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High Resolution Spectroscopy

Interaction of electromagnetic radiation with atoms and molecules

J. Michael Hollas

Published Jan 1, 1982• 0 citations
Publisher
DOI
10.1016/b978-0-408-10605-4.50007-7

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In the environment, there exists a continuous interaction between electromagnetic radiation and matter. So, atoms continuously interact with the photons of the environmental electromagnetic fields. This electromagnetic interaction is the consequence of the continuous and universal thermal non-equilibrium, that introduces an element of randomness to atomic and molecular motion. Consequently, a decreasing of path probability required for microscopic reversibility of evolution occurs. Recently, an energy footprint has been theoretically proven in the atomic electron-photon interaction, related to the well known spectroscopic phase shift effect, and the results on the irreversibility of the electromagnetic interaction with atoms and molecules, experimentally obtained in the late sixties. Here, we want to show how this quantum footprint is the "origin of time". Last, the result obtained represents also a response to the question introduced by Einstein on the analysis of the interaction between radiation and molecules when thermal radiation is considered; he highlighted that in general one restricts oneself to a discussion of the energy exchange, without taking the momentum exchange into account. Our result has been obtained just introducing the momentum into the quantum analysis.
This systematic introduction to quantum electrodynamics focuses on the interaction of radiation with outer electrons and nuclei of atoms and molecules, answering the long-standing need of chemists and physicists for a comprehensive text on this highly specialized subject.Geared toward postgraduate students in the chemical sciences who require an understanding of quantum electrodynamics as applied to the interpretation of optical experiments on atoms and molecules, the text offers a detailed explanation of the quantum theory of electromagnetic radiation and its interaction with matter. It feat