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Bulletin of the American Physical Society

Liquid-Liquid Transition in Kitaev Magnets Driven by Spin Fractionalization

Joji Nasu, Yasuyuki Kato, Junki Yoshitake, Yoshitomo Kamiya, Yukitoshi Motome

Published Mar 13, 2017• 1 citation
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Abstract

While phase transitions between magnetic analogs of three states of matter -- a long-range ordered state, paramagnet, and spin liquid -- have been extensively studied, the possibility of liquid-liquid transitions, namely, between different spin liquids, remains elusive. By introducing the Ising coupling into the honeycomb Kitaev model with bond asymmetry, we discover that the Kitaev spin liquid becomes a bond-nematic quantum paramagnet before magnetically ordered. The phase transition between the two liquid-like states with different topological nature is of first order, driven by delocalization of the $Z_2$ gauge fluxes, and persists to a critical point at finite temperature located inside the regime where quantum spins are fractionalized. It is suggested that similar transitions may occur in other perturbed Kitaev magnets with bond asymmetry.

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Phases and phase transitions of a perturbed Kekulé-Kitaev model

Eoin Quinn, Subhro Bhattacharjee, Roderich Moessner

We study the quantum-spin-liquid phase in a variant of the Kitaev model where the bonds of the honeycomb lattice are distributed in a Kekul\'e pattern. The system supports gapped and gapless ${Z}_{2}$ quantum spin liquids with interesting differences from the original Kitaev model, the most notable being a gapped ${Z}_{2}$ spin liquid on a kagome lattice. Perturbing the exactly solvable model with antiferromagnetic Heisenberg perturbations, we find a magnetically ordered phase stabilized by a quantum ``order by disorder'' mechanism, as well as an exotic continuous quantum phase transition between the topological spin liquid and this magnetically ordered phase. Using a combination of field theory and Monte Carlo simulations, we find that the transition likely belongs to the $3D\text{\ensuremath{-}}XY\ifmmode\times\else\texttimes\fi{}{Z}_{2}$ universality class.

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While phase transitions between magnetic analogs of three states of matter -- a long-range ordered state, paramagnet, and spin liquid -- have been extensively studied, the possibility of liquid-liquid transitions, namely, between different spin liquids, remains elusive. By introducing the Ising coupling into the honeycomb Kitaev model with bond asymmetry, we discover that the Kitaev spin liquid becomes a bond-nematic quantum paramagnet before magnetically ordered. The phase transition between the two liquid-like states with different topological nature is of first order, driven by delocalization of the Z2Z_2Z2​ gauge fluxes, and persists to a critical point at finite temperature located inside the regime where quantum spins are fractionalized. It is suggested that similar transitions may occur in other perturbed Kitaev magnets with bond asymmetry.
While phase transitions between magnetic analogs of the three states of matter-a long-range ordered state, paramagnet, and spin liquid-are extensively studied, the possibility of "liquid-liquid" transitions, namely, between different spin liquids, remains elusive. By introducing the additional Ising coupling into the honeycomb Kitaev model with bond asymmetry, we discover that the Kitaev spin liquid turns into a spin-nematic quantum paramagnet before a magnetic order is established by the Ising coupling. The quantum phase transition between the two liquid states accompanies a topological change driven by fractionalized excitations, the Z_{2} gauge fluxes, and is of first order. At finite temperatures, this yields a persisting first-order transition line that terminates at a critical point located deep inside the regime where quantum spins are fractionalized. It is suggested that similar transitions may occur in other perturbed Kitaev magnets with bond asymmetry.
We study the spin-1/21/21/2 ferromagnetic Heisenberg-Kitaev-$\mathrm{\ensuremath{\Gamma}}$ model in the anisotropic (Toric code) limit to reveal the nature of the quantum phase transition between the gapped Z2{Z}_{2}Z2​ quantum spin liquid and a spin-ordered phase (driven by Heisenberg interactions) as well as a trivial paramagnet (driven by pseudodipolar interactions $\mathrm{\ensuremath{\Gamma}}$). The transitions are obtained by a simultaneous condensation of the Ising electric and magnetic charges---the fractionalized excitations of the Z2{Z}_{2}Z2​ quantum spin liquid. Both these transitions can be continuous and are examples of deconfined quantum critical points. Crucial to our calculations are the symmetry implementations on the soft electric and magnetic modes that become critical. In particular, we find strong constraints on the structure of the critical theory arising from time reversal and lattice translation symmetries with the latter acting as an anyon permutation symmetry that endows the critical theory with a manifestly self-dual structure. We find that the transition between the quantum spin liquid and the spin-ordered phase belongs to a self-dual modified Abelian Higgs field theory while that between the spin liquid and the trivial paramagnet belongs to a self-dual Z2{Z}_{2}Z2​ gauge theory. We also study the effect of an external Zeeman field to show an interesting similarity between the polarized paramagnet obtained due to the Zeeman field and the trivial paramagnet driven pseudodipolar interactions. Interestingly, both the spin liquid and the spin-ordered phases have easily identifiable counterparts in the isotropic limit and the present calculations may shed insights into the corresponding transitions in the material relevant isotropic limit.
We present thermodynamic phase diagrams showing magnetic analog of ``three states of matter,'' namely, spin liquid, paramagnetic, and magnetically ordered phases, obtained by unbiased quantum Monte Carlo simulations. Our simulations are carried out for Kitaev's toric codes in two and three dimensions, i.e., the simplest realizations of gapped topological Z2{Z}_{2}Z2​ spin liquids, extended by a nearest-neighbor ferromagnetic Ising coupling. We find that the ordered phase borders on the spin liquid by a discontinuous transition line in three dimensions, while it grows continuously from the quantum critical point in two dimensions. In both cases, our results elucidate peculiar proximity effects to the nearby spin liquids in the high-temperature paramagnetic phase, even when the ground state is magnetically ordered. The thorough study of magnetic three states of matter is achieved by introducing the ``fictitious vertex'' method into the directed loop algorithm. This provides a generic prescription to simulate models with off-diagonal multispin interactions, in which the conventional scheme may suffer from intrinsic ergodicity breakdown as in the present case.
Quantum spin liquids have fascinated condensed matter physicists for decades because of their unusual properties such as spin fractionalization and long-range entanglement. Unlike conventional symmetry breaking, the topological order underlying quantum spin liquids is hard to detect experimentally. Even theoretical models are scarce for which the ground state is established to be a quantum spin liquid. The Kitaev honeycomb model and its generalizations to other tricoordinated lattices are chief counterexamples—they are exactly solvable, harbor a variety of quantum spin liquid phases, and are also relevant for certain transition metal compounds including the polymorphs of (Na,Li) 2 IrO 3 iridates and RuCl 3 . In this review, we give an overview of the rich physics of the Kitaev model, including two-dimensional and three-dimensional fractionalization as well as dynamic correlations and behavior at finite temperatures. We discuss the different materials and argue how the Kitaev model physics can be relevant even though most materials show magnetic ordering at low temperatures.
We study the dynamics of fractionalized excitations in a Kitaev spin liquid (KSL) induced by a local magnetic field perpendicular to the Kitaev honeycomb lattice. The local magnetic field induces a dynamic excitation of a pair of fluxes described by a generally particle-hole asymmetric interacting resonant level model and the dynamics resembles that of a Kondo problem. The p-h asymmetry competes with the magnetic field and results in a rich phase diagram. Moreover, the magnetic field breaks the gauge equivalence of the ferromagnetic (FM) and anti-ferromagnetic (AFM) Kitaev couplings of the ground state and leads to dramatically different behaviors for the two cases. The latter experiences a first order phase transition during magnetization whereas the former does not. By studying the response of the KSL to the magnetic field in different regimes, we obtain the RG flow and phase diagram of the system in the whole space. This study can be generalized to the KSL in a uniform magnetic field and help resolve issues in recent experiments on KSL candidates.
We study the quantum-spin-liquid phase in a variant of the Kitaev model where the bonds of the honeycomb lattice are distributed in a Kekul\'e pattern. The system supports gapped and gapless Z2{Z}_{2}Z2​ quantum spin liquids with interesting differences from the original Kitaev model, the most notable being a gapped Z2{Z}_{2}Z2​ spin liquid on a kagome lattice. Perturbing the exactly solvable model with antiferromagnetic Heisenberg perturbations, we find a magnetically ordered phase stabilized by a quantum ``order by disorder'' mechanism, as well as an exotic continuous quantum phase transition between the topological spin liquid and this magnetically ordered phase. Using a combination of field theory and Monte Carlo simulations, we find that the transition likely belongs to the $3D\text{\ensuremath{-}}XY\ifmmode\times\else\texttimes\fi{}{Z}_{2}$ universality class.