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Cambridge University Press eBooks

Derivation of relativistic quantum mechanics

B. Roy Frieden

Published Jun 10, 2004• 0 citations
Publisher

Abstract

Derivation of Klein–Gordon equation Goals and prior knowledge The main wave equations of relativistic quantum mechanics are the Klein–Gordon, Dirac, Weyl , and Rarita–Schwinger equations. The principal aim of this chapter is to derive these, by means of the EPI principles (3.16) and (3.18). The derivations generally follow Frieden (1995), or Frieden and Soffer (1995), with numerous additions. In addition, the Schrödinger wave equation (SWE), which is non -relativistic, is also to be derived. Since rigorous use of EPI gives only relativistic wave equations (Chapter 3), EPI can only derive the SWE in some approximate sense. This is directly carried through in Appendix D, or by taking the well-known non-relativistic limit of the Klein–Gordon equation in Appendix G. Also, in Appendix D a simple EPI derivation of classical mechanics is obtained. In particular, in the limit h → 0 the EPI extremum condition (3.16) is found to give Newton's second law , and the zero-condition (3.18) gives the virial theorem , of classical mechanics. Other derived results are Eq. (4.17) – the equivalence of mass, momentum, and energy; the constancy of the Planck constant h (Sec. 4.1.14); the Compton wavelength as an ultimate resolution length (Sec. 4.1.17); and the Heisenberg uncertainty principle (Sec. 4.3). It is important to state what is assumed a priori . The relativistic properties of space and time coordinates were derived in Sec. 3.5. Hence, these are assumed here. Also, appropriate units for the concepts of mass and energy are assumed to be known, although the basic relation Eq. (4.17) between them is not presumed.

DOI
10.1017/cbo9780511616907.005

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Derivation of Klein–Gordon equation Goals and prior knowledge The main wave equations of relativistic quantum mechanics are the Klein–Gordon, Dirac, Weyl , and Rarita–Schwinger equations. The principal aim of this chapter is to derive these, by means of the EPI principles (3.16) and (3.18). The derivations generally follow Frieden (1995), or Frieden and Soffer (1995), with numerous additions. In addition, the Schrödinger wave equation (SWE), which is non -relativistic, is also to be derived. Since rigorous use of EPI gives only relativistic wave equations (Chapter 3), EPI can only derive the SWE in some approximate sense. This is directly carried through in Appendix D, or by taking the well-known non-relativistic limit of the Klein–Gordon equation in Appendix G. Also, in Appendix D a simple EPI derivation of classical mechanics is obtained. In particular, in the limit h → 0 the EPI extremum condition (3.16) is found to give Newton's second law , and the zero-condition (3.18) gives the virial theorem , of classical mechanics. Other derived results are Eq. (4.17) – the equivalence of mass, momentum, and energy; the constancy of the Planck constant h (Sec. 4.1.14); the Compton wavelength as an ultimate resolution length (Sec. 4.1.17); and the Heisenberg uncertainty principle (Sec. 4.3). It is important to state what is assumed a priori . The relativistic properties of space and time coordinates were derived in Sec. 3.5. Hence, these are assumed here. Also, appropriate units for the concepts of mass and energy are assumed to be known, although the basic relation Eq. (4.17) between them is not presumed.
The Schroedinger- and Klein-Gordon equations are directly derived from classical Lagrangians. The only inputs are given by the discreteness of energy (E=hbar.w) and momentum (p=hbar.k), respectively, as well as the assumed existence of a space-pervading field of "zero-point energy" (E_0=hbar.w/2 per spatial dimension) associated to each particle of energy E. The latter leads to an additional kinetic energy term in the classical Lagrangian, which alone suffices to pass from classical to quantum mechanics. Moreover, Heisenberg's uncertainty relations are also derived within this framework, i.e., without referring to quantum mechanical or other complex-numbered functions.
We derive the equations of relativistic quantum mechanics from a modified version of classical electrodynamics, where probability is replaced by potential. As a result, a particle is not a localized entity, in the classical sense, but has a localized energy extremum. The particle/wave aspect of matter is inherent in the particle/wave equation describing elementary particles. Furthermore, the Heisenberg uncertainty and Planck-Einstein-de Broglie relations, and the Klein-Gordon, Dirac and Proca equations follow naturally from the particle/wave equation. In addition, we incorporate a new and more physical interpretation of spin angular momentum.
Abstract This chapter is seeking relativistic wave equations, which are invariant under Lorentz transformations, in an attempt to obtain a quantum mechanical description of relativistic particles. First, the chapter starts with the Klein–Gordon equation and then it discusses the Dirac equation. It also takes the non-relativistic limit of the Dirac equation to derive the Schrödinger equation with two additional terms, the Zeeman term and the spin–orbit coupling term. These two terms emerge naturally from the Dirac equation, and thus the spin, as an internal quantum number which behaves like angular momentum, is clearly identified. Finally, the existence of antimatter is clearly supported by the nature of the solutions to the Dirac equation.
The Klein–Gordon equation, written down in 1926 by Oskar Klein and Walter Gordon (and earlier in unpublished form by Schrödinger himself), is the natural relativistic extension of quantum mechanics for spin‑zero particles: (□ + m²c²/ℏ²) Ψ = 0 where □ = (1/c²) ∂ₜ² − ∇². The equation is second‑order in both time and space, treats them symmetrically, and reduces to the free‑particle Schrödinger equation in the non‑relativistic limit. Its plane‑wave solutions satisfy the relativistic mass‑shell condition E² = p²c² + m²c⁴. Why is a relativistic version needed at all? The Schrödinger equation describes how quantum systems evolve when they’re moving slowly compared to the speed of light — fine for atoms, molecules, and everyday chemistry, where electrons move at less than 1% of c. But the Schrödinger equation is first‑order in time and second‑order in space, treating the two on different footings. Special relativity says space and time are unified into a single four‑dimensional structure where Lorentz transformations mix them, and any equation that privileges time over space breaks Lorentz invariance. A truly fundamental quantum equation must respect this symmetry. Klein–Gordon is the minimal scalar‑field equation that does. The standard derivation runs by analogy: start with the relativistic energy–momentum relation E² = p²c² + m²c⁴, replace E by iℏ∂ₜ and p by −iℏ∇, apply both sides to a wavefunction. This produces the right equation but it’s not really a derivation — it’s a guess motivated by the Schrödinger operator‑substitution procedure. This walkthrough shows how the Event Density framework derives the Klein–Gordon equation from substrate primitives — the same primitives that gave the Born rule, the Schrödinger equation, and the Bell–Tsirelson bound — plus the commitment to Lorentz covariance. The participation measure becomes Lorentz‑covariant. The unique second‑order Lorentz‑scalar differential operator on a scalar field is the d’Alembertian; the minimum‑order Lorentz‑scalar linear equation is therefore (□ + M²) Ψ = 0. Dimensional analysis fixes M² = m²c²/ℏ². Local U(1) gauge invariance forces the covariant derivative and the conserved four‑current. The non‑relativistic limit, via rest‑energy factorization, recovers the free‑particle Schrödinger equation exactly. The structural payoff: the Klein–Gordon equation is what you get when the substrate ontology is pushed through a Lorentz‑covariant reformulation. No new primitives are required. Relativistic and non‑relativistic quantum mechanics are not two theories glued together by analogy; they are the same substrate ontology applied at different velocity regimes. The walkthrough is honest about the known caveats — negative‑energy solutions and the non‑positive‑definite j₀ current — both of which resolve at the Dirac level and at QFT.
This chapter introduces the concepts of the relativistic theory to basic problems of quantum physics, in particular, the extension of the Schrodinger equation to a relativistic form. Starting from the fundamental laws of relativity, the chapter evaluates the Klein–Gordon equation and investigates if the equation can be considered a generalization of the non-relativistic Schrodinger equation to the case of the relativistic energy. The chapter shows that the wave function, which is a solution to the Klein–Gordon equation, cannot be connected with the probability wave function. For this reason, the Dirac equation is used to solve the problems faced by the Klein–Gordon equation. The Dirac equation also includes the spin. The advantage of the Dirac equation over the Schrodinger and Klein–Gordon equations is that it naturally includes the spin. In the Schrodinger and Klein–Gordon equations, the spin is not present and has to be added to the wave function manually whenever the wave function determines a system with the spin.
In this study, both the Klein-Gordon equation and time-dependent Schrodinger equation are directly derived from De Broglie's (\lamda=h/p). Besides that, a new formula of the Klein-Gordon equation was obtained by using two equations, i.e., the classical wave function and relativistic total energy relation [[hw] = [(h^2 k^2)/2m] + V]. Moreover, a new equation of time-dependent Schrodinger (TDSE) in three-dimension 3D was derived and evidently obtained. Thus, the previous result corresponds to (TDSE) in 3D calculated using two equations, (i.e., Einstein energy and Newton's second law of mechanics).