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Journal of Material Science & Engineering

Large-Scale Bose-Einstein Condensation in a Vapor of Cesium Atoms at Normal Temperature (T=353K)

Pei-Lin You

Published Jan 1, 2016• 3 citations
Publisher

Abstract

Large-scale BEC of cesium at T=353 K was first observed. Until now, scientists have applied magnetic fields and lasers, but never applied electric fields, and atoms are oriented at random, so observation of BEC is very difficult. Our innovation lies in the application of electric fields. We theoretically proved that alkali atom (include Cs) may be polar atom doesn't conflict with quantum mechanics. Variation of the capacitance with temperature offers a means of separating the polar and non-polar atom. Cs vapor was filled in cylindrical capacitor. Our experiment shows that Cs is polar atom because its capacitance is related to temperature. In the past, to realize the phase transition, ultralow temperature is necessary. But now we don’t require ultralow temperature, because we use the critical voltage Vc to achieve the phase transition. From the entropy S=Nk ln 2πe /a=0, a=dV/kTH =2πe, Vc ≈ 63volts. When V 0; when V >Vc, S < 0, phase transition occurred. When V=350 volts, the capacitance decreased from C=1.97C0 to C ≈ C0 (C0 is the vacuum capacitance), this result implies that almost all Cs atoms (more than 98.9%), like as dipoles, are aligned with the field. We create BEC with 1.928×1017 atoms, these atoms have the same momentum. Cs material with purity 99.95% was supplied by Strem Chemicals Co., USA. Both BEC and superconductivity are condensed in the momentum space, therefore these two kinds of condensation can’t be observed with the naked eye. When superconductivity occurs, the resistance R≈0, a simple and direct method to observe superconductivity is to measure the resistance by voltammetry. Similarly, when BEC occurs, the electric susceptibility χe=C/C0 –1 ≈ 0, a simple and direct method to observe BEC is to measure the capacitance by cylindrical capacitor. BEC is also a quasi-superconducting state.

DOI
10.4172/2169-0022.1000276

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Large-scale BEC of cesium at T=353 K was first observed. Until now, scientists have applied magnetic fields and lasers, but never applied electric fields, and atoms are oriented at random, so observation of BEC is very difficult. Our innovation lies in the application of electric fields. We theoretically proved that alkali atom (include Cs) may be polar atom doesn't conflict with quantum mechanics. Variation of the capacitance with temperature offers a means of separating the polar and non-polar atom. Cs vapor was filled in cylindrical capacitor. Our experiment shows that Cs is polar atom because its capacitance is related to temperature. In the past, to realize the phase transition, ultralow temperature is necessary. But now we don’t require ultralow temperature, because we use the critical voltage Vc to achieve the phase transition. From the entropy S=Nk ln 2πe /a=0, a=dV/kTH =2πe, Vc ≈ 63volts. When V 0; when V >Vc, S < 0, phase transition occurred. When V=350 volts, the capacitance decreased from C=1.97C0 to C ≈ C0 (C0 is the vacuum capacitance), this result implies that almost all Cs atoms (more than 98.9%), like as dipoles, are aligned with the field. We create BEC with 1.928×1017 atoms, these atoms have the same momentum. Cs material with purity 99.95% was supplied by Strem Chemicals Co., USA. Both BEC and superconductivity are condensed in the momentum space, therefore these two kinds of condensation can’t be observed with the naked eye. When superconductivity occurs, the resistance R≈0, a simple and direct method to observe superconductivity is to measure the resistance by voltammetry. Similarly, when BEC occurs, the electric susceptibility χe=C/C0 –1 ≈ 0, a simple and direct method to observe BEC is to measure the capacitance by cylindrical capacitor. BEC is also a quasi-superconducting state.
Large-scale Bose-Einstein condensation (BEC) of cesium atoms has been observed (T=343K). The technical bottleneck of BEC is very small trapping volume (10-8cm3), which made the number of condensed atoms still stagnant (less than 107), much smaller than normal condensation (more than 1013), large-scale BEC has never been observed. In BEC experiment, scientists have applied magnetic field (used to trap atoms) and laser (used to cool atoms), but never considered applying electric field, because they think that all kinds of atoms are non-polar atoms. The breakthrough of the bottleneck lies in the application of electric field. In theory, despite 6s and 6p states of cesium are not degenerate, but Cs may be polar atom doesn't conflict with quantum mechanics because it is hydrogen-like atom. When an electric field was applied, Cs atoms become dipoles, therefore large-scale BEC can be observed. BEC experiment of cesium has been redone. From the entropy S=0, critical voltage Vc=78V. When V < Vc, S > 0; when V > Vc, S<0, phase transition occurred. When V=370V, condensates contained up to 2.71×1017 atoms, a forty percent improvement over previous results. This BEC is a second-order phase transition because entropy doesn't show discontinuity, from Wikipedia. It is also equivalent to a quantum phase transition. The permanent dipole moment (PDM) of Cs atom has been accurately measured: dCs=[1.84±0.15(stat) ±0.11 (syst)] ×10-8 e.cm. The PDM doesn't arise from the nuclear spin but arises from asymmetrical charge distribution, and it doesn't violate both time reversal and parity symmetry. The maximum induced dipole moment is dind ≤ 2.12 ×10-13e.cm, which can be ignored. BEC has three main features: BEC is macroscopic occupation of the ground state of the system; BEC is condensation in momentum space; Bose gas would undergo a phase transition. Our experiment is an ideal BEC because it conforms to the three features. BEC belongs to the condensation of quantum gas, when V > Vc, almost all Cs atoms (bosons) are in exactly the same state,according to Feynman, “the quantum physics is the same thing as the classical physics”, so our classical theory can explain BEC experiment satisfactorily. Ultra-low temperature is to make Bose gas phase transition, we used critical voltage to achieve phase transition, ultra-low temperature is no longer necessary. Five innovative formulas were first reported in the history of physics, the publication of this article marking mankind will enter a new era of polar atoms.
Bose–Einstein condensation (BEC) at normal temperature (T=343K) has been observed because an electric field was first applied. There are two ways to achieve phase transition: lower the temperature of Bose gas or increase its density. This article provides more appropriate method: increase the voltage. In theory, 3s and 3p states of sodium are not degenerate, but Na may be polar atom doesnot conflict with quantum mechanics because it is hydrogen-like atom. Our innovation lies in we applied an electric field used for the orientation polarization. Na vapor was filled in a cylindrical capacitor. In order to determine the polarity of sodium, we measured the capacitance at different temperatures. If Na is non-polar atom, its capacitance should be independent of temperature because the nucleus of atom is located at the center of the electron cloud. But our experiment shows that its capacitance is related to temperature, so Na is polar atom. In order to achieve Na vapor phase transition, we measured the capacitance at different voltages. From the entropy of Na vapor S=0, the critical voltage Vc=68volts. When V<Vc, many atoms are in random orientation S>0; when V>Vc, the atoms become aligned with the field S<0, phase transition occurred. When V=390 volts »Vc, the capacitance decreased from C=1.9C0 to C≈C0 (C0 is the vacuum capacitance), this result implies that almost all the Na atoms (more than 98%) are aligned with the field, Na vapor entered quasi-vacuum state. We create a BEC with 2.506×1017 atoms, condensate fraction reached 98.9%. This is BEC in momentum space. Our experiment shows that if a Bose gas enters quasi-vacuum state, this also means that it underwent phase transition and generates BEC. Therefore, quasi-vacuum state of alkali gas is essentially large-scale BEC. This is an unexpected discovery. BEC and vacuum theory are two unrelated research areas, but now they are closely linked together. The maximum induced dipole moment dind≤7.8×10−15 e cm can be neglected. Ultra-low temperature is in order to make Bose gas phase transition, we achieve the phase transition by the critical voltage, so the ultra-low temperature is not necessary. According to the standard proposed by Ketterle, although we didn’t use laser cooling atoms, our experiment is real ideal BEC. Na material with purity 99.95% was supplied by Strem Chemicals Co., USA. Our experiments are easily repeated because low temperature is not necessary.
In addition to polar molecules, there is no polar atom in the natural world, which is a deep-rooted traditional concept that has lasted for more than a century. However, our research showed that alkali-metal atoms form an exception. In theory, we proved that alkali atom may be polar atom doesn't conflict with quantum mechanics, which is a great breakthrough in measurement theory of quantum mechanics. Variation of the capacitance with temperature and density offers a means of separating polar and nonpolar atom, but no one has done these experiments so far. If alkali atom is nonpolar atom, its capacitance should be independent of temperature and density, because atomic nucleus located at the center of the electron cloud. Our experiments showed that Na, K, Rb and Cs atoms are polar atoms, because their capacitance is not only related to temperature, but also to density. Unlike alkali atoms, the capacitance of Hg gas is independent of temperature and density, so mercury is nonpolar atom. Therefore atoms can be divided into two categories: polar and nonpolar atom, this discovery will lead to an exciting revolution in Bose- Einstein condensation (BEC) research and condensed matter physics. BEC experiments have been carried out for decades, but the number of condensed atoms is still very small (<107) because scientists has never applied an electric field. Our innovation lies in the application of an electric field, we don't need magnetic field and lasers. When V=390 volts, condensates contained up to 2.51 × 1017 sodium atoms; when V=350 volts, condensates contained up to 1.93 × 1017 cesium atoms, large-scale BEC at T=343 K or 353 K has been observed. Now scientists generally assume that polar molecules may be used as candidate materials for quantum computers. In the future, polar atoms will replace polar molecules as candidate materials for quantum computers, because of its very small moment of inertia.
We study necessary conditions for the observation of Bose–Einstein condensation in a magnetically trapped sample of atomic cesium gas. These constraints are due to interatomic collisions in the sample. We show that the prospects for observing Bose–Einstein condensation are favorable for a gas of ground-state Cs atoms in the highest state of the lowest hyperfine manifold. An interesting aspect of the calculations is that the scattering length for this f = 3, m f = −3 hyperfine state shows pronounced resonance structures as a function of applied magnetic field leading to variations of two orders of magnitude. Most importantly, the scattering length can change sign near the resonances. This suggests a controllable means to change the behavior of the Bose condensate because for negative values a condensate is unstable and other (quantum-)collective effects might be observed. The origin of the resonances is understood from the bound singlet and triplet rovibrational Cs 2 states which are perturbed due to the hyperfine and Zeeman interactions. It is a long standing goal to achieve quantum-collective effects in atomic Fermi- or Bose gases. The prominent reasons are that for a relatively simple system with low density, a microscopic theoretical treatment of the phase transition is still feasible, and to have an experimental testing ground for more complicated quantum-coherent effects such as superfluidity in 4 He and superconductivity in metals. Here, we focus on atomic species which behave as (composite) bosons.
Bose-Einstein condensation (BEC) in ultra-cold magnetically-trapped sp7\\sp7sp7Li vapor was experimentally observed and quantitative measurements of condensate number were made. Compared to other BEC experiments, lithium is unique due to its negative s-wave scattering length, corresponding to effectively attractive interactions. Due to this attraction, condensates are expected to undergo mechanical collapse if the condensate number exceeds a critical value. In this experiment, an upper limit of about 1000 condensate atoms is found, in agreement with theoretical predictions.\nIn the experiment, the atoms are confined by a set of six permanent magnets in the Ioffe configuration. Optical forces are used to slow and guide atoms from a thermal atomic beam into the magnetic trap. With about 10sp810\\sp810sp8 atoms loaded into the trap, the vapor is laser-cooled to near 200 mu\\mumuK and then evaporatively cooled by application of a resonantly-tuned microwave field. Evaporative cooling produces a million-fold increase in phase-space density, reaching quantum-degenerate conditions with about 10sp5\\sp5sp5 atoms at temperatures near 300 mu\\mumuK. After cooling, the trapped atom distribution is observed by in situ imaging via an optical probe. Calculated atom distributions are fit to the image data.\nIn initial data, the imaging resolution was insufficient to see the spatially-narrow condensate peak, but as phase-space densities approached the expected phase transition, the images suddenly became distorted. Initial fits to the data suggested as many as 10sp5\\sp5sp5 condensate atoms, in strong disagreement with theoretical predictions. An imaging model, accounting for imperfections in the imaging optics, shows that the sudden appearance of the distortions is a consequence of BEC, and that these distortions led to the initial over-estimation of cloud phase-space density and condensate number.\nImproved imaging was obtained using large probe detunings, a Phase-Contrast Polarization Imaging (PCPI) technique, and near-diffraction-limited imaging optics. The PCPI method exploits the birefringence of the trapped atoms. From the resulting images, quantitative estimates of condensate number are obtained and compared with theory.
Abstract Superconductivity, superfluidity, and Bose–Einstein condensation (BEC) are among the most fascinating phenomena in nature. Their strange and often surprising properties are direct consequences of quantum mechanics. This is why they only occur at low temperatures, and it is very difficult (but hopefully not impossible!) to find a room temperature superconductor. But, while most other quantum effects only appear in matter on the atomic or subatomic scale, superfluids and superconductors show the effects of quantum mechanics acting on the bulk properties of matter on a large scale. In essence they are macroscopic quantum phenomena.