A new method is proposed for a treatment of ideal quantum gases in the grand microcanonical ensemble near the thermodynamic limit. The method allows rigorous asymptotic calculations of the average number of particles and particle number fluctuations in the system with exactly fixed total energy. It also gives the finite-volume corrections for the total average number of particles and for higher moments of the particle number distribution in a grand microcanonical system approaching the thermodynamic limit. The present consideration confirms our previous findings that the scaled variance for particle number fluctuations in the grand microcanonical ensemble is different from that in the grand canonical ensemble even in the thermodynamic limit.A new method is proposed for a treatment of ideal quantum gases in the grand microcanonical ensemble near the thermodynamic limit. The method allows rigorous asymptotic calculations of the average number of particles and particle number fluctuations in the system with exactly fixed total energy. It also gives the finite-volume corrections for the total average number of particles and for higher moments of the particle number distribution in a grand microcanonical system approaching the thermodynamic limit. The present consideration confirms our previous findings that the scaled variance for particle number fluctuations in the grand microcanonical ensemble is different from that in the grand canonical ensemble even in the thermodynamic limit.

arXiv:nucl-th/0505069Journal of Physics G Nuclear and Particle PhysicsMay 19, 200616 citations

Statistical Ensemble and Quantization of Thermodynamics

Виктор Павлович Маслов

Mathematical NotesMar 1, 20024 citations

Genuine phase diffusion of a Bose-Einstein condensate in the microcanonical ensemble: A classical field study

Alice Sinatra, Yvan Castin

Within the classical field model, we find that the phase of a uniform Bose-Einstein condensate at nonzero temperature undergoes a true diffusive motion in the microcanonical ensemble, the variance of the condensate phase change between time zero and time $t$ growing linearly in $t$ . The phase diffusion coefficient obeys a simple scaling law in the double thermodynamic and Bogoliubov limit. We construct an approximate calculation of the diffusion coefficient, in fair agreement with the numerical results over the considered temperature range, and we extend this approximate calculation to the quantum field.Within the classical field model, we find that the phase of a uniform Bose-Einstein condensate at nonzero temperature undergoes a true diffusive motion in the microcanonical ensemble, the variance of the condensate phase change between time zero and time $t$ growing linearly in $t$. The phase diffusion coefficient obeys a simple scaling law in the double thermodynamic and Bogoliubov limit. We construct an approximate calculation of the diffusion coefficient, in fair agreement with the numerical results over the considered temperature range, and we extend this approximate calculation to the quantum field.

arXiv:0808.1501Physical Review ANov 10, 200820 citations

From phenomenological thermodynamics to the canonical ensemble

H. A. Buchdahl

Foundations of PhysicsDec 1, 19793 citations

Derivation and improvements of the quantum canonical ensemble from a regularized microcanonical ensemble

Jani Lukkarinen

We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by giving an explanation for the, at the first sight unreasonable, effectiveness of the canonical ensemble when applied to certain small, isolated, systems. This method also allows a direct identification between the parameters of the microcanonical and the canonical ensemble and it yields simple indicators and rigorous bounds for the effectiveness of the approximation. Finally, we derive an asymptotic expansion of the microcanonical corrections to the canonical ensemble for those systems, which are near, but not quite, at the thermodynamical limit and show how and why the canonical ensemble can be applied also for systems with an exponentially increasing density of states. The aim throughout the paper is to keep mathematical rigour intact while attempting to produce results which are both physically and practically interesting.We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by giving an explanation for the, at the first sight unreasonable, effectiveness of the canonical ensemble when applied to certain small, isolated, systems. This method also allows a direct identification between the parameters of the microcanonical and the canonical ensemble and it yields simple indicators and rigorous bounds for the effectiveness of the approximation. Finally, we derive an asymptotic expansion of the microcanonical corrections to the canonical ensemble for those systems, which are near, but not quite, at the thermodynamical limit and show how and why the canonical ensemble can be applied also for systems with an exponentially increasing density of states. The aim throughout the paper is to keep mathematical rigour intact while attempting to produce results which are both physically and practically interesting.

arXiv:cond-mat/9809102Journal of Physics A Mathematical and GeneralJan 1, 19998 citations

t

growing linearly in

t

. The phase diffusion coefficient obeys a simple scaling law in the double thermodynamic and Bogoliubov limit. We construct an approximate calculation of the diffusion coefficient, in fair agreement with the numerical results over the considered temperature range, and we extend this approximate calculation to the quantum field.