Atomic fluorescence spectroscopy

Shubham Utreja, Pallab Roy, Harish Kumar Rathore +3 more

M. Á. Rebolledo

The application of fluorescence correlation spectroscopy to the measurement of diffusion coefficients of atoms is proposed. After a theoretical analysis of the problem the experimental viability of this technique is studied in the particular case of Tl. Finally applications to other experiments such as ground state level-crossing are proposed.

Richard A. Passwater

Uwe Czarnetzki, D Luggenhölscher, H. F. Döbele

Fluorescence-dip spectroscopy based on an optical double resonance is used to probe the Stark splitting in highly excited Rydberg states of atomic hydrogen. After Doppler-free two-photon excitation to $n\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3$, fluorescence at Balmer $\ensuremath{\alpha}$ is observed. When the radiation of a second laser is tuned over the resonance between $n\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3$ and a Rydberg state, the Stark splitting manifests itself as a series of dips in the Balmer- $\ensuremath{\alpha}$ fluorescence intensity. Rydberg states up to $n\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}55$ can be identified. The minimum detectable electric field is $5\mathrm{V}/\mathrm{cm}$. This is about an order of magnitude more sensitive than other laser-induced fluorescence techniques.

HERBERT WALTHER

C. Y. She, W. M. Fairbank, Jr.

Using a single-clipped digital correlator, the burst of photons resulting from laser induced resonance fluorescence of a single atom as it passes through a laser beam can be recorded and its transit-time measured. By averaging many fluorescent atoms, the transport characteristics of these atoms in a gaseous system, such as diffusion, flow velocity, and chemical reaction rates can be conveniently determined by photon-burst correlation spectroscopy.