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CRC Press eBooks

Path integrals in quantum mechanics

Масуд Чайчиан, A Demichev

Published Oct 3, 2018• 9 citations
Publisher

Abstract

The aim of this chapter is to expand the concept of the path integral to quantum mechanics. The Wiener path integral which we considered in chapter 1 and the Feynman path integral in quantum mechanics have many common features. We essentially use this similarity in the first section of the present chapter reducing, in fact, some quantum-mechanical problems to consideration of the Bloch equation and the corresponding Wiener path integral.

DOI
10.1201/9781315273358-8

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The aim of this chapter is to expand the concept of the path integral to quantum mechanics. The Wiener path integral which we considered in chapter 1 and the Feynman path integral in quantum mechanics have many common features. We essentially use this similarity in the first section of the present chapter reducing, in fact, some quantum-mechanical problems to consideration of the Bloch equation and the corresponding Wiener path integral.
The aim of this chapter is to introduce the concept of the Feynman path integral. As well as developing the general construction scheme, particular emphasis is placed on establishing the interconnections between the quantum mechanical path integral, classical Hamiltonian mechanics, and classical statistical mechanics. The practice of path integration is discussed in the context of several pedagogical applications. As well as the canonical examples of a quantum particle in a single and a double potential well, we discuss the generalization of the path integral scheme to tunneling of extended objects (quantum fields), dissipative and thermally assisted quantum tunneling, and the quantum mechanical spin. In this chapter we temporarily leave the arena of many-body physics and second quantization and, at least superficially, return to single-particle quantum mechanics. By establishing the path integral approach for ordinary quantum mechanics, we will set the stage for the introduction of field integral methods for many-body theories explored in the next chapter. We will see that the path integral not only represents a gateway to higher-dimensional functional integral methods but, when viewed from an appropriate perspective, already represents a field theoretical approach in its own right. Exploiting this connection, various concepts of field theory, namely stationary phase analysis, the Euclidean formulation of field theory, instanton techniques, and the role of topology in field theory, are introduced in this chapter. The path integral: general formalism Broadly speaking, there are two approaches to the formulation of quantum mechanics: the “operator approach” based on the canonical quantization of physical observables and the associated operator algebra, and the Feynman path integral.
Abstract Feynman developed the path integral approach to quantum mechanics as an alternative to wave or matrix mechanics that has found fruitful implementation in quantum mechanics, quantum electrodynamics, and statistical physics. Despite its many successes, the usual Feynman path integral formalism suffers from a lack of mathematical rigor. Questions of mathematical rigor still exist, but Mark Kac provided a rigorous path integral approach to quantum mechanics. The Kac formulation for quantum systems is given in terms of Wiener measure for a path integral and employs the Brownian motion distribution. In this paper, we review the Feynman–Kac approach and other stochastic processes related to Brownian motion. We also give an account of the successes and difficulties we faced during our journey through numerical path integral problems involved in physics.
Introduction Preliminary remarks The path integral formalism is one of the most important tools in modern theoretical physics. Integration in functional spaces was considered for the first time by Norbert Wiener in his studies of diffusion processes [60, 61]. The corresponding integration measure is now known as the Wiener measure, i.e. the so-called Gaussian path integrals were studied. In quantum mechanics, functional integrals were introduced by R. Feynmann [62, 63] who was inspired by important observations due to P. A. M. Dirac concerning a relation between wave function and classical action [64, 65]. In modern physics the path integral formalism is applied not only to developing a quantum description for systems with infinitely many degrees of freedom as, for example, in quantum field theories or condensed matter physics, but also to ordinary quantum mechanical problems. Moreover there is a tendency to reformulate standard quantum mechanical problems (such as a particle in a “box” or potential well [66, 67], or a particle in the Coulomb field [68]) within the framework of the path integral method. The reason for doing this is rather obvious: physicists develop a new mathematical tool, a new language and, in order to comprehend all of its subtleties, it is necessary to investigate as many concrete examples as possible. Use of the path integral formalism is widespread in quantum field theory because it is the most adequate mathematical tool for a wide range of problems which allows, not only for elegant formulation of problems, but also for a great deal of simplification of their theoretical analysis.
In the late forties Richard Feynman (1948) proposed a path-integral form of quantum mechanics that proved to be equivalent to the conventional Schrödinger-equation form but possessed a much more heuristic force (see Feynman and Hibbs (1965) for a detailed exposition of Feynman’s theory). Our consideration of continuous measurements in the following chapters will be based on Feynman path integrals. A theory of quantum continuous measurements will be formulated directly in terms of path integrals instead of a limiting process of the type used in Chapter 2 .
The aim of this book is to present and explain the concept of the path integral which is intensively used nowadays in almost all the branches of theoretical physics. The notion of path integral (sometimes also called functional integral or integral over trajectories or integral over histories or continuous integral) was introduced, for the first time, in the 1920s by Norbert Wiener (1921, 1923, 1924, 1930) as a method to solve problems in the theory of diffusion and Brownian motion. This integral, which is now also called the Wiener integral, has played a central role in the further development of the subject of path integration.
This chapter presents Feynman’s formulation of quantum mechanics, based on a path integral representation of the evolution operator. The chapter presents detailed examples which make it possible to understand clearly Feynman’s “sum over paths,” and it contains a complete discussion of how to calculate Gaussian path integrals. It also discusses the Euclidean version of the path integral, as well as Wick’s theorem and Feynman diagrams. Finally, it discusses instantons in quantum mechanics.