The Kondo effect, a hallmark of strong correlation physics, is characterized by the formation of an extended cloud of singlet states around magnetic impurities at low temperatures. While many implications of the Kondo cloud's existence have been verified, the existence of the singlet cloud itself has not been directly demonstrated. We suggest a route for such a demonstration by considering an observable that has no classical analog, but is still experimentally measurable: ``singlet weights'', or projections onto particular entangled two-particle states. Using approximate theoretical arguments, we show that it is possible to construct highly specific energy- and position-resolved probes of Kondo correlations. Furthermore, we consider a quantum transport setup that can be driven away from equilibrium by a bias voltage. There, we show that singlet weights are enhanced by voltage even as the Kondo effect is weakened by it. This exposes a patently nonequilibrium mechanism for the generation of Kondo-like entanglement that is inherently different from its equilibrium counterpart.
We disentangle all the individual degrees of freedom in the quantum impurity problem to deconstruct the Kondo singlet, both in real and energy space, by studying the contribution of each individual free electron eigenstate. This is a problem of two spins coupled to a bath, where the bath is formed by the remaining conduction electrons. Being a mixed state, we resort to the ``concurrence'' to quantify entanglement. We identify ``projected natural orbitals'' that allow us to individualize a single-particle electronic wave function that is responsible of more than
90 of the impurity screening. In the weak coupling regime, the impurity is entangled to an electron at the Fermi level, while in the strong coupling regime, the impurity counterintuitively entangles mostly with the high energy electrons and disentangles completely from the low-energy states carving a ``hole'' around the Fermi level. This enables one to use concurrence as a pseudo order parameter to compute the characteristic ``size'' of the Kondo cloud, beyond which electrons are weakly correlated to the impurity and are dominated by the physics of the boundary.
Entanglement entropy (EE) is commonly studied using real-space bipartitions. We show that, in quantum impurity models, an energy-space bipartition, equivalent to the momentum-space bipartition of the bath, can display universal behavior. Motivated by poor man's scaling, we logarithmically discretize the bath and partition it into high- and low-energy sectors. For models with Fermi-liquid fixed points, including the Anderson model and fully screened or underscreened Kondo models, the low-energy EE flows to constants independent of model parameters. These constants are integer multiples of
ln2 plus corrections that depend only on the logarithmic discretization parameter
Λ. We show that scale invariance of the fixed-point wavefunction in energy space maps to effective translation invariance along a one-dimensional chain, allowing the fixed points to be classified by one-dimensional topological band theory. With low-energy chiral symmetry, each
ln2 contribution originates from a topological edge mode. We also study transitions between distinct Fermi-liquid fixed points using the local-singlet--Kondo-singlet transition in a two-orbital Anderson model driven by an inter-orbital antiferromagnetic coupling. The local-singlet phase has an effectively decoupled impurity and nearly vanishing EE, whereas the Kondo-singlet phase has finite EE larger than
ln2 per spin and orbital. When chiral symmetry holds at low energies, this distinction corresponds to a topological transition of the effective bath chain. At the non-Fermi-liquid critical point, the EE develops an unstable plateau. Its
Λ dependence resembles that of the overscreened two-channel Kondo model, supporting universality within the same non-Fermi-liquid universality class.