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Journal of Mathematical Chemistry

The perfect revival time of localized wave packet consisting of superposition of bound states with an arbitrary energy spectrum

M.L. Strekalov

Published Oct 18, 2016• 0 citations
Publisher
DOI
10.1007/s10910-016-0700-1

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A universal approach is developed to study revivals of wave packets made of bound states with an arbitrary spectrum En{\mathit{E}}_{\mathit{n}}En​ exhibiting hierarchical time scales. An analytic expression in form of a recursion formula is derived, which allows for a given wave packet the prediction of all revival times in any time scale. The theory is applied to metallic Rydberg clusters, i.e., two oppositely charged metallic clusters in a bound state with high angular momentum, taking into account their mutual polarization connected with a complicated n dependence of the spectrum En{\mathit{E}}_{\mathit{n}}En​. The theoretical predictions are compared with numerical results using a stroboscopic picture of the autocorrelation function. \textcopyright{} 1996 The American Physical Society.