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Quantum spin systems, probabilistic representations and phase transitions

Benjamin Lees

Published Sep 14, 2026• 0 citations
Publisher

Abstract

This thesis investigates properties of classical and quantum spin systems on lattices. These models have been widely studied due to their relevance to condensed matter physics. We identify the ground states of an antiferromagnetic RP2 model, these ground states are very di�erent from the ferromagnetic model and there was some disagreement over their structure, we settle this disagreement. Correlation inequalities are proved for the spin- 1/2 XY model and the ground state of the spin-1 XY model. This provides fresh results in a topic that had been stagnant and allows the proof of some new results, for example existence of some correlation functions in the thermodynamic limit. The occurrence of nematic order at low temperature in a quantum nematic model is proved using the method of reflection positivity and infrared bounds. Previous results on this nematic order were achieved indirectly via a probabilistic representation. This result is maintained in the presence of a small antiferromagnetic interaction, this case was not previously covered. Probabilistic representations for quantum spin systems are introduced and some consequences are presented. In particular, N´eel order is proved in a bilinear-biquadratic spin-1 system at low temperature. This result extends the famous result of Dyson, Lieb and Simon [35]. Dilute spin systems are introduced and the occurrence of a phase transition at low temperature characterised by preferential occupation of the even or odd sublattice of a cubic box is proved. This result is the first of its type for such a mixed classical and quantum system. A probabilistic representation of the spin-1 Bose-Hubbard model is also presented and some consequences are proved.

DOI
10.82444/warw.33728476

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This thesis investigates properties of classical and quantum spin systems on lattices. These models have been widely studied due to their relevance to condensed matter physics. We identify the ground states of an antiferromagnetic RP2 model, these ground states are very di�erent from the ferromagnetic model and there was some disagreement over their structure, we settle this disagreement. Correlation inequalities are proved for the spin- 1/2 XY model and the ground state of the spin-1 XY model. This provides fresh results in a topic that had been stagnant and allows the proof of some new results, for example existence of some correlation functions in the thermodynamic limit. The occurrence of nematic order at low temperature in a quantum nematic model is proved using the method of reflection positivity and infrared bounds. Previous results on this nematic order were achieved indirectly via a probabilistic representation. This result is maintained in the presence of a small antiferromagnetic interaction, this case was not previously covered. Probabilistic representations for quantum spin systems are introduced and some consequences are presented. In particular, N´eel order is proved in a bilinear-biquadratic spin-1 system at low temperature. This result extends the famous result of Dyson, Lieb and Simon [35]. Dilute spin systems are introduced and the occurrence of a phase transition at low temperature characterised by preferential occupation of the even or odd sublattice of a cubic box is proved. This result is the first of its type for such a mixed classical and quantum system. A probabilistic representation of the spin-1 Bose-Hubbard model is also presented and some consequences are proved.
The study of various types of orders and phases of matter in magnetic systems is extremely popular theme in condensed matter physics. Not only frequently applicable in real world, quantum magnetism provides a fruitful and at the same time frequently feasible framework to search for new phases of matter. In this work we study quantum and associated classical phase transitions of spin systems by combinations of numerical and analytical methods.In Chapter 1 we study quantum paramagnets that are a generalization of antiferromagnetic AKLT [2] construction for the spin group SU(N). We map the so called simplex solid state ansatz wavefunction into a partition function of the classical system on the same lattice using coherent state representation. Then we study phase transitions of that classical models via classical Monte Carlo methods to determine properties of the original quantum simplex solid state [3].In Chapter 2 we are interested in the O(2) model in (2+1)-dimensional system with the dilution, i.e. when some sites are removed from the system. This relativistic O(2) model originates from the description of a transition between superfluid and Mott insulator phases. We study critical properties of the transition using a recently invented [4] worm algorithm.In Chapter 3 we are studying large-N expansion for the symplectic spin group Sp(N). When the original SU(2) spin model proves to be too difficult to be solved, for example at low temperatures, one of the alternative ways is to consider a system based on a more general spin group, for example SU(N) or Sp(N). Results often remain relevant for the original SU(2) group. We are using the mean-field theory approach to find phase transitions associated with the cubic Sp(N) system at large N.Another fundamental question of interest is how different systems behave when they are periodically driven by some external field. Such systems are called Floquet systems, and we will study them in Chapter 4. We will consider interacting and non-interacting systems, that might have a non-conventional type of ordering, topological order.
This thesis focuses on some results about quantum and classical lattice spin systems. We study a wide class of two-dimensional quantum models which enjoy a U(1) symmetry. Using the so called complex rotation method we show that the decay of the relevant correlation functions is at least algebraically fast. We provide some examples of relevant models which belong to our class. We review some results present in the literature concerning the so called GriffthsGinibre inequalities for the classical XY model and propose a generalisation to its quantum counterpart. Correlation inequalities indeed hold for the quantum XY model with spin- 1 2 and for the ground state of the spin-1 system. We propose some applications of these results, namely that the infinite volume limit of some correlation functions exists and that it is possible to compare quenched and annealed averages for a quantum XY model with random couplings. We investigate loop representations for O(n) classical spin systems. We propose a generalised random current representation and show its relationship with the Brydges-Fröhlich-Spencer one. We review some conjectures regarding the expected behaviour of these loop models { namely that macroscopic loops appear and their lengths are distributed according to a Poisson-Dirichlet distribution. We propose some arguments in favour of these conjectures for O(n) loop models, using a mix of exact results and heuristic considerations. In order to do so we de ne a stochastic process which is an effective split-merge process for macroscopic loops and we reformulate some correlation functions for the O(2) spin system in terms of loop properties.
In this thesis, we investigate strongly correlated phenomena in quantum spin systems. In the first part of this work, we study geometrically frustrated antiferromagnets (AFMs). Generalizing the SU(2) Heisenberg Hamiltonian to Sp(N) symmetry, we obtain, in the large-N limit, the mean-field phase diagrams for the planar pyrochlore and cubic AFMs. We then use gauge theories to consider fluctuation effects about their respective mean-field configurations. We find, in addition to conventional Neel states, a plethora of novel magnetically disordered phases: two kinds of spin liquids, Z2 in 2+1D and U(1)in 3+1D, and several valence bond solids such as two and three-dimensional plaquette and columnar singlet states. We use the same approach to study the diamond lattice AFM which possesses extended classical ground state degeneracy. We demonstrate that quantum and entropic fluctuations lift this degeneracy in different ways. In the second part of the thesis, we study ultracold spinor atoms confined in optical lattices. We first demonstrate the feasibility of experimental realization of rotor models using ultracold spin-one Bose atoms in a spin-dependent and disordered optical lattice. We show that the ground state of such disordered rotor models with quadrupolar interactions can exhibit biaxial nematic ordering in the disorder-averaged sense, and suggest an imaging experiment to detect the biaxial nematicity in such systems. Finally, using variational wavefunction methods, we study the Mott phases and superfluid-insulator transition of spin-three bosons in an optical lattice with an anisotropic two dimensional optical trap. We chart out the phase diagrams for Mott states with n = 1 and n = 2 atoms per lattice site. We show that the long-range dipolar interaction stabilizes a state characterized by antiferromagnetic chains made of ferromagnetically aligned spins. We also obtain the mean-field phase boundary for the superfluid-insulator transition, and show that inside the superfluid phase and near the superfluid-insulator phase boundary, the system undergoes a first order antiferromagnetic-ferromagnetic spin ordering transition.
Abstract. We describe random loop models and their relations to a family of quantum spin systems on finite graphs. The family includes spin 1 2 Heisenberg models with possibly anisotropic spin interactions and certain spin 1 models with SU(2)-invariance. Quantum spin correlations are given by loop correlations. Decay of correlations is proved in 2D-like graphs, and occurrence of macroscopic loops is proved in the cubic lattice in dimensions 3 and higher. As a consequence, a magnetic long-range order is rigorously established for the spin 1 model, thus confirming the presence of a nematic phase. Dedicated to Elliott Lieb on the occasion of his eightieth birthday Contents
Magnetic frustrations are the fundamental cause of many interesting phenomena in materials that have been intensely studied since the middle of the 20th century. Magnetic systems with competing interactions, ranging from insulating antiferromagnets to arrays of superconducting qubits, exhibit nontrivial quantum e ects that arise from the need to satisfy a jagged free energy landscape. The search for and characterization of quantum spin liquids, nontrivial topological phases, and quantum phase transitions is conducted through investigations of such frustrated models. Within the large umbrella of frustrated magnetism I have studied some speci c models with the purpose of answering the following questions: (1) What are the interesting phases and less-interesting phases, and how do they fall in the phase diagram relative to one another? (2) What properties do the phases have, and how can we characterize what happens when one phase transitions to another? Armed with the answers to these questions, researchers can further explore these interesting phenomena and apply them towards new materials and devices. In this thesis, I rst develop a computational methodology for studying both classical and quantum spin models using various forms of Monte Carlo simulation. I use classical Monte Carlo to study highly-frustrated models of Ising spins both at nite temperatures and in the T = 0 limit, to map the phase diagram and determine the universality class of phase transitions. Using these methods, I show that in a dissipative chain of qubits, bath-induced qubit-qubit interactions lead to collective decoherence above a critical dissipation strength. This causes the qubits to lose all stored information and become fully correlated with one another, an e ect that one would need to mitigate in order to perform quantum computation. In another study, I show that in antiferromagnetic insulators with anisotropic interactions, frustration can cause an intermediate paramagnetic phase with oblong \droplets" of correlated spins. This phenomenon is quite general and the presence of these droplets can help explain experimental signatures that occur at unexpected temperatures in such materials. In addition to the classical simulations, I develop a variational Monte Carlo (VMC) technique to search for ground states in Heisenberg-type models, speci cally for spins S = 1. The case of S = 1 is more complicated than the case for S = 1=2 due to an additional local degree of freedom, which has interesting implications for the possible states that can be realized. Using semiclassical energy minimization as well as VMC, I show that spin S = 1 diamond-lattice antiferromagnets experience higher-order spinspin interactions that destroy previously theorized liquid-like spiral spin orderings. However, the presence of these higher-order interactions can also potentially allow other phases such as quantum spin liquids and topological paramagnets. Such results can provide an avenue for explaining anomalous phenomena like low-temperature paramagnetism in future experimental materials.