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Cambridge University Press eBooks

The rise of quantum theory

Tian Yu Cao

Published Feb 13, 1997• 0 citations
Publisher

Abstract

The origin of the relativity theories was closely bound up with the development of electromagnetic concepts, a development that approached a coherent fieldtheoretical formulation, according to which all actions may vary in a continuous manner. In contrast, quantum theory arose out of the development of atomic concepts, a development that was characterized by the acknowledgment of a fundamental limitation to classical physical ideas when applied to atomic phenomena. This restriction was expressed in the so-called quantum postulate, which attributed to any atomic process an essential discontinuity that was symbolized by Planck's quantum of action. Quantum field theory (QFT) is a later phase of the conceptual developments of quantum theory, and has the old quantum theory and non-relativistic quantum mechanics, essentially the preliminary analyses of the interactions between atoms and radiation, as its predecessors. This chapter will review some features of quantum physics that are relevant to the rise of QFT. The quantization of motion In solving the problem of the equilibrium between matter and radiation, Max Planck (1900) showed that the laws of heat radiation demanded an element of discontinuity in the description of atomic processes. In the statistical behavior of atoms represented, in Planck's description, by linear resonators in their interactions with radiation, only states of vibration should be taken into account whose energy was an integral multiple of a quantum, hv , where h is Planck's constant and v is the frequency of the resonator. Planck himself believed that the discontinuity of energy was only a property of atoms, and was not ready to apply the idea of energy quantization to radiation itself.

DOI
10.1017/cbo9780511563997.009

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The origin of the relativity theories was closely bound up with the development of electromagnetic concepts, a development that approached a coherent fieldtheoretical formulation, according to which all actions may vary in a continuous manner. In contrast, quantum theory arose out of the development of atomic concepts, a development that was characterized by the acknowledgment of a fundamental limitation to classical physical ideas when applied to atomic phenomena. This restriction was expressed in the so-called quantum postulate, which attributed to any atomic process an essential discontinuity that was symbolized by Planck's quantum of action. Quantum field theory (QFT) is a later phase of the conceptual developments of quantum theory, and has the old quantum theory and non-relativistic quantum mechanics, essentially the preliminary analyses of the interactions between atoms and radiation, as its predecessors. This chapter will review some features of quantum physics that are relevant to the rise of QFT. The quantization of motion In solving the problem of the equilibrium between matter and radiation, Max Planck (1900) showed that the laws of heat radiation demanded an element of discontinuity in the description of atomic processes. In the statistical behavior of atoms represented, in Planck's description, by linear resonators in their interactions with radiation, only states of vibration should be taken into account whose energy was an integral multiple of a quantum, hv , where h is Planck's constant and v is the frequency of the resonator. Planck himself believed that the discontinuity of energy was only a property of atoms, and was not ready to apply the idea of energy quantization to radiation itself.
The origin of the relativity theories was closely bound up with the development of electromagnetic concepts, a development that approached a coherent field-theoretical formulation, according to which all actions may vary in a continuous manner. In contrast, quantum theory arose out of the development of atomic concepts, a development that was characterized by the acknowledgment of a fundamental limitation to classical physical ideas when applied to atomic phenomena. This restriction was expressed in the so-called quantum postulate, which attributed to any atomic process an essential discontinuity that was symbolized by Planck’s quantum of action and soon incarnated in quantization condition (commutation or anticommutation relations) and uncertainty relations.
This chapter presents the basic physical ideas that underpin the quantum theory. Historians place the beginnings of the quantum theory at 1900. That year Max Planck published his famous formula for the distribution of energy as a function of frequency in black-body radiation. Curiously, although radiation theory gave birth to quantum mechanics, the interaction of matter and electromagnetic radiation is a rather advanced topic in quantum mechanics and it took almost fifty years for an acceptable formulation to be achieved. One reason for this is that photons are quanta of the electromagnetic field, and the quantum theory of fields requires a relativistic treatment to be entirely successful. The corpuscular nature of light was only half of the input that gave birth to quantum mechanics. The other half concerns matter. Given that the discreteness of photons manifests itself during the emission and absorption process, it is not surprising to find that quantum oddities afflict the behaviour of material particles too.
Planck's introduction of the quantum of action in 1900 was followed by 25 years of trial and error in quest of the understanding of the quantum world; different ideas and directions had to be pursued until the path leading to the elementary quantum theory was discovered. Radical changes away from traditional perceptions about natural phenomena were necessary, the entire system of basic concepts in classical physics had to be abandoned and replaced by a new mode of thought. Continuity and determinism of classical laws were no longer applicable on the quantum scale, where dynamical behaviour proceeds by discontinuous and statistical quantum transitions. Albert Einstein laid the essential foundations for the new concept; Max Born made the decisive step further leading to the breakthrough in 1925. The development of the ideas, which eventually resulted in the elementary quantum theory in 1925/26, will be described, relying on original publications and letters written during that period in time by the major contributors. The fundamental laws of Quantum Theory derived by Max Born and Pascual Jordan may mathematically be represented in many different ways, and particular emphasis is given to the distinction between physical content and mathematical representation.
Abstract There are two rather different phenomena that furthered the development of quantum theory: blackbody radiation and atomic spectra. In fact quantum theory began in 1900 with Planck’s radiation law and his introduction of the quantum of action h (Episode 7). His derivation of the law was by no means stringent. He assumed the existence of many resonators (atoms or molecules) of different but fixed frequencies ν, which could emit or absorb radiation only in quanta of energy E = hν. Einstein, in his light-quantum hypothesis of 1905, postulated that the energy quantization is a property of the radiation field itself and not due to the material resonators. He found a similarity between a cavity filled with radiation consisting of quanta and a vessel filled with gas consisting of atoms. However, he could not obtain Planck’s law but only Wien’s (Episode 10).
Quantum Mechanics and its Interpretations Peter E. Hodgson (bio) Quantum Mechanics is an elegant and indeed beautiful formalism, and enables the results of many physical measurements to be calculated with great accuracy. But from the earliest days there has been intense debate about the interpretation of quantum mechanics, and it shows no signs of being settled; if anything, it is becoming more intense over the years. It should therefore be evident that the most that can be done here is to try to show where the real difficul-ties lie, and how the failure to recognize that quantum mechanics is an essentially statistical theory has led to a series of confusing quantum paradoxes. It is just these paradoxes that have often been used to support theological speculations. The Discovery of the Quantum The quantum nature of the physical world was discovered by Max Planck in the early years of the twentieth century. He was studying thermodynamics and his attention was drawn to the frequency distribution of black-body radiation. This radiation is emitted from a small hole in a heated enclosure with rough walls, which ensures [End Page 62] that the radiation reaches statistical equilibrium before emission. The frequency distribution is found to be independent of the material lining the walls of the oven, so Planck realized that it must be a fundamental characteristic of all matter. This frequency distribution had been measured by several experimentalists, and Planck resolved to try to see how it can be derived theoretically. Already Rayleigh and Jeans had used classical radiation theory to derive an expression that fitted the data well at low frequencies but tended to infinity at high energies, which was of course unacceptable. The physicist Wien had derived a formula that fitted the data at high frequencies but failed at low frequencies. Planck used an ingenious argument based on entropy to interpolate between these two formulae and obtained a formula, now known as the Planck distribution, that fitted the data perfectly. His next task was to understand the physics behind his formula. He used the familiar technique of assuming that the energy is emitted in small finite amounts, and then let their size tend to zero, so as to represent a continuous distribution. To his great surprise, the intermediate formula with discrete amounts of energy, called quanta, gave the Planck distribution, but the final result, with infinitely small quanta, did not. All his instincts as a physicist rebelled against this conclusion. Surely energy must be emitted continuously. He tried hard to find a way to avoid this unwelcome conclusion, but without success. He had to admit that it is a feature of the world. Soon it was confirmed by Einstein’s interpretation of the photoelectric effect. This story shows clearly that physicists do not impose their ideas on the world, but recognize and accept what they find, whether or not it agrees with their original ideas. The world is made by God in ways that often we cannot imagine. [End Page 63] The Old Quantum Theory A few years later Rutherford discovered that the atom has a small central nucleus containing most of its mass surrounded by a number of electrons. Bohr used the idea of the quantum to build his model of the atom. He assumed that the electrons go around the nucleus in discrete orbits, and that radiation is emitted when an electron falls from one orbit to a lower one. With this model, he was able to calculate to high accuracy the frequencies of the radiation emitted from an excited hydrogen atom. This was a great achievement, but to get his result he had to assume that the electrons stayed in their orbits, whereas classical theory predicted that they would continuously lose energy and rapidly spiral into the nucleus. Quantum Mechanics and its Interpretations These problems were solved by the development of quantum mechanics in the 1920s by Heisenberg, Schrodinger, Dirac, and others. This enabled what is called the wave function to be calculated for any physical system, and from the wave function the probabilities of occurrence of measurable quantities can be found. It is a beautiful theory, and is the indispensable means of calculation for atomic, nuclear...
Student research work in high school on the fundamental principles of quantum mechanics.Abstract:Quantum physics represents one of the most profound conceptual revolutions in modern science,redefining the foundations of matter, energy, and spacetime. This paper presents a structuredtheoretical examination of the development and implications of quantum mechanics, beginningwith the resolution of the ultraviolet catastrophe through energy quantization and extending tothe emergence of wave–particle duality, superposition, and intrinsic indeterminacy. By tracingthe contributions of Planck, Einstein, de Broglie, Schrödinger, Heisenberg, and Dirac, the workanalyzes the transition from classical determinism to probabilistic wave mechanics and thesubsequent formulation of quantum electrodynamics (QED) and quantum field theory (QFT).Particular attention is given to the conceptual shift from particles as localized objects toexcitations of underlying fields, providing a framework for understanding particle interactions,conservation laws, and the Standard Model of particle physics. The tension between quantummechanics and general relativity is examined through the unresolved problem of quantumgravity, highlighting the theoretical limitations that persist at singularities and Planck-scaleregimes. Rather than treating classical and quantum theories as irreconcilable domains, this studyconsiders their structural interplay and philosophical implications, emphasizing the need for aunified framework that coherently incorporates spacetime and quantization. The analysisprovides a qualitative synthesis intended to support future quantitative investigations intofundamental physics and the continued development of quantum technologies.