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World Scientific series in 20th century physics

On the Quantum Theory of the Temperature of Absolute Zero

G. Beck, Hans Albrecht Bethe, W. Riezler

Published Jul 1, 1997• 0 citations
Publisher
DOI
10.1142/9789812795755_0005

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The second and third laws of thermodynamics can be used to establish a fundamental bound for the maximum possible cooling rate in approaching the absolute zero of temperature. In modeling the behavior of the molecular refrigerators geared toward attaining ultralow temperatures, only quantum mechanical, as opposed to classical physics, models can be admissible. As a simple model, we analyze a three-level quantum refrigerator, and in particular its irreversible thermodynamic performance as absolute zero is approached.
This work presents a constructive thermodynamic protocol that reaches exactly absolute zero using finite resources, within the rigorous framework of the resource theory of thermal operations. The core result is a General Zero‑Work Cooling Theorem: for any heat bath with strictly convex microcanonical entropy that contains a local two‑level subsystem matching the target qubit gap, a cascade of energy‑conserving SWAP operations cools the qubit from a finite initial temperature to any lower temperature in the bath’s accessible range with identically zero work and a finite number of steps. When the microcanonical temperature can be made arbitrarily small, as in an explicit quadratic‑entropy construction; the cascade alone reaches arbitrarily low temperatures work‑free. A single quantum non‑demolition measurement and a conditional π‑pulse then deterministically map the qubit to its exact ground state at a small, constant work cost, achieving exactly absolute zero with finite total work, a finite number of operations, and a finite predetermined time. The result demonstrates that the unattainability of absolute zero is not a universal law of nature but a contingent restriction to concave‑entropy baths and measurement‑free unitaries. It elevates the escape clause of Masanes-Oppenheim to a generalized unattainability theorem for convex‑entropy systems, with direct connections to black hole thermodynamics, massive gravity, and quantum gravity models. The paper includes a fully explicit quadratic‑entropy cascade, rigorous bounds on all finite‑size corrections, a thermodynamic embedding of the measurement step via Landauer erasure, and a systematic refutation of all known objections.