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Elsevier eBooks

General Principles of the Statistical Mechanics of Quantum Systems

Alexander I. Akhiezer, S. V. Peletminskiǐ

Published Jan 1, 1981• 0 citations
Publisher
DOI
10.1016/b978-0-08-025040-3.50007-9

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Classical statistical average values are generally generalized to average values of quantum mechanics. It is discovered that quantum mechanics is a direct generalization of classical statistical mechanics, and we generally deduce both a new general continuous eigenvalue equation and a general discrete eigenvalue equation in quantum mechanics, and discover that a eigenvalue of quantum mechanics is just an extreme value of an operator in possibility distribution, the eigenvalue f is just classical observable quantity. A general classical statistical uncertain relation is further given, and the general classical statistical uncertain relation is generally generalized to the quantum uncertainty principle; the two lost conditions in classical uncertain relation and quantum uncertainty principle, respectively, are found. We generally expound the relations among the uncertainty principle, singularity and condensed matter stability, discover that the quantum uncertainty principle prevents the appearance of singularity of the electromagnetic potential between nucleus and electrons, and give the failure conditions of the quantum uncertainty principle. Finally, we discover that the classical limit of quantum mechanics is classical statistical mechanics, the classical statistical mechanics may further be degenerated to classical mechanics and we discover that merely stating that the classical limit of quantum mechanics is classical mechanics is a mistake. As application examples, we deduce both the Schrödinger equation and the state superposition principle, and deduce that there exists a decoherent factor from a general mathematical representation of the state superposition principle; the consistent difficulty between statistical interpretation of quantum mechanics and determinant property of classical mechanics is overcome.