By projecting the BCS ground state of superconducting electron condensate on the N-electron Hilbert space, a real-space equation-of-motion is obtained for the electron pair function [Formula: see text] at absolute zero temperature (T = 0):[Formula: see text]where ρN−2 denotes electron density of the (N – 2)-electron condensate given as[Formula: see text]Since the exchange-correlation potential is given as an explicit functional of electron density, this equation represents the fundamental working equation for the new density functional theory of superconductivity. The 2nd-order density matrix ΓN(1, 2|1′, 2′) projected on the N-electron Hilbert space satisfies[Formula: see text]so that asymptotically[Formula: see text]where [Formula: see text] denotes the center-of-mass coordinate of electrons e1and e2; this is considered the ODLRO (off-diagonal long-range order) at T = 0 projected on the N-electron Hilbert space. A new attractive potential analysis for the two-electron scattering problem (A. Tachibana, Bull. Chem. Soc. Jpn. 66, 3319 (1993); Int. J. Quantum Chem. 49, 625 (1994)) is straightforwardly applicable to the present equation-of-motion, and we can also plug in the vibronic interaction for the enhancement of the attractive force. Our approach is purely mathematical and basic, restricted merely at T = 0, but proves to serve as a real-space analysis of the pair function itself. Key words: equation-of-motion of electron pair, BCS theory, superconductivity, electron pair function, density functional theory.
Hilbert-space ergodicity (HSE) provides a new framework for studying thermalization in driven quantum systems, complementing the eigenstate thermalization hypothesis, which is restricted to static systems. This ergodicity is hierarchical: by quantifying how randomly the dynamics explores the Hilbert space, one obtains a family of levels termed
k-HSE. While HSE has been observed at the lowest and highest levels, finite-order HSE dynamics remains largely unexplored due to the difficulty of constructing such drives. Here, we explore this intermediate regime and uncover its distinctive physics. We first propose and prove that a family of
m-tone drives on qubits realizes
k-HSE up to
k=2m−3, with drive parameters determined at
O(k) cost. Using a single nitrogen-vacancy center in diamond, we verify this design by showing that a 3-tone drive realizes 3-HSE, with fourth-order statistics depending on the initial state. Further in-depth theoretical analysis shows that this initial-state dependence is generic across drives, demonstrating the possibility of recovering the initial state from higher-order statistics even when the dynamics is ergodic. Our work broadens the study of quantum ergodicity and reveals intriguing physics within its hierarchy.
Abstract This paper is a contemporary review of quasi-Monte Carlo (QMC) methods, that is, equal-weight rules for the approximate evaluation of high-dimensional integrals over the unit cube [0,1] s . It first introduces the by-now standard setting of weighted Hilbert spaces of functions with square-integrable mixed first derivatives, and then indicates alternative settings, such as non-Hilbert spaces, that can sometimes be more suitable. Original contributions include the extension of the fast component-by-component (CBC) construction of lattice rules that achieve the optimal convergence order (a rate of almost 1/ N , where N is the number of points, independently of dimension) to so-called “product and order dependent” (POD) weights, as seen in some recent applications. Although the paper has a strong focus on lattice rules, the function space settings are applicable to all QMC methods. Furthermore, the error analysis and construction of lattice rules can be adapted to polynomial lattice rules from the family of digital nets.