An examination of the postulates of quantum mechanics reveals a number of fundamental mathematical constructs that form its theoretical underpinnings. Many of the results that are summarized in this Chapter will only become clear after reading the rest of the book and a re-reading may be in order. The dynamical variables of classical mechanics are superseded by the quantum degree of freedom. An exhaustive and complete description of the indeterminate degree of freedom is given by its state function, which is an element of a state space that, in general, is an infinite-dimensional linear vector space. The properties of the indeterminate degree of freedom are extracted from its state vector by the linear action of operators representing experimentally observable quantities. Repeated applications of the operators on the state function yield the average value of the operator for the state [Baaquie (2013e)]. The conceptual framework of quantum mechanics is discussed in Section 2.1. The concepts of degree of freedom, state space and operators are briefly reviewed in Sections 2.3–2.5. Three distinct formulations of quantum mechanics emerge from the superstructure of quantum mechanics and these are briefly summarized in Sections 2.7–2.9. The Copenhagen quantum postulate The Copenhagen interpretation of quantum mechanics, pioneered by Niels Bohr and Werner Heisenberg, provides a conceptual framework for the interpretation of the mathematical constructs of quantum mechanics and is the standard interpretation that is followed by the majority of practicing physicists [Stapp (1963), Dirac (1999)].
An examination of the postulates of quantum mechanics reveals a number of fundamental mathematical constructs that form its theoretical underpinnings. Many of the results that are summarized in this Chapter will only become clear after reading the rest of the book and a re-reading may be in order. The dynamical variables of classical mechanics are superseded by the quantum degree of freedom. An exhaustive and complete description of the indeterminate degree of freedom is given by its state function, which is an element of a state space that, in general, is an infinite-dimensional linear vector space. The properties of the indeterminate degree of freedom are extracted from its state vector by the linear action of operators representing experimentally observable quantities. Repeated applications of the operators on the state function yield the average value of the operator for the state [Baaquie (2013e)]. The conceptual framework of quantum mechanics is discussed in Section 2.1. The concepts of degree of freedom, state space and operators are briefly reviewed in Sections 2.3–2.5. Three distinct formulations of quantum mechanics emerge from the superstructure of quantum mechanics and these are briefly summarized in Sections 2.7–2.9. The Copenhagen quantum postulate The Copenhagen interpretation of quantum mechanics, pioneered by Niels Bohr and Werner Heisenberg, provides a conceptual framework for the interpretation of the mathematical constructs of quantum mechanics and is the standard interpretation that is followed by the majority of practicing physicists [Stapp (1963), Dirac (1999)].
We summarize below some of the postulates and definitions basic to our formalism, and present some important results based on these postulates. The formalism is purely mathematical in nature with very little physics input, but it provides the structure within which the physical concepts that will be discussed in the later chapters will be framed. State vectors It is important to realize that the Quantum Theory is a linear theory in which the physical state of a system is described by a vector in a complex, linear vector space. This vector may represent a free particle or a particle bound in an atom or a particle interacting with other particles or with external fields. It is much like a vector in ordinary three-dimensional space, following many of the same rules, except that it describes a very complicated physical system. We will be elaborating further on this in the following. The mathematical structure of a quantum mechanical system will be presented in terms of the notations developed by Dirac. A physical state in this notation is described by a “ket” vector, |〉, designated variously as |α〉 or |ψ〉 or a ket with other appropriate symbols depending on the specific problem at hand. The kets can be complex. Their complex conjugates, |〉 * , are designated by 〈| which are called “bra” vectors. Thus, corresponding to every ket vector there is a bra vector. These vectors are abstract quantities whose physical interpretation is derived through their so-called “representatives” in the coordinate or momentum space or in a space appropriate to the problem under consideration.
All the chapters of the book have examined and studied various aspects of path integrals and Hamiltonians, which in turn exemplified different aspects of quantum mathematics. The principles of quantum mathematics, stated in Chapter 2, can be summarized as follows: • The fundamental degrees of freedom F form the bedrock of the quantum system. • A linear vector state space V based on the degrees of freedom F provides an exhaustive description of the quantum system. • Operators O, which includes the Hamiltonian H , represent the physical properties of the degree of freedom and act on the state space V . Observable quantities are the matrix elements of the physical operators. • A spacetime description of quantum indeterminacy is encoded in the Lagrangian L and the Dirac–Feynman formula relates it to the Hamiltonian. • The path integral provides a representation of all the physical properties of a quantum system. In particular, the path integral yields the correlation functions of the degrees of freedom as well as the probability amplitudes for quantum transitions. • The interconnection of the path integral with the underlying Hamiltonian and state space is a specific feature of quantum mathematics that distinguishes path integration from functional integration in general.
The mathematical formalism of quantum theory in terms of vectors and operators in infinite-dimensional complex vector spaces is very abstract. The definitions of many mathematical quantities used do not seem to have an intuitive meaning, which makes it difficult to appreciate the mathematical formalism and understand quantum mechanics. This book provides intuition and motivation to the mathematics of quantum theory, introducing the mathematics in its simplest and familiar form, for instance, with three-dimensional vectors and operators, which can be readily understood. Feeling confident about and comfortable with the mathematics used helps readers appreciate and understand the concepts and formalism of quantum mechanics. This book is divided into four parts. Part I is a brief review of the general properties of classical and quantum systems. A general discussion of probability theory is also included which aims to help in understanding the probability theories relevant to quantum mechanics. Part II is a detailed study of the mathematics for quantum mechanics. Part III presents quantum mechanics in a series of postulates. Six groups of postulates are presented to describe orthodox quantum systems. Each statement of a postulate is supplemented with a detailed discussion. To make them easier to understand, the postulates for discrete observables are presented before those for continuous observables. Part IV presents several illustrative applications, which include harmonic and isotropic oscillators, charged particle in external magnetic fields and the Aharonov–Bohm effect. For easy reference, definitions, theorems, examples, comments, properties and results are labelled with section numbers. Various symbols and notations are adopted to distinguish different quantities explicitly and to avoid misrepresentation. Self-contained both mathematically and physically, the book is accessible to a wide readership, including astrophysicists, mathematicians and philosophers of science who are interested in the foundations of quantum mechanics.
We review the postulates of quantum mechanics with respect to the representation of physical states and measurable quantities, their time evolution, and the interpretation of measurements. We first formulate the postulates in terms of wave functions and differential operators, and then reformulate them in the abstract Hilbert space of state vectors, using Dirac’s notations. Improper states subject to Dirac’s delta normalization are introduced, and the space of physical states is extended to include them. The postulates are rationalized by associating each Hermitian linear operator with a complete orthonormal system of its eigenvectors, where measurement probabilities depend on the projections of these eigenvectors on the system’s state vector. Particularly, wave functions are identified as projections of state vectors on the position operator eigenstates. State vectors representing multidimensional systems are formulated as tensor products of vectors in their subspaces. Finally, we address the general uncertainty relations in simultaneous measurements of different observables.
Operators represent physically observable quantities, as discussed in Section 2.5. The structure and property of operators depend on the nature of the degree of freedom; operators act on the state space and in particular on the state vector of a given degree of freedom. The significance of operators in the interpretation of quantum mechanics has been discussed in Baaquie (2013e). The operators discussed in this chapter are mostly based on the continuous degree of freedom, which is analyzed in Section 3.1. Hermitian operators represent physically observable properties of a degree of freedom and their mathematical properties are defined in Section 3.3. The coordinate and momentum operators are the leading exemplar of a pair of noncommuting Hermitian operators and these are studied in some detail in Section 3.4. The Weyl operators yield, as in Section 3.5, a finite-dimensional example of the shift and scaling operators; Section 3.8 provides a unitary representation of the coordinate and momentum operators. The term self-adjoint operator is used for Hermitian operators when there is a need to emphasize the importance of the domain of the Hilbert space on which the operators act – a topic not usually discussed in most books on quantum mechanics. Sections 3.10 and 3.11 discuss the concept of self-adjoint operators, in particular the crucial role played by the domain for realizing the property of self-adjointness. It is shown in Section 3.12 how the requirement of self-adjointness yields a non-trivial extension of Hamiltonians that include singular interactions.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.