There are more things in heaven and earth, Horatio, Than are dreamt of in your philosophy. Shakespeare , Hamlet, Act 1 Scene 5 The challenge of semiclassical mechanics: Reassessing the views Semiclassical mechanics significantly broadens our understanding of the relationship between classical and quantum mechanics. It reveals that there is much more to the relation between these theories than simply showing that classical behavior can be recovered from quantum systems in the limit of large actions ( ħ → 0) or large quantum numbers ( n → ∞). Although these limits are an important piece of the puzzle, the usual reductionist account of the quantum–classical relation in terms of these limits alone does not tell the whole story. More specifically, research in semiclassical mechanics has uncovered a number of surprising theoretical and experimental correspondences . Indeed the program of semiclassical research can be broadly understood as the theoretical and experimental task of uncovering these correspondences and extending them in new ways. On the theoretical side, semiclassical methods such as EBK quantization, Gutzwiller's trace formula, and closed orbit theory show how classical structures can be used to construct quantum quantities. These semiclassical methods have proven to be not just useful calculational tools, but also important investigative tools, in that they are often able to provide physical insight into the structure of the quantum dynamics, and hence lead to new discoveries.
There are more things in heaven and earth, Horatio, Than are dreamt of in your philosophy. Shakespeare , Hamlet, Act 1 Scene 5 The challenge of semiclassical mechanics: Reassessing the views Semiclassical mechanics significantly broadens our understanding of the relationship between classical and quantum mechanics. It reveals that there is much more to the relation between these theories than simply showing that classical behavior can be recovered from quantum systems in the limit of large actions ( ħ → 0) or large quantum numbers ( n → ∞). Although these limits are an important piece of the puzzle, the usual reductionist account of the quantum–classical relation in terms of these limits alone does not tell the whole story. More specifically, research in semiclassical mechanics has uncovered a number of surprising theoretical and experimental correspondences . Indeed the program of semiclassical research can be broadly understood as the theoretical and experimental task of uncovering these correspondences and extending them in new ways. On the theoretical side, semiclassical methods such as EBK quantization, Gutzwiller's trace formula, and closed orbit theory show how classical structures can be used to construct quantum quantities. These semiclassical methods have proven to be not just useful calculational tools, but also important investigative tools, in that they are often able to provide physical insight into the structure of the quantum dynamics, and hence lead to new discoveries.
Though this be madness, yet there is method in't. Shakespeare , Hamlet, Act 2 Scene 2 Introduction Semiclassical mechanics can be broadly understood as the theoretical and experimental study of the interconnections between classical and quantum mechanics. More narrowly, it is a field that uses classical quantities to investigate, calculate, and even explain quantum phenomena. Its methods involve an unorthodox blending of quantum and classical ideas, such as a classical trajectory with an associated quantum phase. For these reasons, semiclassical mechanics is often referred to as “putting quantum flesh on classical bones,” where classical mechanics provides the skeletal framework on which quantum quantities are constructed. There are three primary motivations for semiclassical mechanics: First, in many systems of physical interest, a full quantum calculation is cumbersome or even unfeasible. Second, even when a full quantum calculation is within reach, semiclassical methods can often provide intuitive physical insight into a problem, when the quantum solutions are opaque. And, third, semiclassical investigations can lead to the discovery of new physical phenomena that have been overlooked by fully quantum-mechanical approaches. Semiclassical methods are ideally suited for studying physics in the so-called mesoscopic regime, which can roughly be understood as the domain between the classically described macro-world and the quantum mechanically described micro-world. An area in which semiclassical studies have proven to be particularly fruitful is in the subfield of quantum chaos.
… there is something in this more than natural, if philosophy could find it out. Shakespeare , Hamlet, Act 2 Scene 2 Introduction The philosophical importance of semiclassical appeals to classical structures in explaining quantum phenomena was first recognized by Robert Batterman (1993; 1995; 2002). More generally, Batterman has argued that when it comes to explaining phenomena in the asymptotic domain between two theories, the fundamental theory describing that domain is often explanatorily deficient, and an adequate explanation must make essential reference to the less fundamental theory. For example, in discussing the relation between classical and quantum mechanics, Batterman writes, “There are many aspects of the semiclassical limit of quantum mechanics that cannot be explained purely in quantum mechanical terms, though they are in some sense quantum mechanical … [T]hese quantum mechanical features require reference to classical properties for their full explanation” (Batterman 2002, pp. 109–10). He has extended these arguments to other theory pairs with singular limits as well, arguing that in optics, for example, one finds explanations of wave-theoretic phenomena that make an essential and ineliminable appeal to ray-theoretic structures such as caustics. More recently, Batterman's arguments have been the subject of considerable criticism from figures such as Clifford Hooker (2004), Michael Redhead (2004), and Gordon Belot (2005). These criticisms have tended to cluster around the following two assumptions: First, in saying that a classical structure (such as a trajectory or caustic) explains , one is thereby committed to the claim that the structure exists .
There are many important questions that do not fall neatly into any one discipline; rather, their full investigation requires the integration of two or more distinct fields. This book is about just such a question – one that arises at the intersection of physics, philosophy, and history. The question can be simply stated as “What is the relation between classical and quantum mechanics?” The simplicity of the question, however, belies the complexity of the answer. Classical mechanics and quantum mechanics are two of the most successful scientific theories ever developed, and yet how these two very different theories can successfully describe one and the same world – the world we live in – is far from clear. One theory is deterministic, the other indeterministic; one theory describes a world in which chaotic behavior is pervasive, and the other a world in which it is almost entirely absent. Did quantum mechanics simply replace classical mechanics as the new universal theory? Do they each describe their own distinct domains of phenomena? Or is one theory really just a continuation of the other? In the philosophy literature, this sort of issue is known as the problem of intertheoretic relations. Currently, there are two accepted philosophical frameworks for thinking about intertheoric relations: the first is reductionism, and the second, pluralism. As we shall see, these labels each actually describe a family of related views.
I could be bounded in a nutshell, and count myself a king of infinite space. Shakespeare , Hamlet, Act 2 Scene 2 Introduction As we saw in the last chapter, the received account of the relation between classical and quantum mechanics is a form of reductionism, where classical mechanics is supposed to emerge from quantum mechanics in the limit of some parameter. When we examine more closely the views of three of the key founders of quantum theory, however, we see that none of them took the relation between these theories to be adequately captured by such a reductionist limit. Indeed as we shall see presently, Werner Heisenberg's account of the relation between classical and quantum mechanics is actually a strong form of theoretical pluralism, quite similar to Nancy Cartwright's metaphysical nomological pluralism introduced in Section 1.3. Rather than viewing quantum mechanics as the fundamental theory that replaced classical mechanics, Heisenberg argues that both theories are required, each having its own proper domain of applicability and each being a perfectly accurate and final description of that domain. Throughout his career, Heisenberg held a highly original view in the philosophy of science, centered on his notion of a closed theory. Very briefly, a closed theory is a tightly knit system of axioms, definitions, and laws that provides a perfectly accurate and final description of a certain limited domain of phenomena. This notion has profound implications for Heisenberg's understanding of scientific methodology, theory change, intertheoretic relations, and realism.
Physical systems have been traditionally described in terms of either classical or quantum mechanics. But in recent years, semiclassical methods have developed rapidly, providing deep physical insight and computational tools for quantum dynamics and spectroscopy. In this book, Eric Heller introduces and develops this subject, demonstrating its power with many examples. In the first half of the book, Heller covers relevant aspects of classical mechanics, building from them the semiclassical way through the semiclassical limit of the Feynman path integral. The second half of the book applies this approach to various kinds of spectroscopy, such as molecular spectroscopy and electron imaging and quantum dynamical systems with an emphasis on tunneling. Adopting a distinctly time-dependent viewpoint, Heller argues for semiclassical theories from experimental and theoretical vantage points valuable to research in physics and chemistry. Featuring more than two hundred figures, the book provides a geometric, phase-space, and coordinate-space pathway to greater understanding. Filled with practical examples and applications, The Semiclassical Way to Dynamics and Spectroscopy is a comprehensive presentation of the tools necessary to successfully delve into this unique area of quantum mechanics.