considering the so-called dynamical localization. It implies that the periodic atom-molecule conversion is more robust than we expect from the semiclassical approximation. We also show that for much larger frequencies delocalization takes place so that the dynamics becomes diffusive.
We investigate the quantum many-body dynamics of ultracold atom−molecule conversion using a Floquet spin-boson model, where the periodic energy detuning between molecules and atomic pairs is utilized to explore various dynamical regimes. We find that the upper bound of the adiabatic driving frequency increases continuously with the strength of molecule−molecule interactions, indicating that many-body interactions are beneficial in meeting the requirement of the adiabatic condition, thereby facilitating the realization of adiabatic atom−molecule conversion. This enhancement of the fulfillment of the adiabatic condition is further evidenced by the stabilization of periodic oscillations in the mean molecule number over time, protected by these interactions, even when the frequency lies within the localized regime. Interestingly, in the diffusive regime, while the many-body interaction has little effect on the dynamical equilibrium of atom−molecule conversion, it significantly expands the diffusive regime. In the high-frequency limit, many-body interactions are found to completely suppress atom−molecule conversion. Our results shed light on how molecule−molecule interactions influence the boundaries between different dynamical regimes.
We consider a simple quantum model of atom-molecule conversion where bosonic atoms can combine into diatomic molecules and vice versa. The many-particle system can be expressed in terms of the generators of a deformed su(2)\text{su}(2)su(2) algebra, and the mean-field dynamics takes place on a deformed version of the Bloch sphere, a teardrop shaped surface with a cusp singularity. We analyze the mean-field and many-particle correspondence, which shows typical features of quantum-classical correspondence. We demonstrate that semiclassical methods can be employed to recover full many-particle features from the mean-field description in cold atom systems with atom-molecule conversion, and we derive an analytic expression for the many-particle density of states in the limit of large particle numbers.
Abstract We adopt a modified spin-boson model to investigate the quantum phase transition in an ultracold atom-molecule conversion system involving molecule–molecule interaction. We explore the properties of ground state, entanglement entropy, and many-body dynamics, which confirm that the system exhibits a second-order phase transition from a pure atom phase to a mixed atom-molecule phase when the energy detuning is below a critical value. We obtain three scaling laws and the corresponding two critical exponents to characterize the phase transition. In particular, we discuss the effects of both the speed of ground-state dynamical evolution and the strength of molecular interaction on the phase transition. The adiabatic evolution condition is obtained as well. Our results show that the molecular interaction can greatly reduce the upper bound of the adiabatic condition, which provides a theoretical basis for easier observation of the phase transition in experiments.
Now, many different approaches have been presented to study the different semi-classical models derived from the Dicke Hamiltonian, which reflect a fact that the quantum-mechanical spin possesses no direct classical analog. The Hartree-Fock-type approximation is one of the widely used approaches, with which we derive the Heisenberg equations of motion for the system and replace the operators in these equations with the corresponding expectation values. In the present paper, we investigate the role of quantum phase transition in determining the chaotic property of the time-dependent driven Dicke model. The semi-classical Hamiltonian is derived by evaluating the expectation value of the Dicke Hamiltonian in a state, which is a product state of photonic and atomic coherent states. Based on the inverse of the relations between the position-momentum representation and the Bosonic creation-annihilation operators, the Hamiltonian is rewritten in the position-momentum representation and it undergoes a spontaneous symmetry-breaking phase transition, which is directly analogous to the quantum phase transition of the quantum system. In order to depict the Poincaré sections, which are used to analyze the trajectories through the four-dimensional phase space, we give the equations of motion of system from the derivatives of the semi-classical Hamiltonian for a variety of different parameters and initial conditions. According to the Dicke quantum phase transition observed from the experimental setup , we study the effect of a monochromatic non-adiabatic modulation of the atom-field coupling in Dicke model (i.e., the driven Dicke model) on the system chaos by adjusting the pump laser intensity. The change from periodic track to chaotic figure reflects the quantum properties of the system, especially the quantum phase transition point, which is a key position for people to analyse the shift from periodic orbit to chaos. In an undriven case, the system reduces to the standard Dicke model. We discover from the Poincaré sections that the system undergoes a change from the classical periodic orbit to a number of chaotic trajectories and in the superradiant phase area, the whole phase space is completely chaotic. When the static and driving coupling both exist, the system shows rich chaotic motion. The ground state properties are mainly determined by the static coupling, while the orbit of the system is adjusted by the driving coupling. If the static coupling is greater than the critical coupling, the system displays completely chaotic images in the Poincaré sections, and the periodic orbits in the chaos can also be adjusted by the strong driving coupling. While the static coupling is less than the critical coupling, the system can also show the chaotic images by adjusting the driving coupling strength and oscillation frequency. Moreover, by tuning the oscillation frequency, the Poincaré sections may change from the classical orbits to the chaos, and back to the classical orbits in the normal phase of the system.
New experimental results are presented for short-pulse microwave ionization of highly excited hydrogen atoms. A comparison of these results with quantum numerical computations and analytical predictions provides for the first time experimentally grounded evidence of the localization phenomenon that leads to the suppression of the quantum version of the chaotic diffusion in action space occurring in the classical limit. The onset of chaotic motion in externally driven classical systems is a key problem in nonlinear dynamics that is now well understood in its essential aspects. In many physically interesting cases, as the perturbation strength increases beyond some critical value, the system starts absorbing energy in a diffusive way. The question whether “diffusive” excitation processes can take place also in externally driven quantum systems is then a very interesting one for the physics of atoms and molecules in external electromagnetic fields. This is a deep question involving the nature and the validity of the quasiclassical approximation when the underlying classical dynamics is chaotic. The question of “quantum diffusion” was first addressed in a simple model system, the kicked rotator. It was chosen because the features of classical chaos in it were relatively clean and well understood. Besides that, the numerical simulation of its quantum dynamics could be easily accomplished. The major indication of this model was that quantum mechanics suppresses the classical chaotic diffusion in action via a destructive interference effect similar to that responsible for the Anderson localization well known in condensed matter physics.
We study the evolution of bosons in a periodically driven optical lattice during a slow change of the driving amplitude. Both the regime of high-frequency and low-frequency driving are investigated. In the low-frequency regime, resonant absorption of energy is observed. In the high-frequency regime, the dynamics is compared to a system with an effective Hamiltonian in which the atoms are ``dressed'' by the driving field. This ``dressing'' can dramatically change the amplitude and sign of the effective tunneling. A particular focus of this study is the investigation of the time scales necessary for the evolving quantum state to follow almost adiabatically to the ground state of the effective many-body system.